Disorder recovers the Wiedemann-Franz law in the metallic phase of VO2

Jin, Lei; Zeltmann, Steven E.; Choe, Hwan Sung; Liu, Huili; Allen, Frances I.; Minor, Andrew M.; Wu, Junqiao

doi:10.1103/physrevb.102.041120

Title: Disorder recovers the Wiedemann-Franz law in the metallic phase of VO₂

Journal Article · Wed Jul 22 00:00:00 EDT 2020 · Physical Review B

DOI:https://doi.org/10.1103/physrevb.102.041120· OSTI ID:1783109

Jin, Lei ^[1]; Zeltmann, Steven E. ^[2];

^[1]; Liu, Huili ^[1];

^[2]; Minor, Andrew M. ^[2];

^[1]

Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Center for Electron Microscopy

At temperatures higher than 341 K, vanadium dioxide (VO₂) is a strongly correlated metal with resistivity exceeding the Mott-Ioffe-Regel limit. Its electronic thermal conductivity is lower than that predicted by the Wiedemann-Franz (WF) law, and can be explained by nonquasiparticle transport where heat and charge currents follow separate diffusive modes. In contradiction, the Wiedemann-Franz law is a direct consequence of quasiparticle transport where charge carriers are elastically scattered. In this work, we enhance elastic electron scattering in VO₂ by introducing atomic disorder with ion irradiation. Furthermore, a gradual and eventually full recovery of the WF law is observed at high defect densities. This observation provides an example that connects hydrodynamic quasiparticle transport to nonquasiparticle transport in metallic systems.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: AC02-05CH11231; DMR-1608899; 0939514; DMR1548924

OSTI ID:: 1783109

Journal Information:: Physical Review B, Vol. 102, Issue 4; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

References (31)

