Energetics of Ag Adsorption on and Adhesion to Rutile TiO2(100) Studied by Microcalorimetry

Mao, Zhongtian; Rumptz, John R.; Campbell, Charles T.

doi:10.1021/acs.jpcc.0c10504

Energetics of Ag Adsorption on and Adhesion to Rutile TiO₂(100) Studied by Microcalorimetry

Journal Article · Mon Feb 01 00:00:00 EST 2021 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.0c10504· OSTI ID:1774922

^[1]; Rumptz, John R. ^[2]; ^[2]

Univ. of Washington, Seattle, WA (United States); University of Washington
Univ. of Washington, Seattle, WA (United States)

The adsorption and adhesion energies of vapor-deposited Ag on rutile TiO₂(100) films have been measured using single crystal adsorption calorimetry (SCAC) and He⁺ low energy ion scattering spectroscopy (LEIS). Ag grows as three-dimensional (3D) nanoparticles at 300 and 100 K. The saturation particle density is 8 × 10¹⁶ particles/m² at 300 K and 2.5 × 10¹⁷ particles/m² at 100 K. The differential heat of adsorption starts low, increases with Ag coverage, and finally approaches the sublimation enthalpy of Ag at both 300 and 100 K. At 300 K, the differential heat of adsorption starts from 208 kJ/mol and rises rapidly to 265 kJ/mol by 1 ML. At 100 K, Ag grows nanoparticles with smaller particle size on the terraces, while at 300 K, the Ag nanoparticles have bigger particle size and grow on step edges with stronger binding strength to the nanoparticles. Thus, the heat of Ag adsorption at 100 K starts at 141 kJ/mol (near the monomer size limit on terrace sites) and remains lower than that at 300 K until 1.5 ML. Here, the adhesion energy of Ag(solid) to rutile TiO₂(100) is found to be large (~2.44 J/m²), supporting a trend of decreasing adhesion energy with the enthalpy of oxide reduction.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Washington, Seattle, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: FG02-96ER14630

OSTI ID:: 1774922

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 5 Vol. 125; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (88)

Active Oxygen on a Au/TiO2 Catalyst: Formation, Stability, and CO Oxidation Activity Widmann, Daniel; Behm, R. Jürgen Angewandte Chemie International Edition, Vol. 50, Issue 43 https://doi.org/10.1002/anie.201102062	journal	July 2011
Dry Reforming of Methane on a Highly-Active Ni-CeO ₂ Catalyst: Effects of Metal-Support Interactions on C−H Bond Breaking Liu, Zongyuan; Grinter, David C.; Lustemberg, Pablo G. Angewandte Chemie International Edition, Vol. 55, Issue 26 https://doi.org/10.1002/anie.201602489	journal	May 2016
In Situ Investigation of Methane Dry Reforming on Metal/Ceria(111) Surfaces: Metal-Support Interactions and C−H Bond Activation at Low Temperature Liu, Zongyuan; Lustemberg, Pablo; Gutiérrez, Ramón A. Angewandte Chemie International Edition, Vol. 56, Issue 42 https://doi.org/10.1002/anie.201707538	journal	September 2017
Electron inelastic mean free path for Ti, TiC, TiN and TiO2 as determined by quantitative reflection electron energy-loss spectroscopy Fuentes, G. G.; Elizalde, E.; Yubero, F. Surface and Interface Analysis, Vol. 33, Issue 3 https://doi.org/10.1002/sia.1205	journal	January 2002
