Heterometallic Actinide-Containing Photoresponsive Metal-Organic Frameworks: Dynamic and Static Tuning of Electronic Properties

Martin, Corey R.; Leith, Gabrielle A.; Kittikhunnatham, Preecha; Park, Kyoung Chul; Ejegbavwo, Otega A.; Mathur, Abhijai; Callahan, Cameron R.; Desmond, Shelby L.; Keener, Myles R.; Ahmed, Fiaz; Pandey, Shubham; Smith, Mark D.; Phillpot, Simon R.; Greytak, Andrew B.; Shustova, Natalia B.

doi:10.1002/anie.202016826

Heterometallic Actinide-Containing Photoresponsive Metal-Organic Frameworks: Dynamic and Static Tuning of Electronic Properties

Journal Article · Tue Feb 23 23:00:00 EST 2021 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.202016826· OSTI ID:1776548

Martin, Corey R. ^[1]; ^[2]; Kittikhunnatham, Preecha ^[2]; Park, Kyoung Chul ^[2]; ^[2]; Mathur, Abhijai ^[2]; Callahan, Cameron R. ^[2]; Desmond, Shelby L. ^[2]; Keener, Myles R. ^[2]; ^[2]; Pandey, Shubham ^[3]; ^[2]; ^[4]; Greytak, Andrew B. ^[2]; ^[2]

Univ. of South Carolina, Columbia, SC (United States); University of South Carolina
Univ. of South Carolina, Columbia, SC (United States)
Colorado School of Mines, Golden, CO (United States)
Univ. of Florida, Gainesville, FL (United States)

Acquiring fundamental knowledge of properties of actinide-based materials is a necessary step to create new possibilities for addressing the current challenges in the nuclear energy and nuclear waste sectors. Here in this report, we established a photophysics–electronics correlation for actinide-containing metal-organic frameworks (An-MOFs) as a function of excitation wavelength, for the first time. A stepwise approach for dynamically modulating electronic properties was applied for the first time towards actinide-based heterometallic MOFs through integration of photochromic linkers. Optical cycling, modeling of density of states near the Fermi edge, conductivity measurements, and photoisomerization kinetics were employed to shed light on the process of tailoring optoelectronic properties of An-MOFs. Furthermore, the first photochromic MOF-based field-effect transistor, in which the field-effect response could be changed through light exposure, was constructed. As a demonstration, the change in current upon light exposure was sufficient to operate a two-LED fail-safe indicator circuit.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of South Carolina, Columbia, SC (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Alfred P. Sloan Foundation

Grant/Contract Number:: SC0016574

OSTI ID:: 1776548

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 15 Vol. 60; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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