Structural and Spectroscopic Comparison of Soft-Se vs. Hard-O Donor Bonding in Trivalent Americium/Neodymium Molecules

Goodwin, Conrad Alexander Phillip; Schlimgen, Anthony William; Albrecht-Schönzart, Thomas E; Batista, Enrique Ricardo; Gaunt, Andrew James; Janicke, Michael Timothy; Kozimor, Stosh Anthony; Scott, Brian Lindley; Stevens, Lauren Marie; White, Frankie Don Jr.; Yang, Ping

doi:10.1002/anie.202017186

Title: Structural and Spectroscopic Comparison of Soft-Se vs. Hard-O Donor Bonding in Trivalent Americium/Neodymium Molecules

Journal Article · Wed Mar 10 00:00:00 EST 2021 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.202017186· OSTI ID:1782645

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^[1]; Albrecht-Schönzart, Thomas E ^[2];

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^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Florida State Univ., Tallahassee, FL (United States)

Abstract Covalency is often considered to be an influential factor in driving An ³⁺ vs. Ln ³⁺ selectivity invoked by soft donor ligands. This is intensely debated, particularly the extent to which An ³⁺ /Ln ³⁺ covalency differences prevail and manifest as the f‐block is traversed, and the effects of periodic breaks beyond Pu. Herein, two Am complexes, [Am{N(E=PPh ₂ ) ₂ } ₃ ] ( 1‐Am , E=Se; 2‐Am , E=O) are compared to isoradial [Nd{N(E=PPh ₂ ) ₂ } ₃ ] ( 1‐Nd , 2‐Nd ) complexes. Covalent contributions are assessed and compared to U/La and Pu/Ce analogues. Through ab initio calculations grounded in UV‐vis‐NIR spectroscopy and single‐crystal X‐ray structures, we observe differences in f orbital involvement between Am–Se and Nd–Se bonds, which are not present in O‐donor congeners.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC); USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: 89233218CNA000001; AC52-06NA25396; SC0016568; 20180703PRD1; 20190091ER

OSTI ID:: 1782645

Alternate ID(s):: OSTI ID: 1782988

Report Number(s):: LA-UR-21-20831

Journal Information:: Angewandte Chemie (International Edition), Vol. 60, Issue 17; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (71)