Growth of Ag and Au Nanoparticles on Reduced and Oxidized Rutile TiO2(110) Surfaces Lira, Estephania; Hansen, Jonas Ø.; Merte, Lindsay R. Topics in Catalysis, Vol. 56, Issue 15-17 https://doi.org/10.1007/s11244-013-0141-z	journal	July 2013
Large scale photochemical synthesis of M@TiO2 nanocomposites (M = Ag, Pd, Au, Pt) and their optical properties, CO oxidation performance, and antibacterial effect Chen, Shao Feng; Li, Jian Ping; Qian, Kun Nano Research, Vol. 3, Issue 4 https://doi.org/10.1007/s12274-010-1027-z	journal	March 2010
Molecular beam investigation of adsorption kinetics on bulk metal targets: Nitrogen on tungsten King, David A.; Wells, Michael G. Surface Science, Vol. 29, Issue 2 https://doi.org/10.1016/0039-6028(72)90232-4	journal	February 1972
Atomic processes in crystal growth Venables, John A. Surface Science, Vol. 299-300, p. 798-817 https://doi.org/10.1016/0039-6028(94)90698-x	journal	January 1994
Ultrathin metal film growth on TiO2(110): an overview Diebold, Ulrike; Pan, Jian-Mei; Madey, Theodore E. Surface Science, Vol. 331-333 https://doi.org/10.1016/0039-6028(95)00124-7	journal	July 1995
Titanium and reduced titania overlayers on titanium dioxide(110) Mayer, J. T.; Diebold, U.; Madey, T. E. Journal of Electron Spectroscopy and Related Phenomena, Vol. 73, Issue 1 https://doi.org/10.1016/0368-2048(94)02258-5	journal	May 1995
A mechanism for enhanced photocatalytic activity of silver-loaded titanium dioxide Liu, S. X.; Qu, Z. P.; Han, X. W. Catalysis Today, Vol. 93-95 https://doi.org/10.1016/j.cattod.2004.06.097	journal	September 2004
Deactivation of cobalt based Fischer–Tropsch catalysts: A review Tsakoumis, Nikolaos E.; Rønning, Magnus; Borg, Øyvind Catalysis Today, Vol. 154, Issue 3-4 https://doi.org/10.1016/j.cattod.2010.02.077	journal	September 2010
Morphological transformations during Fischer-Tropsch synthesis on a titania-supported cobalt catalyst Kliewer, C. E.; Soled, S. L.; Kiss, G. Catalysis Today, Vol. 323 https://doi.org/10.1016/j.cattod.2018.05.021	journal	February 2019
Photocatalytic activity of TiO2 nanotube layers loaded with Ag and Au nanoparticles Paramasivam, I.; Macak, J. M.; Schmuki, P. Electrochemistry Communications, Vol. 10, Issue 1 https://doi.org/10.1016/j.elecom.2007.11.001	journal	January 2008
High photocatalytic activity and selectivity for nitrogen in nitrate reduction on Ag/TiO catalyst with fine silver clusters Zhang, F.; Jin, R.; Chen, J. Journal of Catalysis, Vol. 232, Issue 2 https://doi.org/10.1016/j.jcat.2005.04.014	journal	June 2005
Deactivation of Ni catalysts during methane autothermal reforming with CO2 and O2 in a fluidized-bed reactor Hou, Z.; Gao, J.; Guo, J. Journal of Catalysis, Vol. 250, Issue 2 https://doi.org/10.1016/j.jcat.2007.06.023	journal	September 2007
Hydrogen production by photocatalytic steam reforming of methanol on noble metal-modified TiO2 Chiarello, Gian Luca; Aguirre, Myriam H.; Selli, Elena Journal of Catalysis, Vol. 273, Issue 2 https://doi.org/10.1016/j.jcat.2010.05.012	journal	July 2010
From the Sabatier principle to a predictive theory of transition-metal heterogeneous catalysis Medford, Andrew J.; Vojvodic, Aleksandra; Hummelshøj, Jens S. Journal of Catalysis, Vol. 328 https://doi.org/10.1016/j.jcat.2014.12.033	journal	August 2015
