Self-Assembly of Metal–Organic Framework (MOF) Nanoparticle Monolayers and Free-Standing Multilayers

Katayama, Yuji; Kalaj, Mark; Barcus, Kyle S.; Cohen, Seth M.

doi:10.1021/jacs.9b10966

Self-Assembly of Metal–Organic Framework (MOF) Nanoparticle Monolayers and Free-Standing Multilayers

Journal Article · Fri Nov 29 00:00:00 EST 2019 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.9b10966· OSTI ID:1598442

Katayama, Yuji ^[1]; ^[2]; Barcus, Kyle S. ^[2]; ^[2]

Univ. of California, San Diego, CA (United States); Asahi Kasei Corp., Fuji-city (Japan); U.C. San Diego
Univ. of California, San Diego, CA (United States)

Here, we report the first self-assembled porous monolayer and free-standing multilayer films composed of metal–organic framework (MOF) nanoparticles. Self-assembled MOF monolayers (SAMMs) were assembled at a liquid–air interface to produce films that are 87 wt % (89 vol %) MOF. Monolayer self-assembly was aided by growing a layer of poly(methyl methacrylate) (PMMA) on the particle surface using a histamine anchor. SAMMs could be stacked to obtain MOF multilayers, including alternating MOF/polymer heterostructures. SAMMs were coated on silicon microparticles, and a MOF film constructed of only five stacked layers could be manipulated as a free-standing, opalescent film. These monolayers are a great advancement for obtaining highly functional porous membranes and coatings.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, San Diego, CA (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Contributing Organization:: Achievement Rewards for College Scientists (ARCS) Foundation Fellowship; Asahi Kasei Corporation

Grant/Contract Number:: FG02-08ER46519

OSTI ID:: 1598442

Alternate ID(s):: OSTI ID: 1780599

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 51 Vol. 141; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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