Modified Winterbottom Construction Including Boundaries

Mansley, Zachary R.; Marks, Laurence D.

doi:10.1021/acs.jpcc.0c07316

Modified Winterbottom Construction Including Boundaries

Journal Article · Wed Dec 09 00:00:00 EST 2020 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.0c07316· OSTI ID:1778933

^[1]; Marks, Laurence D. ^[2]

Northwestern Univ., Evanston, IL (United States); Northwestern University
Northwestern Univ., Evanston, IL (United States)

There has been extensive work on the equilibrium shape of isolated nanoparticles with internal boundaries, and also single crystals on substrates. Surprisingly, almost shockingly, there has been very little work on the equilibrium shape of particles with internal boundaries on substrates. Here in this paper, the general solution is given for the configuration of particles which contain twin and other grain boundaries on a flat substrate, which can be applied to any polycrystalline or multiphase nanoparticle configuration. The solution is based upon combining the established modified-Wulff construction that has been extensively validated for twinned particles with the Winterbottom construction for single particles on a substrate. The solution is illustrated for the specific case of five-fold multiply twinned particles. Good agreement is observed between both existing experimental data in the literature as well as some experimental data included within this work.

View Accepted Manuscript (DOE)

Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-03ER15457

OSTI ID:: 1778933

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 51 Vol. 124; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Modified Winterbottom Construction Including Boundaries

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