Calorimetric metal vapor adsorption energies for characterizing industrial catalyst support materials Zhang, Wei; Campbell, Charles T. Journal of Catalysis, Vol. 392 https://doi.org/10.1016/j.jcat.2020.09.022	journal	December 2020
Oxygen reduction reactions in the SOFC cathode of Ag/CeO2 Wang, J.; Liu, M.; Lin, M. Solid State Ionics, Vol. 177, Issue 9-10 https://doi.org/10.1016/j.ssi.2006.02.029	journal	March 2006
Surface chemistry of Au/TiO2: Thermally and photolytically activated reactions Panayotov, Dimitar A.; Morris, John R. Surface Science Reports, Vol. 71, Issue 1 https://doi.org/10.1016/j.surfrep.2016.01.002	journal	March 2016
Oxygen vacancies on TiO2(110) and their interaction with H2O and O2: A combined high-resolution STM and DFT study Wendt, S.; Schaub, R.; Matthiesen, J. Surface Science, Vol. 598, Issue 1-3 https://doi.org/10.1016/j.susc.2005.08.041	journal	December 2005
Ion scattering spectroscopy intensities for supported nanoparticles: The hemispherical cap model Campbell, Charles T.; James, Trevor E. Surface Science, Vol. 641 https://doi.org/10.1016/j.susc.2015.06.013	journal	November 2015
Quantum chemical study of adsorption of Ag2, Ag4 and Ag8 on stoichiometric TiO2 (110) surface Mazheika, Aliaksei S.; Matulis, Vitaly E.; Ivashkevich, Oleg A. Journal of Molecular Structure: THEOCHEM, Vol. 942, Issue 1-3 https://doi.org/10.1016/j.theochem.2009.11.032	journal	February 2010
Small, uniform, and thermally stable silver particles on TiO2(110)-(1×1) Chen, D. A.; Bartelt, M. C.; Seutter, S. M. Surface Science, Vol. 464, Issue 1 https://doi.org/10.1016/s0039-6028(00)00700-7	journal	September 2000
Cu, Ag, and Au atoms adsorbed on TiO2(110): cluster and periodic calculations Giordano, Livia; Pacchioni, Gianfranco; Bredow, Thomas Surface Science, Vol. 471, Issue 1-3 https://doi.org/10.1016/s0039-6028(00)00879-7	journal	January 2001
Synthesis and characterization of titania films on Mo(110) Lai, X.; Guo, Q.; Min, B. K. Surface Science, Vol. 487, Issue 1-3 https://doi.org/10.1016/s0039-6028(01)01094-9	journal	July 2001
High resolution scanning tunnelling microscopy of the rutile TiO2(110) surface Tanner, R. E.; Castell, M. R.; Briggs, G. A. D. Surface Science, Vol. 412-413 https://doi.org/10.1016/s0039-6028(98)00464-6	journal	September 1998
Titanium oxide films grown on Mo(110) Guo, Q.; Oh, W. S.; Goodman, D. W. Surface Science, Vol. 437, Issue 1-2 https://doi.org/10.1016/s0039-6028(99)00678-0	journal	August 1999
Initial growth and morphology of thin Au films on TiO2(110) Zhang, Lei; Cosandey, Frederic; Persaud, Rajendra Surface Science, Vol. 439, Issue 1-3 https://doi.org/10.1016/s0039-6028(99)00734-7	journal	September 1999
Scanning tunneling microscopy studies of metal clusters supported on TiO2 (110): Morphology and electronic structure Lai, X.; Clair, T. P. St.; Valden, M. Progress in Surface Science, Vol. 59, Issue 1-4 https://doi.org/10.1016/s0079-6816(98)00034-3	journal	September 1998
The surface science of titanium dioxide Diebold, Ulrike Surface Science Reports, Vol. 48, Issue 5-8 https://doi.org/10.1016/s0167-5729(02)00100-0	journal	January 2003
Ultrathin metal films and particles on oxide surfaces: structural, electronic and chemisorptive properties Campbell, Charles T. Surface Science Reports, Vol. 27, Issue 1-3 https://doi.org/10.1016/s0167-5729(96)00011-8	journal	January 1997
