Equilibrium vapor pressure properties for absorbent and adsorbent materials

Yang, Zhiyao; Gluesenkamp, Kyle R.; Frazzica, Andrea

doi:10.1016/j.ijrefrig.2020.12.013

Equilibrium vapor pressure properties for absorbent and adsorbent materials

Journal Article · Sun Dec 13 00:00:00 EST 2020 · International Journal of Refrigeration

DOI:https://doi.org/10.1016/j.ijrefrig.2020.12.013· OSTI ID:1783056

^[1]; ^[2]; Frazzica, Andrea ^[3]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Purdue Univ., West Lafayette, IN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Consiglio Nazionale delle Ricerche (CNR), Messina (Italy). Inst. di Tecnologie Avanzate per l'Energia Nicola Giordano

Sorption devices are important tools for the efficient utilization of fuels and waste heat. Amid a tremendous diversity of cycles and applications, all sorption systems have an equilibrium vapor pressure that depends on the sorbent temperature and composition. The vapor pressure properties of working fluids are reported in the literature in a variety of ways, which impedes wide-ranging cross comparisons or screening studies for novel applications. This work compiles equilibrium vapor pressure properties for 123 liquid absorbents with 31 absorbates and 139 solid adsorbents with 16 adsorbates. The adsorption pairs are represented with six functional forms. Additionally, most of the absorption pairs are represented with 10 functional forms, plus several that are represented with custom empirical equations. Because the functional forms used in the literature vary widely, in this work each functional form was generalized. This paper is designed to facilitate comparisons of working fluid properties for screening studies, provide a quick reference to existing research, and present a framework for standardizing the reportage of vapor pressure equilibrium data for existing and future working pairs.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1783056

Alternate ID(s):: OSTI ID: 1776344

Journal Information:: International Journal of Refrigeration, Journal Name: International Journal of Refrigeration Vol. 124; ISSN 0140-7007

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
Sorption
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adsorption
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isotherm
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Equilibrium vapor pressure properties for absorbent and adsorbent materials

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