Heterometal incorporation in NH2-MIL-125(Ti) and its participation in the photoinduced charge-separated excited state

Hanna, Lauren; Long, Conor L.; Zhang, Xiaoyi; Lockard, Jenny V.

doi:10.1039/d0cc05339b

Heterometal incorporation in NH₂-MIL-125(Ti) and its participation in the photoinduced charge-separated excited state

Journal Article · Wed Aug 26 00:00:00 EDT 2020 · ChemComm

DOI:https://doi.org/10.1039/d0cc05339b· OSTI ID:1774328

Hanna, Lauren ^[1]; Long, Conor L. ^[1]; ^[2]; ^[1]

Rutgers Univ., New Brunswick, NJ (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Optical and X-ray spectroscopy studies reveal the location and role of Fe³⁺ sites incorporated through direct synthesis in NH₂-MIL-125(Ti). Fe K-edge XAS analysis confirms its metal–oxo cluster node coordination while time-resolved optical and X-ray transient absorption studies disclose its role as an electron trap site, promoting long-lived photo-induced charge separation in the framework. Notably, XTA measurements show sustained electron reduction of the Fe sites into the microsecond time range. Finally, comparison with an Fe-doped MOF generated through post-synthetic modification indicates that only the direct synthesis approach affords efficient Fe participation in the charge separated excited state.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; SC0012704

OSTI ID:: 1774328

Alternate ID(s):: OSTI ID: 1657302
OSTI ID: 1688379

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 78 Vol. 56; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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