Kinetics of heterogeneous catalytic reactions: Analysis of reaction schemes Cortright, R. D.; Dumesic, J. A. Advances in Catalysis https://doi.org/10.1016/s0360-0564(02)46023-3	book	March 2001
High temperature partial oxidation reactions over silver catalysts Nagy, Anton; Mestl, Gerhard Applied Catalysis A: General, Vol. 188, Issue 1-2 https://doi.org/10.1016/s0926-860x(99)00246-x	journal	November 1999
Energetics and Structure of Nickel Atoms and Nanoparticles on MgO(100) Mao, Zhongtian; Zhao, Wei; Al-Mualem, Ziareena A. The Journal of Physical Chemistry C, Vol. 124, Issue 27 https://doi.org/10.1021/acs.jpcc.0c03468	journal	June 2020
Energetics of Cu Adsorption and Adhesion onto Reduced CeO ₂ (111) Surfaces by Calorimetry James, Trevor E.; Hemmingson, Stephanie L.; Ito, Tsuyoshi The Journal of Physical Chemistry C, Vol. 119, Issue 30 https://doi.org/10.1021/acs.jpcc.5b04621	journal	July 2015
Adsorption and Adhesion of Au on Reduced CeO ₂ (111) Surfaces at 300 and 100 K Hemmingson, Stephanie L.; James, Trevor E.; Feeley, Gabriel M. The Journal of Physical Chemistry C, Vol. 120, Issue 22 https://doi.org/10.1021/acs.jpcc.6b03789	journal	May 2016
Configurational Energies of Nanoparticles Based on Metal–Metal Coordination Roling, Luke T.; Li, Lin; Abild-Pedersen, Frank The Journal of Physical Chemistry C, Vol. 121, Issue 41 https://doi.org/10.1021/acs.jpcc.7b08438	journal	October 2017
Ni Nanoparticles on CeO ₂ (111): Energetics, Electron Transfer, and Structure by Ni Adsorption Calorimetry, Spectroscopies, and Density Functional Theory Mao, Zhongtian; Lustemberg, Pablo G.; Rumptz, John R. ACS Catalysis, Vol. 10, Issue 9 https://doi.org/10.1021/acscatal.0c00333	journal	April 2020
Energy of Supported Metal Catalysts: From Single Atoms to Large Metal Nanoparticles James, Trevor E.; Hemmingson, Stephanie L.; Campbell, Charles T. ACS Catalysis, Vol. 5, Issue 10 https://doi.org/10.1021/acscatal.5b01372	journal	September 2015
Chemical Potential of Metal Atoms in Supported Nanoparticles: Dependence upon Particle Size and Support Campbell, Charles T.; Mao, Zhongtian ACS Catalysis, Vol. 7, Issue 12 https://doi.org/10.1021/acscatal.7b03090	journal	November 2017
Trends in Adhesion Energies of Metal Nanoparticles on Oxide Surfaces: Understanding Support Effects in Catalysis and Nanotechnology Hemmingson, Stephanie L.; Campbell, Charles T. ACS Nano, Vol. 11, Issue 2 https://doi.org/10.1021/acsnano.6b07502	journal	January 2017
Sintering of Catalytic Nanoparticles: Particle Migration or Ostwald Ripening? Hansen, Thomas W.; DeLaRiva, Andrew T.; Challa, Sivakumar R. Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar3002427	journal	April 2013
Insights into Catalytic Oxidation at the Au/TiO ₂ Dual Perimeter Sites Green, Isabel X.; Tang, Wenjie; Neurock, Matthew Accounts of Chemical Research, Vol. 47, Issue 3 https://doi.org/10.1021/ar400196f	journal	December 2013
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results Linsebigler, Amy L.; Lu, Guangquan.; Yates, John T. Chemical Reviews, Vol. 95, Issue 3 https://doi.org/10.1021/cr00035a013	journal	May 1995
Structure of Clean and Adsorbate-Covered Single-Crystal Rutile TiO ₂ Surfaces Pang, Chi Lun; Lindsay, Robert; Thornton, Geoff Chemical Reviews, Vol. 113, Issue 6 https://doi.org/10.1021/cr300409r	journal	December 2012
