Carburization resistance of cu-coated stainless steel in supercritical carbon dioxide environments

Brittan, Andrew Meyer; Mahaffey, Jacob Thomas; Colgan, Nathan Eamon; Elbakhshwan, Mohamed; Anderson, Mark Harlan

doi:10.1016/j.corsci.2020.108639

Carburization resistance of cu-coated stainless steel in supercritical carbon dioxide environments

Journal Article · Wed Apr 15 00:00:00 EDT 2020 · Corrosion Science

DOI:https://doi.org/10.1016/j.corsci.2020.108639· OSTI ID:1773288

Brittan, Andrew Meyer ^[1]; Mahaffey, Jacob Thomas ^[2]; Colgan, Nathan Eamon ^[1]; Elbakhshwan, Mohamed ^[1]; Anderson, Mark Harlan ^[1]

Univ. of Wisconsin, Madison, WI (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

This study investigates the effectiveness of Cu as a corrosion barrier in supercritical carbon dioxide (s-CO₂) by coating 316 stainless steel (316) with various thicknesses of Cu. In this work, 316 exposed to s-CO₂ with 50 ppm CO showed a reduction in oxidation corresponding to the thickness of its Cu barrier coating. Additionally, a continuous Cu layer between the environment and the alloy was found to correlate to an elimination of carburization and corrosion-related mechanical degradation. This Cu coating technique could be applied over a variety of temperatures to improve the corrosion resistance of alloys that are susceptible to carburization.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office; USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000; EE0007120; NA0003525

OSTI ID:: 1773288

Alternate ID(s):: OSTI ID: 1616220

Report Number(s):: SAND--2021-3482J; 695003

Journal Information:: Corrosion Science, Journal Name: Corrosion Science Vol. 169; ISSN 0010-938X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

36 MATERIALS SCIENCE
Carburization
Corrosion protection
Mechanical properties
Oxidation
Stainless steel
Supercritical carbon dioxide

Carburization resistance of cu-coated stainless steel in supercritical carbon dioxide environments

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