ToF-SIMS characterization of glyoxal surface oxidation products by hydrogen peroxide: A comparison between dry and liquid samples

Sui, Xiao; Zhou, Yufan; Zhang, Fei; Zhang, Yanyan; Chen, Jianmin; Zhu, Zihua; Yu, Xiao-Ying

doi:10.1002/sia.6334

ToF-SIMS characterization of glyoxal surface oxidation products by hydrogen peroxide: A comparison between dry and liquid samples

Journal Article · Mon Oct 01 04:00:00 EDT 2018 · Surface and Interface Analysis

DOI:https://doi.org/10.1002/sia.6334· OSTI ID:1773358

Sui, Xiao ^[1]; Zhou, Yufan ^[1]; Zhang, Fei ^[2]; Zhang, Yanyan ^[3]; Chen, Jianmin ^[4]; ^[3]; ^[3]

UNIVERSITY PROGRAMS
FUDAN UNIVERSITY
BATTELLE (PACIFIC NW LAB)
Fudan University

As one of the simplest volatile organic compounds (VOCs), glyoxal and its oxidation products were considered to be important precursors to aqueous secondary organic aerosol (aqSOA) formation. Herein, we analyzed products from glyoxal oxidation by hydrogen peroxide in dry and liquid samples using time-of-flight secondary ion mass spectrometry (ToF-SIMS). ToF-SIMS spectra and spectral principal component analysis (PCA) were used to investigate surface oxidation products. Dry samples were prepared on clean silicon wafers. Liquid samples consisting of glyoxal and hydrogen peroxide (H2O2) were introduced to a vacuum compatible microfluidic reactor prior to UV illumination or dark aging followed by in situ liquid SIMS analysis. A number of reaction products were observed in both dry and liquid samples; different oligomers and carboxylic acids could be formed depending on reaction conditions. In addition, hydrolyzed products were observed in the liquid samples, but not in the dry samples. Although dry samples reveal some products of the aqueous process, they are not fully representative as results from those of the aqueous samples. Our findings suggest that the ability to characterize the liquid surface reaction products provides more realistic information of the reaction products associated with aqSOA formation in the atmosphere. Meanwhile, the high mass resolution spectra from the dry sample SIMS measurement are helpful to identify oxidation products in the liquid samples.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1773358

Report Number(s):: PNNL-SA-129566

Journal Information:: Surface and Interface Analysis, Journal Name: Surface and Interface Analysis Journal Issue: 10 Vol. 50

Country of Publication:: United States

Language:: English

References (39)

Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies Ervens, B.; Turpin, B. J.; Weber, R. J. Atmospheric Chemistry and Physics, Vol. 11, Issue 21 https://doi.org/10.5194/acp-11-11069-2011	journal	January 2011
Aqueous aerosol SOA formation: impact on aerosol physical properties Woo, Joseph L.; Kim, Derek D.; Schwier, Allison N. Faraday Discussions, Vol. 165 https://doi.org/10.1039/c3fd00032j	journal	January 2013
Aqueous Organic Chemistry in the Atmosphere: Sources and Chemical Processing of Organic Aerosols McNeill, V. Faye Environmental Science & Technology, Vol. 49, Issue 3 https://doi.org/10.1021/es5043707	journal	January 2015
Wavelengths of spectral lines in mercury pencil lamps Sansonetti, Craig J.; Salit, Marc L.; Reader, Joseph Applied Optics, Vol. 35, Issue 1 https://doi.org/10.1364/AO.35.000074	journal	January 1996
Glyoxal processing by aerosol multiphase chemistry: towards a kinetic modeling framework of secondary organic aerosol formation in aqueous particles Ervens, B.; Volkamer, R. Atmospheric Chemistry and Physics, Vol. 10, Issue 17 https://doi.org/10.5194/acp-10-8219-2010	journal	January 2010
Effects of Precursor Concentration and Acidic Sulfate in Aqueous Glyoxal−OH Radical Oxidation and Implications for Secondary Organic Aerosol Tan, Yi; Perri, Mark J.; Seitzinger, Sybil P. Environmental Science & Technology, Vol. 43, Issue 21 https://doi.org/10.1021/es901742f	journal	November 2009
O RGANIC A TMOSPHERIC P ARTICULATE M ATERIAL Seinfeld, John H.; Pankow, James F. Annual Review of Physical Chemistry, Vol. 54, Issue 1 https://doi.org/10.1146/annurev.physchem.54.011002.103756	journal	October 2003
Perspective: Water cluster mediated atmospheric chemistry Vaida, Veronica The Journal of Chemical Physics, Vol. 135, Issue 2 https://doi.org/10.1063/1.3608919	journal	July 2011
Why ozonolysis may not increase the hydrophilicity of particles McIntire, T. M.; Ryder, O. S.; Gassman, P. L. Atmospheric Environment, Vol. 44, Issue 7 https://doi.org/10.1016/j.atmosenv.2009.11.009	journal	March 2010
Imaging liquids using microfluidic cells Yu, Xiao-Ying; Liu, Bingwen; Yang, Li Microfluidics and Nanofluidics, Vol. 15, Issue 6 https://doi.org/10.1007/s10404-013-1199-4	journal	May 2013
Performance of a microfluidic device for in situ ToF-SIMS analysis of selected organic molecules at aqueous surfaces Yang, Li; Zhu, Zihua; Yu, Xiao-Ying Analytical Methods, Vol. 5, Issue 10 https://doi.org/10.1039/c3ay26513g	journal	January 2013
Secondary Organic Aerosol Formation by Glyoxal Hydration and Oligomer Formation: Humidity Effects and Equilibrium Shifts during Analysis Hastings, William P.; Koehler, Charles A.; Bailey, Earl L. Environmental Science & Technology, Vol. 39, Issue 22 https://doi.org/10.1021/es050446l	journal	November 2005
Time-of-flight secondary ion mass spectrometry: techniques and applications for the characterization of biomaterial surfaces Belu, Anna M.; Graham, Daniel J.; Castner, David G. Biomaterials, Vol. 24, Issue 21 https://doi.org/10.1016/S0142-9612(03)00159-5	journal	September 2003
In situ chemical probing of the electrode–electrolyte interface by ToF-SIMS Liu, Bingwen; Yu, Xiao-Ying; Zhu, Zihua Lab Chip, Vol. 14, Issue 5 https://doi.org/10.1039/C3LC50971K	journal	January 2014
Analysis of organic and inorganic species on the surface of atmospheric aerosol using time-of-flight secondary ion mass spectrometry (TOF-SIMS) Peterson, Richard E.; Tyler, Bonnie J. Atmospheric Environment, Vol. 36, Issue 39-40 https://doi.org/10.1016/S1352-2310(02)00686-6	journal	December 2002
Uptake Rate Measurements of Methanesulfonic Acid and Glyoxal by Aqueous Droplets Schweitzer, Francis; Magi, Laurent; Mirabel, Philippe The Journal of Physical Chemistry A, Vol. 102, Issue 3 https://doi.org/10.1021/jp972451k	journal	January 1998
Capturing the transient species at the electrode–electrolyte interface by in situ dynamic molecular imaging Yu, Jiachao; Zhou, Yufan; Hua, Xin Chemical Communications, Vol. 52, Issue 73 https://doi.org/10.1039/C6CC02893D	journal	January 2016
In situ molecular imaging of a hydrated biofilm in a microfluidic reactor by ToF-SIMS Hua, Xin; Yu, Xiao-Ying; Wang, Zhaoying The Analyst, Vol. 139, Issue 7 https://doi.org/10.1039/C3AN02262E	journal	January 2014
Multivariate analysis of ToF-SIMS data for biological applications Park, Ji-Won; Min, Hyegeun; Kim, Young-Pil Surface and Interface Analysis, Vol. 41, Issue 8 https://doi.org/10.1002/sia.3049	journal	August 2009
Improving the Molecular Ion Signal Intensity for In Situ Liquid SIMS Analysis Zhou, Yufan; Yao, Juan; Ding, Yuanzhao Journal of The American Society for Mass Spectrometry, Vol. 27, Issue 12 https://doi.org/10.1007/s13361-016-1478-x	journal	September 2016
