Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Sub-diffractional cavity modes of terahertz hyperbolic phonon polaritons in tin oxide

Journal Article · · Nature Communications
Abstract

Hyperbolic phonon polaritons have recently attracted considerable attention in nanophotonics mostly due to their intrinsic strong electromagnetic field confinement, ultraslow polariton group velocities, and long lifetimes. Here we introduce tin oxide (SnO 2 ) nanobelts as a photonic platform for the transport of surface and volume phonon polaritons in the mid- to far-infrared frequency range. This report brings a comprehensive description of the polaritonic properties of SnO 2 as a nanometer-sized dielectric and also as an engineered material in the form of a waveguide. By combining accelerator-based IR-THz sources (synchrotron and free-electron laser) with s-SNOM, we employed nanoscale far-infrared hyper-spectral-imaging to uncover a Fabry–Perot cavity mechanism in SnO 2 nanobelts via direct detection of phonon-polariton standing waves. Our experimental findings are accurately supported by notable convergence between theory and numerical simulations. Thus, the SnO 2 is confirmed as a natural hyperbolic material with unique photonic properties essential for future applications involving subdiffractional light traffic and detection in the far-infrared range.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
BMBF; USDOE; USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1773527
Alternate ID(s):
OSTI ID: 1797733
Journal Information:
Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 12; ISSN 2041-1723
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United Kingdom
Language:
English

References (55)

Nanoscale Guiding of Infrared Light with Hyperbolic Volume and Surface Polaritons in van der Waals Material Ribbons journal January 2020
Probing Polaritons in 2D Materials with Synchrotron Infrared Nanospectroscopy journal December 2019
Mapping the near fields of plasmonic nanoantennas by scattering-type scanning near-field optical microscopy: Mapping the near fields of plasmonic nanoantennas journal November 2015
3D hopping conduction in SnO 2 nanobelts: 3D hopping conduction in SnO 2 nanobelts journal May 2012
Optical Properties of Crystalline and Amorphous Semiconductors book January 1999
Polar optical-mode scattering of electrons in SnO2 journal January 1968
Scanning probe optical microscopy using a metallic probe tip journal February 1995
Variations of the infrared powder spectra of TiO2 and SnO2 (rutile) with polarization journal January 1991
Enhanced dielectric contrast in scattering-type scanning near-field optical microscopy journal August 2000
Plasmons in graphene: Recent progress and applications journal November 2013
Hexagonal Boron Nitride Self-Launches Hyperbolic Phonon Polaritons journal May 2017
Efficient Energy Harvesting in SnO 2 -Based Dye-Sensitized Solar Cells Utilizing Nano-Amassed Mesoporous Zinc Oxide Hollow Microspheres as Synergy Boosters journal October 2018
Far Infrared Synchrotron Near-Field Nanoimaging and Nanospectroscopy journal December 2017
Photoluminescence and High-Temperature Persistent Photoconductivity Experiments in SnO 2 Nanobelts journal April 2013
Near-field probing of vibrational absorption for chemical microscopy journal May 1999
Coherent emission of light by thermal sources journal March 2002
Boron nitride nanoresonators for phonon-enhanced molecular vibrational spectroscopy at the strong coupling limit journal December 2017
Phonon-enhanced light–matter interaction at the nanometre scale journal July 2002
Nanoimaging of resonating hyperbolic polaritons in linear boron nitride antennas journal June 2017
Understanding materials challenges for rechargeable ion batteries with in situ transmission electron microscopy journal August 2017
Sub-diffractional volume-confined polaritons in the natural hyperbolic material hexagonal boron nitride journal October 2014
Hyperbolic phonon-polaritons in boron nitride for near-field optical imaging and focusing journal June 2015
Subwavelength-scale tailoring of surface phonon polaritons by focused ion-beam implantation journal August 2004
Polaritons in layered two-dimensional materials journal November 2016
Atomic-scale photonic hybrids for mid-infrared and terahertz nanophotonics journal January 2016
Naturally hyperbolic journal March 2015
Real-space mapping of tailored sheet and edge plasmons in graphene nanoresonators journal March 2016
In situ click chemistry generation of cyclooxygenase-2 inhibitors journal February 2017
Challenges and prospects of advanced oxidation water treatment processes using catalytic nanomaterials journal August 2018
In-plane anisotropic and ultra-low-loss polaritons in a natural van der Waals crystal journal October 2018
Ultrastructural Characterization of the Lower Motor System in a Mouse Model of Krabbe Disease journal December 2016
Ror2 signaling regulates Golgi structure and transport through IFT20 for tumor invasiveness journal January 2017
Improved recovery time and sensitivity to H2 and NH3 at room temperature with SnOx vertical nanopillars on ITO journal July 2018
Occurrence of the potent mutagens 2- nitrobenzanthrone and 3-nitrobenzanthrone in fine airborne particles journal January 2019
Dipole modelling for a robust description of subdiffractional polariton waves journal January 2019
Electrical observation of sub-band formation in SnO2 nanobelts journal January 2013
Narrow-band near-field nanoscopy in the spectral range from 1.3 to 8.5 THz journal March 2016
Phonon-induced near-field resonances in multiferroic BiFeO 3 thin films at infrared and THz wavelengths journal February 2020
Ultrabroadband infrared nanospectroscopic imaging journal May 2014
Metal-to-insulator transition induced by UV illumination in a single SnO 2 nanobelt journal October 2017
Polarization-dependent near-field phonon nanoscopy of oxides: SrTiO 3 ,   LiNbO 3 , and PbZr 0.2 Ti 0.8 O 3 journal July 2019
Topological insulators are tunable waveguides for hyperbolic polaritons journal November 2015
Complex Optical Constants on a Subwavelength Scale journal October 2000
FELBE -Upgrades and Status of the IRlTHz FEL User Facility at HZDR
  • Klopf, J. Michael; Zvyagin, Sergei; Helm, Manfred
  • 2018 43rd International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz 2018), 2018 43rd International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz) https://doi.org/10.1109/IRMMW-THz.2018.8510402
conference September 2018
Ultra-confined mid-infrared resonant phonon polaritons in van der Waals nanostructures journal June 2018
Nanoribbon Waveguides for Subwavelength Photonics Integration journal August 2004
In Situ Observation of the Electrochemical Lithiation of a Single SnO2 Nanowire Electrode journal December 2010
Tunable Phonon Polaritons in Atomically Thin van der Waals Crystals of Boron Nitride journal March 2014
Scanning Interferometric Apertureless Microscopy: Optical Imaging at 10 Angstrom Resolution journal August 1995
Physical Properties of SnO[sub 2] Materials journal January 1976
Near-field imaging and nano-Fourier-transform infrared spectroscopy using broadband synchrotron radiation journal January 2013
Fabry-Perot description for Mie resonances of rectangular dielectric nanowire optical resonators journal January 2016
Low-aberration beamline optics for synchrotron infrared nanospectroscopy journal January 2018
Low-loss, infrared and terahertz nanophotonics using surface phonon polaritons journal January 2015
Optical and Electrical Properties of Nanocrystalline SnO2 Thin Films Synthesized by Chemical Bath Deposition Method journal January 2015

Similar Records

Ultrabroadband Nanocavity of Hyperbolic Phonon–Polaritons in 1D-Like α-MoO3
Journal Article · Wed Sep 08 20:00:00 EDT 2021 · ACS Photonics · OSTI ID:1834589

Ultraconfined terahertz phonon polaritons in hafnium dichalcogenides
Journal Article · Sun Sep 14 20:00:00 EDT 2025 · Nature Materials · OSTI ID:3004294