Insights into the Structure and Dynamics of Metal–Organic Frameworks via Transmission Electron Microscopy

Gong, Xinyi; Gnanasekaran, Karthikeyan; Chen, Zhijie; Robison, Lee; Wasson, Megan C.; Bentz, Kyle C.; Cohen, Seth M.; Farha, Omar K.; Gianneschi, Nathan C.

doi:10.1021/jacs.0c08773

Insights into the Structure and Dynamics of Metal–Organic Frameworks via Transmission Electron Microscopy

Journal Article · Fri Sep 18 00:00:00 EDT 2020 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.0c08773· OSTI ID:1779735

^[1]; ^[2]; ^[2]; ^[2]; ^[2]; Bentz, Kyle C. ^[3]; ^[3]; ^[2]; ^[4]

Northwestern Univ., Evanston, IL (United States); U.C. San Diego
Northwestern Univ., Evanston, IL (United States)
Univ. of California, San Diego, La Jolla, CA (United States)
Northwestern Univ., Evanston, IL (United States); Univ. of California, San Diego, La Jolla, CA (United States)

Metal–organic frameworks (MOFs) are hybrid materials composed of metal ions and organic linkers featuring high porosity, crystallinity, and chemical tunability at multiple length scales. Here, a recent advancement in transmission electron microscopy (TEM) and its direct application to MOF structure–property relationships have changed how we consider rational MOF design and development. Herein, we provide a perspective on TEM studies of MOFs and highlight the utilization of state-of-the-art TEM technologies to explore dynamic MOF processes and host–guest interactions. Additionally, we provide thoughts on what the future holds for TEM in the study of MOFs.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, San Diego, La Jolla, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; National Science Foundation's MRSEC program; Army Research Office

Grant/Contract Number:: FG02-08ER46519

OSTI ID:: 1779735

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 41 Vol. 142; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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