Study on the oxidation mechanism of mixed thiols in light oil sweetening. 1: Kinetics and mechanism of homogeneous catalytic cooxidation of mixed 2-methyl-2-propanethiol and ethanethiol
Journal Article
·
· Industrial and Engineering Chemistry Research
- Univ. of Petroleum, Dongying (China). Chemical Engineering Dept.
The accelerated oxidation of 2-methyl-2-propanethiol by ethanethiol was discovered first through the kinetics study of homogeneous catalyst cooxidation of mixed 2-methyl-2-propanethiol and ethanethiol. A mechanism which conforms well to the experimental results was proposed, and the derived rate law follows the two-substrate Michaelis-Menten equation. Discussion is presented for the industrial sweetening operation in view of the mechanism.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 178373
- Journal Information:
- Industrial and Engineering Chemistry Research, Journal Name: Industrial and Engineering Chemistry Research Journal Issue: 6 Vol. 34; ISSN IECRED; ISSN 0888-5885
- Country of Publication:
- United States
- Language:
- English
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