Evidence for covalence in a N-donor complex of americium(iii) Adam, Christian; Kaden, Peter; Beele, Björn B. Dalton Transactions, Vol. 42, Issue 39 https://doi.org/10.1039/c3dt50953b	journal	January 2013
Assembly of Hydrophobic Shells and Shields around Lanthanides Magennis, Steven W.; Parsons, Simon; Pikramenou, Zoe Chemistry - A European Journal, Vol. 8, Issue 24 https://doi.org/10.1002/1521-3765(20021216)8:24<5761::AID-CHEM5761>3.0.CO;2-H	journal	December 2002
Covalency in AnCp4 (An = Th–Cm): a comparison of molecular orbital, natural population and atoms-in-molecules analyses Tassell, Matthew J.; Kaltsoyannis, Nikolas Dalton Transactions, Vol. 39, Issue 29 https://doi.org/10.1039/c000704h	journal	January 2010
A Molecular Actinide–Tellurium Bond and Comparison of Bonding in [MIII{N(TePiPr2)2}3] (M=U, La) Gaunt, Andrew J.; Scott, Brian L.; Neu, Mary P. Angewandte Chemie International Edition, Vol. 45, Issue 10 https://doi.org/10.1002/anie.200503372	journal	February 2006
Bonding Changes in Plutonium(III) and Americium(III) Borates Polinski, Matthew J.; Wang, Shuao; Alekseev, Evgeny V. Angewandte Chemie, Vol. 123, Issue 38 https://doi.org/10.1002/ange.201103502	journal	August 2011
Long-Lived Near-Infrared Luminescent Lanthanide Complexes of Imidodiphosphinate “Shell” Ligands Bassett, Andrew P.; Van Deun, Rik; Nockemann, Peter Inorganic Chemistry, Vol. 44, Issue 18 https://doi.org/10.1021/ic0482436	journal	September 2005
Covalency in the f Element−Chalcogen Bond. Computational Studies of M[N(EPR ₂ ) ₂ ] ₃ (M = La, Ce, Pr, Pm, Eu, U, Np, Pu, Am, Cm; E = O, S, Se, Te; R = H, ⁱ Pr, Ph) Ingram, Kieran I. M.; Tassell, Matthew J.; Gaunt, Andrew J. Inorganic Chemistry, Vol. 47, Issue 17 https://doi.org/10.1021/ic800835k	journal	September 2008
[Am(C ₅ Me ₄ H) ₃ ]: An Organometallic Americium Complex Goodwin, Conrad A. P.; Su, Jing; Albrecht‐Schmitt, Thomas E. Angewandte Chemie, Vol. 131, Issue 34 https://doi.org/10.1002/ange.201905225	journal	July 2019
The Cambridge Structural Database Groom, Colin R.; Bruno, Ian J.; Lightfoot, Matthew P. Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 72, Issue 2, p. 171-179 https://doi.org/10.1107/S2052520616003954	journal	April 2016
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Actinide Partitioning—A Review Mathur, J. N.; Murali, M. S.; Nash, K. L. Solvent Extraction and Ion Exchange, Vol. 19, Issue 3 https://doi.org/10.1081/SEI-100103276	journal	May 2001
Structural and Density Functional Studies of Uranium(III) and Lanthanum(III) Complexes with a Neutral Tripodal N-Donor Ligand Suggesting the Presence of a U−N Back-Bonding Interaction Mazzanti, Marinella; Wietzke, Raphaël; Pécaut, Jacques Inorganic Chemistry, Vol. 41, Issue 9 https://doi.org/10.1021/ic010839v	journal	May 2002
Determining Relative f and d Orbital Contributions to M–Cl Covalency in MCl ₆ ^2– (M = Ti, Zr, Hf, U) and UOCl ₅ ^– Using Cl K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R. Journal of the American Chemical Society, Vol. 134, Issue 12 https://doi.org/10.1021/ja2105015	journal	March 2012
A structural and spectrophotometric study on the complexation of Am( iii ) with TMOGA in comparison with the extracted complex of DMDOOGA Tian, Guoxin; Shuh, David K.; Beavers, Christine M. Dalton Transactions, Vol. 44, Issue 42 https://doi.org/10.1039/C4DT02882A	journal	January 2015
Uncovering f-element bonding differences and electronic structure in a series of 1 : 3 and 1 : 4 complexes with a diselenophosphinate ligand Jones, Matthew B.; Gaunt, Andrew J.; Gordon, John C. Chemical Science, Vol. 4, Issue 3 https://doi.org/10.1039/c2sc21806b	journal	January 2013
Low‐Temperature Optical Absorption of Americium Halides Pappalardo, R. G.; Carnall, W. T.; Fields, P. R. The Journal of Chemical Physics, Vol. 51, Issue 3 https://doi.org/10.1063/1.1672121	journal	August 1969
Does covalency really increase across the 5f series? A comparison of molecular orbital, natural population, spin and electron density analyses of AnCp ₃ (An = Th–Cm; Cp = η ⁵ -C ₅ H ₅ ) Kirker, Ian; Kaltsoyannis, Nikolas Dalton Trans., Vol. 40, Issue 1 https://doi.org/10.1039/C0DT01018A	journal	January 2011
