Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Magnetic impurities in Kondo insulators: An application to samarium hexaboride

Journal Article · · Physical Review B
 [1];  [2]
  1. Johns Hopkins Univ., Baltimore, MD (United States); Johns Hopkins University
  2. Johns Hopkins Univ., Baltimore, MD (United States); George Mason Univ., Fairfax, VA (United States)

Impurities and defects in Kondo insulators can have an unusual impact on dynamics that blends with effects of intrinsic electron correlations. Such crystal imperfections are difficult to avoid, and their consequences are incompletely understood. In this work, we study magnetic impurities in Kondo insulators via perturbation theory of the s-d Kondo impurity model adapted to small-band-gap insulators. The calculated magnetization and specific heat agree with recent thermodynamic measurements in samarium hexaboride (SmB6). This qualitative agreement supports the physical picture of multichannel Kondo screening of local moments by electrons and holes involving both intrinsic and impurity bands. Specific heat is thermally activated in zero field by Kondo screening through subgap impurity bands and exhibits a characteristic upturn as the temperature is decreased. In contrast, magnetization obtains a dominant quantum correction from partial screening by virtual particle-hole pairs in intrinsic bands. We point out that magnetic impurities could impact de Haas–van Alphen quantum oscillations in SmB6, through the effects of Landau quantization in intrinsic bands on the Kondo screening of impurity moments.

Research Organization:
Johns Hopkins Univ., Baltimore, MD (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0019331; FG02-08ER46544
OSTI ID:
1775124
Journal Information:
Physical Review B, Journal Name: Physical Review B Journal Issue: 24 Vol. 101; ISSN 2469-9950
Publisher:
American Physical Society (APS)Copyright Statement
Country of Publication:
United States
Language:
English

References (86)