Understanding TiO ₂ Photocatalysis: Mechanisms and Materials Schneider, Jenny; Matsuoka, Masaya; Takeuchi, Masato Chemical Reviews, Vol. 114, Issue 19 https://doi.org/10.1021/cr5001892	journal	May 2014
Photocatalytic H ₂ O ₂ Production from Ethanol/O ₂ System Using TiO ₂ Loaded with Au–Ag Bimetallic Alloy Nanoparticles Tsukamoto, Daijiro; Shiro, Akimitsu; Shiraishi, Yasuhiro ACS Catalysis, Vol. 2, Issue 4 https://doi.org/10.1021/cs2006873	journal	March 2012
Metal Adsorption and Adhesion Energies on MgO(100) Campbell, Charles T.; Starr, David E. Journal of the American Chemical Society, Vol. 124, Issue 31 https://doi.org/10.1021/ja020146t	journal	August 2002
Adsorption of Water on Reconstructed Rutile TiO ₂ (011)-(2×1): TiO Double Bonds and Surface Reactivity Di Valentin, Cristiana; Tilocca, Antonio; Selloni, Annabella Journal of the American Chemical Society, Vol. 127, Issue 27 https://doi.org/10.1021/ja0511624	journal	July 2005
Size and Support Effects for the Water–Gas Shift Catalysis over Gold Nanoparticles Supported on Model Al ₂ O ₃ and TiO ₂ Shekhar, Mayank; Wang, Jun; Lee, Wen-Sheng Journal of the American Chemical Society, Vol. 134, Issue 10 https://doi.org/10.1021/ja210083d	journal	February 2012
Silver Adsorption on Calcium Niobate(001) Nanosheets: Calorimetric Energies That Explain Sinter-Resistant Support Zhang, Wei; Uppuluri, Ritesh; Mallouk, Thomas E. Journal of the American Chemical Society, Vol. 142, Issue 37 https://doi.org/10.1021/jacs.0c05044	journal	August 2020
Thermal Stability of Au Nanoparticles in O ₂ and Air on Fully Oxidized TiO ₂ (110) Substrates at Elevated Pressures. An AFM/XPS Study of Au/TiO ₂ Model Systems Kielbassa, S.; Kinne, M.; Behm, R. J. The Journal of Physical Chemistry B, Vol. 108, Issue 50 https://doi.org/10.1021/jp048547d	journal	December 2004
Structural Properties of Ag/TiO ₂ Catalysts for Acrolein Hydrogenation Grünert, Wolfgang; Brückner, Angelika; Hofmeister, Herbert The Journal of Physical Chemistry B, Vol. 108, Issue 18 https://doi.org/10.1021/jp049855e	journal	May 2004
Ag/AgBr/TiO ₂ Visible Light Photocatalyst for Destruction of Azodyes and Bacteria Hu, Chun; Lan, Yongqing; Qu, Jiuhui The Journal of Physical Chemistry B, Vol. 110, Issue 9 https://doi.org/10.1021/jp0564400	journal	March 2006
Ag Adsorption on Reduced CeO ₂ (111) Thin Films Farmer, Jason A.; Baricuatro, Jack H.; Campbell, Charles T. The Journal of Physical Chemistry C, Vol. 114, Issue 40 https://doi.org/10.1021/jp104593y	journal	July 2010
Theoretical Study of Adsorption of Ag Clusters on the Anatase TiO ₂ (100) Surface Mazheika, Aliaksei S.; Bredow, Thomas; Matulis, Vitaly E. The Journal of Physical Chemistry C, Vol. 115, Issue 35 https://doi.org/10.1021/jp200575u	journal	August 2011
High Water−Gas Shift Activity in TiO ₂ (110) Supported Cu and Au Nanoparticles: Role of the Oxide and Metal Particle Size Rodríguez, José A.; Evans, Jaime; Graciani, Jesús The Journal of Physical Chemistry C, Vol. 113, Issue 17 https://doi.org/10.1021/jp900483u	journal	April 2009
Silver Growth on TiO ₂ (110) (1 × 1) and (1 × 2) ^† Luo, K.; St. Clair, T. P.; Lai, X. The Journal of Physical Chemistry B, Vol. 104, Issue 14 https://doi.org/10.1021/jp993062o	journal	April 2000