Zur Synthese und Reaktivit�t von Komplexen des Samariums mit Bis(diphenylchalkogenophosphoryl)amid. Kristallstrukturen von [{?2-(Ph2PS)2N}2Sm(thf)2],[{?3-(Ph2PSe)2N}{?2-(Ph2PSe)2N}Sm(thf)2],[{?3-(Ph2PSe)2N}2Sm(SePh)(thf)] und [{?3-(Ph2PSe)2N}2Sm(SeMes)(thf)] Geissinger, M.; Magull, J. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 623, Issue 1-6 https://doi.org/10.1002/zaac.199762301119	journal	January 1997
Lanthanide(III)/Actinide(III) Differentiation in the Cerium and Uranium Complexes [M(C5Me5)2(L)]0,+ (L=2,2′-Bipyridine, 2,2′:6′,2′′-Terpyridine): Structural, Magnetic, and Reactivity Studies Mehdoui, Thouraya; Berthet, Jean-Claude; Thuéry, Pierre Chemistry - A European Journal, Vol. 11, Issue 23 https://doi.org/10.1002/chem.200500479	journal	November 2005
N-electron valence state perturbation theory: a fast implementation of the strongly contracted variant Angeli, Celestino; Cimiraglia, Renzo; Malrieu, Jean-Paul Chemical Physics Letters, Vol. 350, Issue 3-4 https://doi.org/10.1016/S0009-2614(01)01303-3	journal	December 2001
Introduction of n -electron valence states for multireference perturbation theory Angeli, C.; Cimiraglia, R.; Evangelisti, S. The Journal of Chemical Physics, Vol. 114, Issue 23 https://doi.org/10.1063/1.1361246	journal	June 2001
Covalency in f-element complexes Neidig, Michael L.; Clark, David L.; Martin, Richard L. Coordination Chemistry Reviews, Vol. 257, Issue 2 https://doi.org/10.1016/j.ccr.2012.04.029	journal	January 2013
A comparative spectroscopic study of U(III)/Am(III) and Ln(III) complexed with N-donor ligands Denecke, Melissa A.; Panak, Petra J.; Burdet, Fabien Comptes Rendus Chimie, Vol. 10, Issue 10-11 https://doi.org/10.1016/j.crci.2006.12.010	journal	October 2007
Complexation and Separation of Lanthanides(III) and Actinides(III) by Heterocyclic N-Donors in Solutions Kolarik, Zdenek Chemical Reviews, Vol. 108, Issue 10 https://doi.org/10.1021/cr078003i	journal	October 2008
Lanthanide imidodiphosphinate complexes Katkova, Marina A.; Burin, Mikhail E.; Logunov, Alexander A. Synthetic Metals, Vol. 159, Issue 14 https://doi.org/10.1016/j.synthmet.2009.03.015	journal	July 2009
Quantification of f-element covalency through analysis of the electron density: insights from simulation Kerridge, A. Chemical Communications, Vol. 53, Issue 50 https://doi.org/10.1039/C7CC00962C	journal	January 2017
Homoleptic uranium(iii) imidodiphosphinochalcogenides including the first structurally characterised molecular trivalent actinide–Se bond Gaunt, Andrew J.; Scott, Brian L.; Neu, Mary P. Chemical Communications, Issue 25 https://doi.org/10.1039/b503106k	journal	January 2005
The CASSCF state interaction method Malmqvist, Per-Åke; Roos, Björn O. Chemical Physics Letters, Vol. 155, Issue 2 https://doi.org/10.1016/0009-2614(89)85347-3	journal	February 1989
Does Covalency Increase or Decrease across the Actinide Series? Implications for Minor Actinide Partitioning Kaltsoyannis, Nikolas Inorganic Chemistry, Vol. 52, Issue 7 https://doi.org/10.1021/ic3006025	journal	June 2012
Emergence of californium as the second transitional element in the actinide series Cary, Samantha K.; Vasiliu, Monica; Baumbach, Ryan E. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7827	journal	April 2015
Conversion of Americia to Anhydrous Trivalent Americium Halides Galley, Shane S.; Sperling, Joseph M.; Windorff, Cory J. Organometallics, Vol. 38, Issue 3 https://doi.org/10.1021/acs.organomet.8b00840	journal	January 2019
Bonding Changes in Plutonium(III) and Americium(III) Borates Polinski, Matthew J.; Wang, Shuao; Alekseev, Evgeny V. Angewandte Chemie International Edition, Vol. 50, Issue 38 https://doi.org/10.1002/anie.201103502	journal	August 2011
Separation of trivalent actinides and lanthanides using various ‘N’, ‘S’ and mixed ‘N,O’ donor ligands: a review Bhattacharyya, Arunasis; Mohapatra, Prasanta K. Radiochimica Acta, Vol. 107, Issue 9-11 https://doi.org/10.1515/ract-2018-3064	journal	September 2019
On the Origin of Covalent Bonding in Heavy Actinides Kelley, Morgan P.; Su, Jing; Urban, Matthew Journal of the American Chemical Society, Vol. 139, Issue 29 https://doi.org/10.1021/jacs.7b03251	journal	July 2017
Electronic Energy Levels in the Trivalent Lanthanide Aquo Ions. I. Pr ³⁺ , Nd ³⁺ , Pm ³⁺ , Sm ³⁺ , Dy ³⁺ , Ho ³⁺ , Er ³⁺ , and Tm ³⁺ Carnall, W. T.; Fields, P. R.; Rajnak, K. The Journal of Chemical Physics, Vol. 49, Issue 10 https://doi.org/10.1063/1.1669893	journal	November 1968
Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium Cross, Justin N.; Macor, Joseph A.; Bertke, Jeffery A. Angewandte Chemie International Edition, Vol. 55, Issue 41 https://doi.org/10.1002/anie.201606367	journal	September 2016
NMR and TRLFS studies of Ln( iii ) and An( iii ) C5-BPP complexes Adam, Christian; Beele, Björn B.; Geist, Andreas Chemical Science, Vol. 6, Issue 2 https://doi.org/10.1039/C4SC03103B	journal	January 2015
A complete active space SCF method (CASSCF) using a density matrix formulated super-CI approach Roos, Björn O.; Taylor, Peter R.; Sigbahn, Per E. M. Chemical Physics, Vol. 48, Issue 2 https://doi.org/10.1016/0301-0104(80)80045-0	journal	May 1980
Ultra-selective ligand-driven separation of strategic actinides Deblonde, Gauthier J. -P.; Ricano, Abel; Abergel, Rebecca J. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10240-x	journal	June 2019
The role of the 5f valence orbitals of early actinides in chemical bonding Vitova, T.; Pidchenko, I.; Fellhauer, D. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms16053	journal	July 2017
Hexavalent Americium Recovery Using Copper(III) Periodate McCann, Kevin; Brigham, Derek M.; Morrison, Samuel Inorganic Chemistry, Vol. 55, Issue 22 https://doi.org/10.1021/acs.inorgchem.6b02120	journal	October 2016
6-(3,5-Dimethyl-1 H -pyrazol-1-yl)-2,2′-bipyridine as Ligand for Actinide(III)/Lanthanide(III) Separation Girnt, Denise; Roesky, Peter W.; Geist, Andreas Inorganic Chemistry, Vol. 49, Issue 20 https://doi.org/10.1021/ic101309j	journal	October 2010
Software update: the ORCA program system, version 4.0: Software update Neese, Frank Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 8, Issue 1 https://doi.org/10.1002/wcms.1327	journal	July 2017
The Chemistry of the Actinide and Transactinide Elements Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean https://doi.org/10.1007/1-4020-3598-5	book	January 2006
Crystal field analysis of LaCl3:Am3+ and AmCl3 and its relationship to the spectra of frozen solutions of Am3+(aquo) Carnall, W. T. Journal of the Less Common Metals, Vol. 156, Issue 1-2 https://doi.org/10.1016/0022-5088(89)90421-9	journal	December 1989
The Renaissance of Non-Aqueous Uranium Chemistry Liddle, Stephen T. Angewandte Chemie International Edition, Vol. 54, Issue 30 https://doi.org/10.1002/anie.201412168	journal	June 2015
Experimental and Theoretical Comparison of Actinide and Lanthanide Bonding in M[N(EPR ₂ ) ₂ ] ₃ Complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, i Pr, H) Gaunt, Andrew J.; Reilly, Sean D.; Enriquez, Alejandro E. Inorganic Chemistry, Vol. 47, Issue 1 https://doi.org/10.1021/ic701618a	journal	January 2008
Unique crown thioether complexes of f elements: the crystal structure of U(iii) and La(iii) complexes of 1,4,7-trithiacyclononane Karmazin, Lydia; Mazzanti, Marinella; Pécaut, Jacques Chemical Communications, Issue 6 https://doi.org/10.1039/b200315p	journal	February 2002
Crystallographic studies of some transuranic trihalides: 239PuCl3, 244CmBr3, 249BkBr3 and 249CfBr3 Burns, John H.; Peterson, J. R.; Stevenson, J. N. Journal of Inorganic and Nuclear Chemistry, Vol. 37, Issue 3 https://doi.org/10.1016/0022-1902(75)80532-X	journal	March 1975
A series of dithiocarbamates for americium, curium, and californium Cary, Samantha K.; Su, Jing; Galley, Shane S. Dalton Transactions, Vol. 47, Issue 41 https://doi.org/10.1039/C8DT02658K	journal	January 2018
Electronic Energy Levels of the Lighter Actinides: U ³⁺ , Np ³⁺ , Pu ³⁺ , Am ³⁺ , and Cm ³⁺ Carnall, W. T.; Wybourne, B. G. The Journal of Chemical Physics, Vol. 40, Issue 11 https://doi.org/10.1063/1.1725018	journal	June 1964
Compression of curium pyrrolidine-dithiocarbamate enhances covalency Sperling, Joseph M.; Warzecha, Evan J.; Celis-Barros, Cristian Nature, Vol. 583, Issue 7816 https://doi.org/10.1038/s41586-020-2479-2	journal	July 2020
Transuranic Computational Chemistry Kaltsoyannis, Nikolas Chemistry - A European Journal, Vol. 24, Issue 12 https://doi.org/10.1002/chem.201704445	journal	November 2017
