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Thermodynamic Models for Highly Charged Aqueous Species: Solubility of Th(IV) Hydrous Oxide in Concentrated NaHCO3 and Na2CO3 Solutions

Journal Article · · Journal of Solution Chemistry
DOI:https://doi.org/10.1007/BF02767996· OSTI ID:1773372

An aqueous thermodynamic model is proposed to describe the solubility ofTh(IV) hydrous oxide in the aqueous Na+-HCO -3-CO 2-3-OH--ClO -4-H2O system extending to high concentration at 25‡C.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1773372
Report Number(s):
PNNL-SA-28491
Journal Information:
Journal of Solution Chemistry, Journal Name: Journal of Solution Chemistry Journal Issue: 3 Vol. 26
Country of Publication:
United States
Language:
English

References (11)

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The Solubility of Th(IV) and U(IV) Hydrous Oxides in Concentrated Nahco 3 and Na 2 Co 3 Solutions journal January 1994
Etude structurale des carbonates complexes de cérium et de thorium. II. Structure cristalline et moléculaire du pentacarbonatothorate de guanidine tétrahydraté, [C(NH 2 ) 3 ] 6 [Th(CO 3 ) 5 ].4H 2 O journal November 1975
The prediction of mineral solubilities in natural waters: The Na-K-Mg-Ca-H-Cl-SO4-OH-HCO3-CO3-CO2-H2O system to high ionic strengths at 25°C journal April 1984
High-order multiple-scattering calculations of x-ray-absorption fine structure journal December 1992
Thermodynamics of electrolytes. V. effects of higher-order electrostatic terms journal March 1975
Thermodynamics of electrolytes. I. Theoretical basis and general equations journal January 1973
Multiple-scattering calculations of x-ray-absorption spectra journal July 1995

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