Open questions on the reactivity of Criegee intermediates

Caravan, Rebecca L.; Vansco, Michael F.; Lester, Marsha I.

doi:10.1038/s42004-021-00483-5

Open questions on the reactivity of Criegee intermediates

Journal Article · Thu Mar 25 00:00:00 EDT 2021 · Communications Chemistry

DOI:https://doi.org/10.1038/s42004-021-00483-5· OSTI ID:1782239

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Argonne National Lab. (ANL), Lemont, IL (United States); University of Pennsylvania, PA (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)
Univ. of Pennsylvania, Philadelphia, PA (United States)

Criegee intermediates are reactive intermediates formed in Earth’s atmosphere through ozonolysis of alkenes. Here the authors outline the fundamental chemistry that influences their highly conformer- and substituent-dependent unimolecular and bimolecular reactivity, and discuss open questions of fundamental and atmospheric interest.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Pennsylvania, Philadelphia, PA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; National Science Foundation; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: FG02-87ER13792; AC02-06CH11357; AC02-05CH11231

OSTI ID:: 1782239

Alternate ID(s):: OSTI ID: 1798304

Journal Information:: Communications Chemistry, Journal Name: Communications Chemistry Journal Issue: 1 Vol. 4; ISSN 2399-3669

Publisher:: Springer NatureCopyright Statement

Country of Publication:: United States

Language:: English

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