Stabilization of pentazolate anions in the high-pressure compounds Na 2 N 5 and NaN 5 and in the sodium pentazolate framework NaN 5 ·N 2

Bykov, Maxim; Bykova, Elena; Chariton, Stella; Prakapenka, Vitali B.; Batyrev, Iskander G.; Mahmood, Mohammad F.; Goncharov, Alexander F.

doi:10.1039/D1DT00722J

Stabilization of pentazolate anions in the high-pressure compounds Na ₂ N ₅ and NaN ₅ and in the sodium pentazolate framework NaN ₅ ·N ₂

Journal Article · Tue Jun 01 00:00:00 EDT 2021 · Dalton Transactions

DOI:https://doi.org/10.1039/D1DT00722J· OSTI ID:1780075

^[1]; ^[2]; ^[3]; ^[3]; Batyrev, Iskander G. ^[4]; Mahmood, Mohammad F. ^[5]; ^[2]

Department of Mathematics, Howard University, Washington, USA, The Earth and Planets Laboratory
The Earth and Planets Laboratory, Carnegie Institution for Science, Washington, USA
Center for Advanced Radiation Sources, University of Chicago, Lemont, USA
U.S. Army Research Laboratory, Aberdeen Proving Ground, USA
Department of Mathematics, Howard University, Washington, USA

Three oxygen-free pentazolate salts Na ₂ N ₅ , NaN ₅ and NaN ₅ ·N ₂ were synthesized from sodium azide NaN ₃ and molecular nitrogen N ₂ at 50 GPa.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1780075

Alternate ID(s):: OSTI ID: 1810838
OSTI ID: 1787792
OSTI ID: 1797497

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 21 Vol. 50; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Stabilization of pentazolate anions in the high-pressure compounds Na ₂ N ₅ and NaN ₅ and in the sodium pentazolate framework NaN ₅ ·N ₂