The effects of SMSI on m-Cresol Hydrodeoxygenation over Pt/Nb2O5 and Pt/TiO2

Huang, Renjing; Kwon, Ohhun; Lin, Chao; Gorte, Raymond J.

doi:10.1016/j.jcat.2021.04.012

The effects of SMSI on m-Cresol Hydrodeoxygenation over Pt/Nb₂O₅ and Pt/TiO₂

Journal Article · Wed Apr 21 00:00:00 EDT 2021 · Journal of Catalysis

DOI:https://doi.org/10.1016/j.jcat.2021.04.012· OSTI ID:1779103

^[1]; Kwon, Ohhun ^[2]; ^[2]; Gorte, Raymond J. ^[3]

Univ. of Pennsylvania, Philadelphia, PA (United States); Univ. of Delaware, Newark, DE (United States). Catalysis Center for Energy Innovation; University of Pennsylvania
Univ. of Pennsylvania, Philadelphia, PA (United States)
Univ. of Pennsylvania, Philadelphia, PA (United States); Univ. of Delaware, Newark, DE (United States). Catalysis Center for Energy Innovation

The hydrodeoxygenation (HDO) of m-cresol was studied on Pt/Nb₂O₅/MgAl₂O₄ and Pt/TiO₂/MgAl₂O₄ catalysts to understand the effects of Strong Metal Support Interactions (SMSI). The Nb₂O₅ and TiO₂ supports were prepared as 0.7-nm films on MgAl₂O₄ by Atomic Layer Deposition (ALD) to ensure that the structures of the catalyst were the same. When reduced at 773 K to place Pt in the encapsulated state, Pt/Nb₂O₅/MgAl₂O₄ was much less active than Pt/MgAl₂O₄ at 573 K but much more active at 623 K. While Pt/MgAl₂O₄ deactivated rapidly due to coking, Pt/Nb₂O₅/MgAl₂O₄ showed significantly better coke tolerance and was almost 100% selective towards toluene production. Pt/Nb₂O₅/MgAl₂O₄ reduced at lower temperatures exhibited intermediate catalytic properties. The effect of reduction temperature on Pt/TiO₂/MgAl₂O₄ was much less and this catalyst was more similar to Pt/MgAl₂O₄ than its Nb₂O₅ counterpart. Lastly, the implications of these results for understanding the nature of oxide promoters on HDO of m-cresol are discussed.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Delaware, Newark, DE (United States). Catalysis Center for Energy Innovation

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001004

OSTI ID:: 1779103

Alternate ID(s):: OSTI ID: 1781868

Journal Information:: Journal of Catalysis, Journal Name: Journal of Catalysis Vol. 398; ISSN 0021-9517

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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The effects of SMSI on m-Cresol Hydrodeoxygenation over Pt/Nb₂O₅ and Pt/TiO₂