OctaDist: a tool for calculating distortion parameters in spin crossover and coordination complexes Ketkaew, Rangsiman; Tantirungrotechai, Yuthana; Harding, Phimphaka Dalton Transactions, Vol. 50, Issue 3 https://doi.org/10.1039/D0DT03988H	journal	January 2021
Efficient and accurate approximations to the molecular spin-orbit coupling operator and their use in molecular g-tensor calculations Neese, Frank The Journal of Chemical Physics, Vol. 122, Issue 3 https://doi.org/10.1063/1.1829047	journal	January 2005
Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium Cross, Justin N.; Macor, Joseph A.; Bertke, Jeffery A. Angewandte Chemie, Vol. 128, Issue 41 https://doi.org/10.1002/ange.201606367	journal	September 2016
A Molecular Actinide–Tellurium Bond and Comparison of Bonding in [MIII{N(TePiPr2)2}3] (M=U, La) Gaunt, Andrew J.; Scott, Brian L.; Neu, Mary P. Angewandte Chemie, Vol. 118, Issue 10 https://doi.org/10.1002/ange.200503372	journal	February 2006
Extraction of tetravalent americium Myasoedov, B. F.; Milyukova, M. S.; Kuzovkina, E. V. Journal of the Less Common Metals, Vol. 122 https://doi.org/10.1016/0022-5088(86)90409-1	journal	August 1986
Covalency in Americium(III) Hexachloride Cross, Justin N.; Su, Jing; Batista, Enrique R. Journal of the American Chemical Society, Vol. 139, Issue 25 https://doi.org/10.1021/jacs.7b03755	journal	June 2017
n -electron valence state perturbation theory: A spinless formulation and an efficient implementation of the strongly contracted and of the partially contracted variants Angeli, Celestino; Cimiraglia, Renzo; Malrieu, Jean-Paul The Journal of Chemical Physics, Vol. 117, Issue 20 https://doi.org/10.1063/1.1515317	journal	November 2002
[Am(C ₅ Me ₄ H) ₃ ]: An Organometallic Americium Complex Goodwin, Conrad A. P.; Su, Jing; Albrecht-Schmitt, Thomas E. Angewandte Chemie International Edition, Vol. 58, Issue 34 https://doi.org/10.1002/anie.201905225	journal	July 2019
Energy-Degeneracy-Driven Covalency in Actinide Bonding Su, Jing; Batista, Enrique R.; Boland, Kevin S. Journal of the American Chemical Society, Vol. 140, Issue 51 https://doi.org/10.1021/jacs.8b09436	journal	December 2018
δ and φ back-donation in AnIV metallacycles Kelley, Morgan P.; Popov, Ivan A.; Jung, Julie Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15197-w	journal	March 2020
Exploring Soft Donor Character of the N -2-Pyrazinylmethyl Group by Coordinating Trivalent Actinides and Lanthanides Using Aminopolycarboxylates Grimes, Travis S.; Heathman, Colt R.; Jansone-Popova, Santa Inorganic Chemistry, Vol. 59, Issue 1 https://doi.org/10.1021/acs.inorgchem.9b01427	journal	August 2019
Electrochemical oxidation of 243Am(III) in nitric acid by a terpyridyl-derivatized electrode Dares, C. J.; Lapides, A. M.; Mincher, B. J. Science, Vol. 350, Issue 6261 https://doi.org/10.1126/science.aac9217	journal	November 2015
Die Renaissance der nichtwässrigen Uranchemie Liddle, Stephen T. Angewandte Chemie, Vol. 127, Issue 30 https://doi.org/10.1002/ange.201412168	journal	June 2015
A Single Small-Scale Plutonium Redox Reaction System Yields Three Crystallographically-Characterizable Organoplutonium Complexes Windorff, Cory J.; Sperling, Joseph M.; Albrecht-Schönzart, Thomas E. Inorganic Chemistry, Vol. 59, Issue 18 https://doi.org/10.1021/acs.inorgchem.0c01671	journal	September 2020
Comparison of Covalency in the Complexes of Trivalent Actinide and Lanthanide Cations Jensen, Mark P.; Bond, Andrew H. Journal of the American Chemical Society, Vol. 124, Issue 33 https://doi.org/10.1021/ja0178620	journal	August 2002
Structure and Characterization of an Americium Bis( O,O’ -diethyl)dithiophosphate Complex Greer, R. D. M.; Celis-Barros, Cristian; Sperling, Joseph M. Inorganic Chemistry, Vol. 59, Issue 22 https://doi.org/10.1021/acs.inorgchem.0c02085	journal	October 2020
Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform Corbey, Jordan F.; Rapko, Brian M.; Wang, Zheming Inorganic Chemistry, Vol. 57, Issue 4 https://doi.org/10.1021/acs.inorgchem.7b03154	journal	February 2018
Nephelauxetic Effect and Hypersensitivity in the Optical Spectra of Actinides Barbanel’, A. ract, Vol. 78, Issue s1 https://doi.org/10.1524/ract.1997.78.special-issue.91	journal	December 1997

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
actinides
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