Oxygen-induced morphological changes of Ag nanoclusters supported on TiO2(110) Lai, Xiaofeng; St. Clair, Todd P.; Wayne Goodman, D. Faraday Discussions, Vol. 114 https://doi.org/10.1039/a902795e	journal	January 1999
Chemical reactions on rutile TiO2(110) Lun Pang, Chi; Lindsay, Robert; Thornton, Geoff Chemical Society Reviews, Vol. 37, Issue 10 https://doi.org/10.1039/b719085a	journal	January 2008
Adsorption of organic molecules on rutile TiO2 and anatase TiO2 single crystal surfaces Thomas, Andrew G.; Syres, Karen L. Chemical Society Reviews, Vol. 41, Issue 11 https://doi.org/10.1039/c2cs35057b	journal	January 2012
Anchored metal nanoparticles: Effects of support and size on their energy, sintering resistance and reactivity Campbell, Charles T.; Sellers, Jason R. V. Faraday Discussions, Vol. 162 https://doi.org/10.1039/c3fd00094j	journal	January 2013
Photocatalysis on supported gold and silver nanoparticles under ultraviolet and visible light irradiation Sarina, Sarina; Waclawik, Eric R.; Zhu, Huaiyong Green Chemistry, Vol. 15, Issue 7 https://doi.org/10.1039/c3gc40450a	journal	January 2013
Tuning the charge state of Ag and Au atoms and clusters deposited on oxide surfaces by doping: a DFT study of the adsorption properties of nitrogen- and niobium-doped TiO ₂ and ZrO ₂ Schlexer, Philomena; Ruiz Puigdollers, Antonio; Pacchioni, Gianfranco Physical Chemistry Chemical Physics, Vol. 17, Issue 34 https://doi.org/10.1039/c5cp03834k	journal	January 2015
Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO ₂ hydrogenation, and methane and alcohol reforming Rodriguez, José A.; Grinter, David C.; Liu, Zongyuan Chemical Society Reviews, Vol. 46, Issue 7 https://doi.org/10.1039/c6cs00863a	journal	January 2017
The physical chemistry and materials science behind sinter-resistant catalysts Dai, Yunqian; Lu, Ping; Cao, Zhenming Chemical Society Reviews, Vol. 47, Issue 12 https://doi.org/10.1039/c7cs00650k	journal	January 2018
A novel single-crystal adsorption calorimeter and additions for determining metal adsorption and adhesion energies Stuckless, J. T.; Frei, Nathan A.; Campbell, Charles T. Review of Scientific Instruments, Vol. 69, Issue 6 https://doi.org/10.1063/1.1148971	journal	June 1998
Adsorption calorimetry during metal vapor deposition on single crystal surfaces: Increased flux, reduced optical radiation, and real-time flux and reflectivity measurements Sellers, Jason R. V.; James, Trevor E.; Hemmingson, Stephanie L. Review of Scientific Instruments, Vol. 84, Issue 12 https://doi.org/10.1063/1.4832980	journal	December 2013
Adsorption energetics of Ag on MgO(100) Larsen, J. H.; Ranney, J. T.; Starr, D. E. Physical Review B, Vol. 63, Issue 19 https://doi.org/10.1103/physrevb.63.195410	journal	April 2001
Adsorption and diffusion of Pt and Au on the stoichiometric and reduced Ti O 2 rutile (110) surfaces Iddir, Hakim; Öğüt, Serdar; Browning, Nigel D. Physical Review B, Vol. 72, Issue 8 https://doi.org/10.1103/physrevb.72.081407	journal	August 2005
Kinetic model for sintering of supported metal particles with improved size-dependent energetics and applications to Au on TiO 2 ( 110 ) Parker, Stephen C.; Campbell, Charles T. Physical Review B, Vol. 75, Issue 3 https://doi.org/10.1103/physrevb.75.035430	journal	January 2007
