Review—The Lithiation/Delithiation Behavior of Si-Based Electrodes: A Connection between Electrochemistry and Mechanics

Kim, Minkyu; Yang, Zhenzhen; Bloom, Ira

doi:10.1149/1945-7111/abd56f

Title: Review—The Lithiation/Delithiation Behavior of Si-Based Electrodes: A Connection between Electrochemistry and Mechanics

Journal Article · Thu Jan 14 00:00:00 EST 2021 · Journal of the Electrochemical Society (Online)

DOI:https://doi.org/10.1149/1945-7111/abd56f· OSTI ID:1775079

^[1]; Yang, Zhenzhen ^[1]; Bloom, Ira ^[1]

Argonne National Lab. (ANL), Lemont, IL (United States)

Silicon is a promising alternative anode material to graphite because of its high gravimetric and volumetric energy densities. However, severe capacity fading is observed in Si electrodes, and it is a result of mechanical changes of Si, such as volume changes, stress or fracture. Furthermore, these mechanical behaviors are strongly coupled with the electrochemistry of the Li-Si alloying reaction in Si-based electrodes, including both thermodynamics and kinetics. Therefore, the electrochemical properties of Si-based electrodes are strongly dependent on the control of the mechanics of Si during lithiation/delithiation. As such, it is very important to understand the correlation between electrochemistry and mechanics. Here, we review lithiation/delithiation behaviors of various types of Si-based electrodes, applying a fundamental understanding of electrochemistry and mechanics and the correlation between them.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1775079

Journal Information:: Journal of the Electrochemical Society (Online), Vol. 168, Issue 1; ISSN 1945-7111

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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Silicon nano-trees as high areal capacity anodes for lithium-ion batteries Leveau, Lucie; Laïk, Barbara; Pereira-Ramos, Jean-Pierre Journal of Power Sources, Vol. 316 https://doi.org/10.1016/j.jpowsour.2016.03.053	journal	June 2016
Size-dependent fracture of Si nanowire battery anodes Ryu, Ill; Choi, Jang Wook; Cui, Yi Journal of the Mechanics and Physics of Solids, Vol. 59, Issue 9 https://doi.org/10.1016/j.jmps.2011.06.003	journal	September 2011
Reaction of Li with Alloy Thin Films Studied by In Situ AFM Beaulieu, L. Y.; Hatchard, T. D.; Bonakdarpour, A. Journal of The Electrochemical Society, Vol. 150, Issue 11 https://doi.org/10.1149/1.1613668	journal	January 2003
Solid-State NMR and Electrochemical Dilatometry Study on Li[sup +] Uptake/Extraction Mechanism in SiO Electrode Kim, Taeahn; Park, Sangjin; Oh, Seung M. Journal of The Electrochemical Society, Vol. 154, Issue 12 https://doi.org/10.1149/1.2790282	journal	January 2007

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