Negative and zero thermal expansion in α-(Cu2-xZnx)V2O7 solid solutions

Shi, Naike; Sanson, Andrea; Venier, Alessandro; Fan, Longlong; Sun, Chengjun; Xing, Xianran; Chen, Jun

doi:10.1039/d0cc04505e

Negative and zero thermal expansion in α-(Cu_2-xZnx)V₂O₇ solid solutions

Journal Article · Mon Aug 03 04:00:00 EDT 2020 · ChemComm

DOI:https://doi.org/10.1039/d0cc04505e· OSTI ID:1780663

Shi, Naike ^[1]; Sanson, Andrea ^[2]; Venier, Alessandro ^[2]; Fan, Longlong ^[3]; Sun, Chengjun ^[4]; Xing, Xianran ^[1]; ^[1]

Univ. of Science and Technology Beijing (China). Beijing Advanced Innovation Center for Materials Genome Engineering
Univ. of Padova (Italy)
Tianjin Normal Univ. (China); Argonne National Lab. (ANL), Argonne, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Negative or zero thermal expansion (NTE or ZTE) of materials is intriguing for controllable thermal expansion. In this work, we report a series of orthorhombic α-Cu_2-xZn_xV₂O₇ (x = 0, 0.1, 0.2), in which the volumetric coefficients of thermal expansion are successfully tuned from -10.19 × 10^-6 K^-1 to -1.58 × 10^-6 K^-1 in the temperature range of 100–475 K by increasing the content of Zn²⁺. It has been revealed that the transverse vibrations of oxygen bonded with vanadium are dominant in the contraction of the bc plane, leading to the overall volume NTE in α-Cu₂V₂O₇. The introduction of Zn²⁺ densifies the crystal structure, which is presumed to suppress the space of transverse vibrations and results in the ZTE in α-Cu_1.8Zn_0.2V₂O₇. This work presents an effective method to realize ZTE in anisotropic framework systems.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1780663

Alternate ID(s):: OSTI ID: 1647263

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 73 Vol. 56; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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