Self-similarity during growth of the Au ∕ Ti O 2 ( 110 ) model catalyst as seen by the scattering of x-rays at grazing-angle incidence Lazzari, Rémi; Renaud, Gilles; Jupille, Jacques Physical Review B, Vol. 76, Issue 12 https://doi.org/10.1103/physrevb.76.125412	journal	September 2007
Density functional theory study of TiO 2 /Ag interfaces and their role in memristor devices Prada, Stefano; Rosa, Massimo; Giordano, Livia Physical Review B, Vol. 83, Issue 24 https://doi.org/10.1103/physrevb.83.245314	journal	June 2011
Two ( 1 × 2 ) Reconstructions of TiO 2 (110): Surface Rearrangement and Reactivity Studied Using Elevated Temperature Scanning Tunneling Microscopy Bennett, R. A.; Stone, P.; Price, N. J. Physical Review Letters, Vol. 82, Issue 19 https://doi.org/10.1103/physrevlett.82.3831	journal	May 1999
Bonding of Gold Nanoclusters to Oxygen Vacancies on Rutile T i O 2 ( 110 ) Wahlström, E.; Lopez, N.; Schaub, R. Physical Review Letters, Vol. 90, Issue 2 https://doi.org/10.1103/physrevlett.90.026101	journal	January 2003
Unfolding adsorption on metal nanoparticles: Connecting stability with catalysis Dean, James; Taylor, Michael G.; Mpourmpakis, Giannis Science Advances, Vol. 5, Issue 9 https://doi.org/10.1126/sciadv.aax5101	journal	September 2019
Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides Asahi, R. Science, Vol. 293, Issue 5528 https://doi.org/10.1126/science.1061051	journal	July 2001
Efficient Photochemical Water Splitting by a Chemically Modified n-TiO2 Khan, S. U. M. Science, Vol. 297, Issue 5590 https://doi.org/10.1126/science.1075035	journal	September 2002
The Effect of Size-Dependent Nanoparticle Energetics on Catalyst Sintering Campbell, C. T. Science, Vol. 298, Issue 5594 https://doi.org/10.1126/science.1075094	journal	October 2002
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects Lei, Y.; Mehmood, F.; Lee, S. Science, Vol. 328, Issue 5975, p. 224-228 https://doi.org/10.1126/science.1185200	journal	April 2010
Ceria Maintains Smaller Metal Catalyst Particles by Strong Metal-Support Bonding Farmer, J. A.; Campbell, C. T. Science, Vol. 329, Issue 5994 https://doi.org/10.1126/science.1191778	journal	August 2010
Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties Valden, M. Science, Vol. 281, Issue 5383 https://doi.org/10.1126/science.281.5383.1647	journal	September 1998
Thermally stable single-atom platinum-on-ceria catalysts via atom trapping Jones, J.; Xiong, H.; DeLaRiva, A. T. Science, Vol. 353, Issue 6295 https://doi.org/10.1126/science.aaf8800	journal	July 2016
Active sites for CO ₂ hydrogenation to methanol on Cu/ZnO catalysts Kattel, Shyam; Ramírez, Pedro J.; Chen, Jingguang G. Science, Vol. 355, Issue 6331 https://doi.org/10.1126/science.aal3573	journal	March 2017
CRC Handbook of Chemistry and Physics Haynes, William M. CRC Press https://doi.org/10.1201/b17118	book	June 2014
Ni Nanoparticles on CeO2(111): Energetics, Electron Transfer and Structure by Ni Adsorption Calorimetry, Spectroscopies and DFT Zhongtian, Mao,; G., Lustemberg, Pablo; R., Rumptz, John Materials Cloud https://doi.org/10.24435/materialscloud:2020.0032/v1	dataset	January 2020

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