Probing liquid surfaces under vacuum using SEM and ToF-SIMS Yang, Li; Yu, Xiao-Ying; Zhu, Zihua Lab on a Chip, Vol. 11, Issue 15 https://doi.org/10.1039/c0lc00676a	journal	January 2011
Aqueous chemistry and its role in secondary organic aerosol (SOA) formation Lim, Y. B.; Tan, Y.; Perri, M. J. Atmospheric Chemistry and Physics, Vol. 10, Issue 21 https://doi.org/10.5194/acp-10-10521-2010	journal	January 2010
Secondary organic aerosol production from aqueous photooxidation of glycolaldehyde: Laboratory experiments Perri, Mark J.; Seitzinger, Sybil; Turpin, Barbara J. Atmospheric Environment, Vol. 43, Issue 8 https://doi.org/10.1016/j.atmosenv.2008.11.037	journal	March 2009
Multiphase Chemistry of Glyoxal: Revised Kinetics of the Alkyl Radical Reaction with Molecular Oxygen and the Reaction of Glyoxal with OH, NO ₃ , and SO ₄ ^– in Aqueous Solution Schaefer, T.; van Pinxteren, D.; Herrmann, H. Environmental Science & Technology, Vol. 49, Issue 1 https://doi.org/10.1021/es505860s	journal	December 2014
Cluster TOF-SIMS imaging as a tool for micrometric histology of lipids in tissue: CLUSTER TOF-SIMS IMAGING Bich, Claudia; Touboul, David; Brunelle, Alain Mass Spectrometry Reviews, Vol. 33, Issue 6 https://doi.org/10.1002/mas.21399	journal	November 2013
TOF-SIMS: Accurate mass scale calibration Green, F. M.; Gilmore, I. S.; Seah, M. P. Journal of the American Society for Mass Spectrometry, Vol. 17, Issue 4 https://doi.org/10.1016/j.jasms.2005.12.005	journal	April 2006
Atmospheric oxalic acid and SOA production from glyoxal: Results of aqueous photooxidation experiments Carlton, Annmarie G.; Turpin, Barbara J.; Altieri, Katye E. Atmospheric Environment, Vol. 41, Issue 35 https://doi.org/10.1016/j.atmosenv.2007.05.035	journal	November 2007
Reactions at Interfaces As a Source of Sulfate Formation in Sea-Salt Particles Laskin, A. Science, Vol. 301, Issue 5631 https://doi.org/10.1126/science.1085374	journal	July 2003
In Situ Molecular Imaging of the Biofilm and Its Matrix Ding, Yuanzhao; Zhou, Yufan; Yao, Juan Analytical Chemistry, Vol. 88, Issue 22 https://doi.org/10.1021/acs.analchem.6b03909	journal	October 2016
Deciphering the aqueous chemistry of glyoxal oxidation with hydrogen peroxide using molecular imaging Sui, Xiao; Zhou, Yufan; Zhang, Fei Physical Chemistry Chemical Physics, Vol. 19, Issue 31 https://doi.org/10.1039/C7CP02071F	journal	January 2017
Secondary Ion Mass Spectrometry: Characterizing Complex Samples in Two and Three Dimensions Fletcher, John S.; Vickerman, John C. Analytical Chemistry, Vol. 85, Issue 2 https://doi.org/10.1021/ac303088m	journal	November 2012
Catechol Oxidation by Ozone and Hydroxyl Radicals at the Air–Water Interface Pillar, Elizabeth A.; Camm, Robert C.; Guzman, Marcelo I. Environmental Science & Technology, Vol. 48, Issue 24 https://doi.org/10.1021/es504094x	journal	November 2014
Oligomer Formation in Evaporating Aqueous Glyoxal and Methyl Glyoxal Solutions Loeffler, Kirsten W.; Koehler, Charles A.; Paul, Nichole M. Environmental Science & Technology, Vol. 40, Issue 20 https://doi.org/10.1021/es060810w	journal	October 2006
Characterisation of biological material with ToF-SIMS: a review Fearn, S. Materials Science and Technology, Vol. 31, Issue 2 https://doi.org/10.1179/1743284714Y.0000000668	journal	March 2014
Chemical insights, explicit chemistry, and yields of secondary organic aerosol from OH radical oxidation of methylglyoxal and glyoxal in the aqueous phase Lim, Y. B.; Tan, Y.; Turpin, B. J. Atmospheric Chemistry and Physics, Vol. 13, Issue 17 https://doi.org/10.5194/acp-13-8651-2013	journal	January 2013
Glyoxal uptake on ammonium sulphate seed aerosol: reaction products and reversibility of uptake under dark and irradiated conditions Galloway, M. M.; Chhabra, P. S.; Chan, A. W. H. Atmospheric Chemistry and Physics, Vol. 9, Issue 10 https://doi.org/10.5194/acp-9-3331-2009	journal	January 2009
Internal structure, hygroscopic and reactive properties of mixed sodium methanesulfonate-sodium chloride particles Liu, Y.; Minofar, B.; Desyaterik, Y. Physical Chemistry Chemical Physics, Vol. 13, Issue 25 https://doi.org/10.1039/c1cp20444k	journal	January 2011
Uptake of Glyoxal by Organic and Inorganic Aerosol Corrigan, Ashley L.; Hanley, Sean W.; De Haan, David O. Environmental Science & Technology, Vol. 42, Issue 12 https://doi.org/10.1021/es7032394	journal	June 2008
The Evolution of Silicon Wafer Cleaning Technology Kern, Werner Journal of The Electrochemical Society, Vol. 137, Issue 6 https://doi.org/10.1149/1.2086825	journal	January 1990

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