Influence of the Mixed-Valences State on the Magnetic Excitation Spectrum of SmB6-Based Compounds journal October 1997
Are Kondo insulators gapless? journal May 1993
Impurity states in Kondo insulators: Density of states and specific heat journal May 1993
Studies of the correlated electron system SmB6 journal June 1996
Specific heat of SmB6 at very low temperatures journal May 2006
Introduction to Many-Body Physics book December 2015
Surface electronic structure of the topological Kondo-insulator candidate correlated electron system SmB6 journal December 2013
Observation of possible topological in-gap surface states in the Kondo insulator SmB6 by photoemission journal December 2013
Direct observation of the spin texture in SmB6 as evidence of the topological Kondo insulator journal July 2014
Topological surface state in the Kondo insulator samarium hexaboride journal March 2014
One-dimensional edge state transport in a topological Kondo insulator journal November 2015
Fermi surface in the absence of a Fermi liquid in the Kondo insulator SmB6 journal October 2017
Screened moments and extrinsic in-gap states in samarium hexaboride journal April 2018
Mixed-valence insulators with neutral Fermi surfaces journal May 2018
Unconventional thermal metallic state of charge-neutral fermions in an insulator journal July 2019
MIXED VALENT SEMICONDUCTORS : SmB 6 journal July 1980
Topological surface states interacting with bulk excitations in the Kondo insulator SmB 6 revealed via planar tunneling spectroscopy journal May 2016
Transport gap in SmB 6 protected against disorder journal June 2019
Heavy fermion semiconductors journal May 2000
Exact results in the theory of magnetic alloys journal January 1983
Exact solution of the s-d exchange model (Kondo problem) journal April 1981
A poor man's derivation of scaling laws for the Kondo problem journal December 1970
Magnetic excitations observed by means of inelastic neutron scattering in polycrystalline journal June 1998
Magnetic excitation spectrum of mixed-valence SmB 6 studied by neutron scattering on a single crystal journal January 1995
Fermi surfaces in Kondo insulators journal March 2018
Localized Magnetic States in Metals journal October 1961
Bound State Due to the s − d Exchange Interaction journal July 1966
Theory of s − d Scattering in Dilute Magnetic Alloys. I. Perturbation Theory and the Derivation of the Low Equation journal September 1967
Theory of s − d Scattering in Dilute Magnetic Alloys. II. Derivation and Solution of Linear Vertex Equations journal September 1967
Quantum oscillations in strongly correlated topological Kondo insulators journal August 2019
Impurity bands in Kondo insulators journal July 1992
Kondo hole behavior in Ce 0.97 La 0.03 Pd 3 journal May 1996
Thermal conductivity of R B 6 ( R = C e , P r , N d , S m , G d ) single crystals journal August 1996
Impurity-induced localization of quasiparticles in the presence of a pseudogap in CeNiSn journal June 1999
Low-energy electrodynamics of SmB 6 journal January 1999
Collapse of the coherence gap in Kondo semiconductors journal December 2003
Orbital magnetic field effects in spin liquid with spinon Fermi sea: Possible application to κ − ( ET ) 2 Cu 2 ( C N ) 3 journal April 2006
Theory of topological Kondo insulators journal January 2012
Surface and bulk electronic structure of the strongly correlated system SmB 6 and implications for a topological Kondo insulator journal September 2013
Low-temperature surface conduction in the Kondo insulator SmB 6 journal November 2013
Strongly interacting Dirac liquid on the surface of a topological Kondo insulator journal August 2014
Surface theory of a family of topological Kondo insulators journal October 2014
In-gap collective mode spectrum of the topological Kondo insulator SmB 6 journal November 2014
Two-dimensional heavy fermions on the strongly correlated boundaries of Kondo topological insulators journal December 2014
Magnetotransport measurements of the surface states of samarium hexaboride using Corbino structures journal September 2015
Breakdown of the Kondo insulating state in SmB 6 by introducing Sm vacancies journal August 2016
Chemical potential asymmetry and quantum oscillations in insulators journal September 2016
Anomalous three-dimensional bulk ac conduction within the Kondo gap of SmB 6 single crystals journal October 2016
Effects of spin excitons on the surface states of SmB 6 : A photoemission study journal December 2016
Suppression of magnetic excitations near the surface of the topological Kondo insulator SmB 6 journal January 2017
Theory of quantum oscillations of magnetization in Kondo insulators journal August 2017
Critical examination of quantum oscillations in SmB 6 journal November 2017
Quantum oscillations in insulators with neutral Fermi surfaces journal January 2018
Modification of the Lifshitz-Kosevich formula for anomalous de Haas–van Alphen oscillations in inverted insulators journal March 2018
Field-dependent heat transport in the Kondo insulator SmB 6 : Phonons scattered by magnetic impurities journal June 2018
Magnetic dichroism in the Kondo insulator SmB 6 journal January 2019
Topological Kondo Insulators journal March 2010
Interaction Driven Subgap Spin Exciton in the Kondo Insulator SmB 6 journal January 2015
Quantum Oscillations without a Fermi Surface and the Anomalous de Haas–van Alphen Effect journal September 2015
Kondo Breakdown and Quantum Oscillations in SmB 6 journal January 2016
Quantum Oscillation in Narrow-Gap Topological Insulators journal January 2016
Bulk Fermi Surface of Charge-Neutral Excitations in SmB 6 or Not: A Heat-Transport Study journal June 2016
Excitons in topological Kondo insulators: Theory of thermodynamic and transport anomalies in SmB 6 journal March 2017
Skyrme Insulators: Insulators at the Brink of Superconductivity journal August 2017
Quantum Oscillation from In-Gap States and a Non-Hermitian Landau Level Problem journal July 2018
Highly Asymmetric Nodal Semimetal in Bulk SmB 6 journal July 2018
Scaling Theory of the Asymmetric Anderson Model journal February 1978
Diagonalization of the Kondo Hamiltonian journal August 1980
Thermodynamic Properties of the Anderson Model journal April 1983
Hybridization, Inter-Ion Correlation, and Surface States in the Kondo Insulator SmB 6 journal February 2013
Correlation between Bulk Thermodynamic Measurements and the Low-Temperature-Resistance Plateau in SmB 6 journal July 2014
Bulk Rotational Symmetry Breaking in Kondo Insulator SmB 6 journal September 2017
Electron scattering on magnetic impurities in metals and anomalous resistivity effects journal September 1965
Influence of impurity ferromagnetism and of the external magnetic field on the resistance of a metal with magnetic impurities journal October 1965
The renormalization group: Critical phenomena and the Kondo problem journal October 1975
Solution of the Kondo problem journal April 1983
Dynamical mean-field theory of strongly correlated fermion systems and the limit of infinite dimensions journal January 1996
Two-dimensional Fermi surfaces in Kondo insulator SmB 6 journal December 2014
Unconventional Fermi surface in an insulating state journal July 2015
Quantum oscillations of electrical resistivity in an insulator journal August 2018
Magnetic excitations in systems with a nonmagnetic ground state and valence fluctuations journal August 2010
A new exotic state in an old material: a tale of SmB6 journal September 2013
Numerical Renormalization Group Study of Magnetic Impurities in Superconductors journal September 1992
1/ N and Quantum Monte Carlo Studies of a Magnetic Impurity in an Insulator with a Small Gap journal October 1992
Magnetic Impurity in Insulators with Small Energy Gap journal December 1993
Resistance Minimum in Dilute Magnetic Alloys journal July 1964

Similar Records

Screened moments and extrinsic in-gap states in samarium hexaboride
Journal Article · Wed Apr 18 00:00:00 EDT 2018 · Nature Communications · OSTI ID:1529934

Emergent mystery in the Kondo insulator samarium hexaboride
Journal Article · Wed Aug 05 00:00:00 EDT 2020 · Nature Reviews Physics · OSTI ID:1649780

Magnetic dichroism in the Kondo insulator SmB6
Journal Article · Tue Jan 08 23:00:00 EST 2019 · Physical Review B · OSTI ID:1505147