Effect of Zn impurities on the normal-state Hall angle in single-crystal YBa_{2}Cu_{3-x}Zn_{x}O_{7-δ} Chien, T.; Wang, Z.; Ong, N. Physical Review Letters, Vol. 67, Issue 15 https://doi.org/10.1103/PhysRevLett.67.2088	journal	October 1991
Resistivity of the high-temperature metallic phase of ${VO}_{2}$ Allen, Philip B.; Wentzcovitch, Renata M.; Schulz, Werner W. Physical Review B, Vol. 48, Issue 7 https://doi.org/10.1103/PhysRevB.48.4359	journal	August 1993
Measuring Thermal and Thermoelectric Properties of One-Dimensional Nanostructures Using a Microfabricated Device Shi, Li; Li, Deyu; Yu, Choongho Journal of Heat Transfer, Vol. 125, Issue 5 https://doi.org/10.1115/1.1597619	journal	September 2003
Electrical transport, electrothermal transport, and effective electron mass in single-crystalline In $_{2}$ O $_{3}$ films Preissler, Natalie; Bierwagen, Oliver; Ramu, Ashok T. Physical Review B, Vol. 88, Issue 8 https://doi.org/10.1103/PhysRevB.88.085305	journal	August 2013
Wiedemann-Franz law and Fermi liquids Lavasani, Ali; Bulmash, Daniel; Das Sarma, Sankar Physical Review B, Vol. 99, Issue 8 https://doi.org/10.1103/PhysRevB.99.085104	journal	February 2019
The metal-insulator transitions of VO2: A band theoretical approach Eyert, V. Annalen der Physik, Vol. 11, Issue 9 https://doi.org/10.1002/1521-3889(200210)11:9%3C650::AID-ANDP650%3E3.0.CO;2-K	journal	October 2002
Metallization of vanadium dioxide driven by large phonon entropy Budai, John D.; Hong, Jiawang; Manley, Michael E. Nature, Vol. 515, Issue 7528 https://doi.org/10.1038/nature13865	journal	November 2014
Defects in correlated metals and superconductors Alloul, H.; Bobroff, J.; Gabay, M. Reviews of Modern Physics, Vol. 81, Issue 1 https://doi.org/10.1103/RevModPhys.81.45	journal	January 2009
Non-Fermi liquids and the Wiedemann-Franz law Mahajan, Raghu; Barkeshli, Maissam; Hartnoll, Sean A. Physical Review B, Vol. 88, Issue 12 https://doi.org/10.1103/PhysRevB.88.125107	journal	September 2013
Observation of the Dirac fluid and the breakdown of the Wiedemann-Franz law in graphene Crossno, J.; Shi, J. K.; Wang, K. Science, Vol. 351, Issue 6277 https://doi.org/10.1126/science.aad0343	journal	February 2016
Nanoscale Engineering in VO ₂ Nanowires via Direct Electron Writing Process Zhang, Zhenhua; Guo, Hua; Ding, Wenqiang Nano Letters, Vol. 17, Issue 2 https://doi.org/10.1021/acs.nanolett.6b04118	journal	January 2017
Suppression of Metal-Insulator Transition in VO2 by Electric Field-Induced Oxygen Vacancy Formation Jeong, J.; Aetukuri, N.; Graf, T. Science, Vol. 339, Issue 6126 https://doi.org/10.1126/science.1230512	journal	March 2013
Axially Engineered Metal–Insulator Phase Transition by Graded Doping VO ₂ Nanowires Lee, Sangwook; Cheng, Chun; Guo, Hua Journal of the American Chemical Society, Vol. 135, Issue 12 https://doi.org/10.1021/ja400658u	journal	March 2013
Anomalously low electronic thermal conductivity in metallic vanadium dioxide Lee, Sangwook; Hippalgaonkar, Kedar; Yang, Fan Science, Vol. 355, Issue 6323 https://doi.org/10.1126/science.aag0410	journal	January 2017
Violation of the Wiedemann-Franz Law in Hydrodynamic Electron Liquids Principi, Alessandro; Vignale, Giovanni Physical Review Letters, Vol. 115, Issue 5 https://doi.org/10.1103/PhysRevLett.115.056603	journal	July 2015
Correlated metallic state of vanadium dioxide Qazilbash, M. M.; Burch, K. S.; Whisler, D. Physical Review B, Vol. 74, Issue 20 https://doi.org/10.1103/PhysRevB.74.205118	journal	November 2006
Simultaneous Enhancement of Electrical Conductivity and Thermopower of Bi ₂ Te ₃ by Multifunctionality of Native Defects Suh, Joonki; Yu, Kin Man; Fu, Deyi Advanced Materials, Vol. 27, Issue 24 https://doi.org/10.1002/adma.201501350	journal	May 2015
Ultra-long, free-standing, single-crystalline vanadium dioxide micro/nanowires grown by simple thermal evaporation Cheng, Chun; Liu, Kai; Xiang, Bin Applied Physics Letters, Vol. 100, Issue 10 https://doi.org/10.1063/1.3693381	journal	March 2012
Theory of universal incoherent metallic transport Hartnoll, Sean A. Nature Physics, Vol. 11, Issue 1 https://doi.org/10.1038/nphys3174	journal	December 2014
On the calculation of Lorenz numbers for complex thermoelectric materials Wang, Xufeng; Askarpour, Vahid; Maassen, Jesse Journal of Applied Physics, Vol. 123, Issue 5 https://doi.org/10.1063/1.5009939	journal	February 2018
Evolution of Metallicity in Vanadium Dioxide by Creation of Oxygen Vacancies Zhang, Zhen; Zuo, Fan; Wan, Chenghao Physical Review Applied, Vol. 7, Issue 3 https://doi.org/10.1103/PhysRevApplied.7.034008	journal	March 2017
Ioffe-Regel criterion and resistivity of metals Gurvitch, M. Physical Review B, Vol. 24, Issue 12 https://doi.org/10.1103/PhysRevB.24.7404	journal	December 1981
SRIM – The stopping and range of ions in matter (2010) Ziegler, James F.; Ziegler, M. D.; Biersack, J. P. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 268, Issue 11-12 https://doi.org/10.1016/j.nimb.2010.02.091	journal	June 2010
Anomalous Reduction of the Lorenz Ratio at the Quantum Critical Point in YbAgGe Dong, J. K.; Tokiwa, Y.; Bud’ko, S. L. Physical Review Letters, Vol. 110, Issue 17 https://doi.org/10.1103/PhysRevLett.110.176402	journal	April 2013
Anisotropic Violation of the Wiedemann-Franz Law at a Quantum Critical Point Tanatar, M. A.; Paglione, J.; Petrovic, C. Science, Vol. 316, Issue 5829 https://doi.org/10.1126/science.1140762	journal	June 2007
Gross violation of the Wiedemann–Franz law in a quasi-one-dimensional conductor Wakeham, Nicholas; Bangura, Alimamy F.; Xu, Xiaofeng Nature Communications, Vol. 2, Issue 1 https://doi.org/10.1038/ncomms1406	journal	July 2011
Isostructural metal-insulator transition in VO ₂ Lee, D.; Chung, B.; Shi, Y. Science, Vol. 362, Issue 6418 https://doi.org/10.1126/science.aam9189	journal	November 2018
The identification of defect structures for oxygen pressure dependent VO2 crystal films Fan, Shaojuan; Fan, Lele; Li, Qiang Applied Surface Science, Vol. 321 https://doi.org/10.1016/j.apsusc.2014.10.057	journal	December 2014
Electronic hydrodynamics and the breakdown of the Wiedemann-Franz and Mott laws in interacting metals Lucas, Andrew; Das Sarma, Sankar Physical Review B, Vol. 97, Issue 24 https://doi.org/10.1103/PhysRevB.97.245128	journal	June 2018
Effect of disorder on the metal-insulator transition of vanadium oxides: Local versus global effects Ramirez, Juan Gabriel; Saerbeck, Thomas; Wang, Siming Physical Review B, Vol. 91, Issue 20 https://doi.org/10.1103/PhysRevB.91.205123	journal	May 2015
Hall Effect in V $O_{2}$ near the Semiconductor-to-Metal Transition Rosevear, W. H.; Paul, W. Physical Review B, Vol. 7, Issue 5 https://doi.org/10.1103/PhysRevB.7.2109	journal	March 1973

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Title: Disorder recovers the Wiedemann-Franz law in the metallic phase of VO₂