Carbonyl Identification and Quantification Uncertainties for Oxidative Polymer Degradation

Celina, Mathew C.; Linde, Erik; Martinez, Estevan

doi:10.1016/j.polymdegradstab.2021.109550

Carbonyl Identification and Quantification Uncertainties for Oxidative Polymer Degradation

Journal Article · Sat Mar 13 00:00:00 EST 2021 · Polymer Degradation and Stability

DOI:https://doi.org/10.1016/j.polymdegradstab.2021.109550· OSTI ID:1772948

Celina, Mathew C. ^[1]; ^[1]; Martinez, Estevan ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

The most revealing indicator for oxidative processes or state of degraded plastics is usually carbonyl formation, a key step in materials degradation as part of the carbon cycle for man-made materials. Hence, the identification and quantification of carbonyl species with infrared spectroscopy have been the method of choice for generations, thanks to their strong absorbance and being an essential intermediate in carbon oxidation pathways. Despite their importance, precise identification and quantification can be challenging and rigorous fully traceable data are surprisingly rare in the existing literature. An overview of the complexity of carbonyl quantification is presented by the screening of reference compounds in solution with transmission and polymer films with ATR IR spectroscopy, and systematic data analyses. Significant variances in existing data and their past use have been recognized. Guidance is offered how better measurements and data reporting could be accomplished. Experimental variances depend on the combination of uncertainty in exact carbonyl species, extinction coefficient, contributions from neighboring convoluting peaks, matrix interaction phenomena and instrumental variations in primary IR spectral acquisition (refractive index and penetration depth for ATR measurements). In addition, diverging sources for relevant extinction coefficients may exist, based on original spectral acquisition. For common polymer degradation challenges, a relative comparison of carbonyl yields for a material is easily accessible, but quantification for other purposes, such as degradation rates and spatially dependent interpretation, requires thorough experimental validation. All variables featured in this overview demonstrate the significant error margins in carbonyl quantification, with exact carbonyl species and extinction coefficients already being major contributors on their own.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE; USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000; NA0003525

OSTI ID:: 1772948

Alternate ID(s):: OSTI ID: 1828396

Report Number(s):: SAND2021-3276J; 694889

Journal Information:: Polymer Degradation and Stability, Journal Name: Polymer Degradation and Stability Vol. 188; ISSN 0141-3910

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (93)

Mesocellular Silica Foam as an Epoxy Polymer Reinforcing Agent Park, I.; Pinnavaia, T. J. Advanced Functional Materials, Vol. 17, Issue 15 https://doi.org/10.1002/adfm.200700063	journal	October 2007
1HT2-NMR monitoring of crosslinked polyolefin aging Harris, Douglas J.; Assink, Roger A.; Gillen, Kenneth T. Journal of Applied Polymer Science, Vol. 90, Issue 9 https://doi.org/10.1002/app.12872	journal	September 2003
Oxidation of bisphenol a polymers Gesner, B. D.; Kelleher, P. G. Journal of Applied Polymer Science, Vol. 13, Issue 10 https://doi.org/10.1002/app.1969.070131013	journal	October 1969
Infrared identification of carboxylic acids formed in polymer photooxidation Wilhelm, Catherine; Gardette, Jean-Luc Journal of Applied Polymer Science, Vol. 51, Issue 8 https://doi.org/10.1002/app.1994.070510808	journal	February 1994
The design of a test protocol to model the degradation of polyolefins during recycling and service life Strömberg, Emma; Karlsson, Sigbritt Journal of Applied Polymer Science, Vol. 112, Issue 3 https://doi.org/10.1002/app.29724	journal	May 2009
Chemical and spectroscopic methods for investigating polymer degradation and stabilization: Oxidative degradation of a hydrogenated nitrile rubber Carlsson, D. J.; Chmela, S.; Wiles, D. M. Makromolekulare Chemie. Macromolecular Symposia, Vol. 27, Issue 1 https://doi.org/10.1002/masy.19890270108	journal	April 1989
Infrared spectrophotometric studies on polyethylene. II. Oxidation Rugg, Frank M.; Smith, Joseph J.; Bacon, R. Charles Journal of Polymer Science, Vol. 13, Issue 72 https://doi.org/10.1002/pol.1954.120137202	journal	June 1954
Analysis of the nonvolatile oxidation products of polypropylene I. Thermal oxidation Adams, J. H. Journal of Polymer Science Part A-1: Polymer Chemistry, Vol. 8, Issue 5 https://doi.org/10.1002/pol.1970.150080505	journal	May 1970
Epoxy resins. III. Application of fourier transform IR to degradation studies of epoxy systems Lin, S. C.; Bulkin, B. J.; Pearce, E. M. Journal of Polymer Science: Polymer Chemistry Edition, Vol. 17, Issue 10 https://doi.org/10.1002/pol.1979.170171006	journal	October 1979
Quantitative analysis of polymers by attenuated total reflectance fourier-transform infrared spectroscopy: Vinyl acetate and methyl content of polyethylenes Mirabella, Francis M. Journal of Polymer Science: Polymer Physics Edition, Vol. 20, Issue 12 https://doi.org/10.1002/pol.1982.180201211	journal	December 1982
Strength of interaction and penetration of infrared radiation for polymer films in internal reflection spectroscopy Mirabella, Francis M. Journal of Polymer Science: Polymer Physics Edition, Vol. 21, Issue 11 https://doi.org/10.1002/pol.1983.180211115	journal	November 1983
Evolution of H2O and CO2 during the copper-catalyzed oxidation of isotactic polypropylene Jellinek, H. H. G.; Wei, You Ching Journal of Polymer Science Part A: Polymer Chemistry, Vol. 24, Issue 3 https://doi.org/10.1002/pola.1986.080240301	journal	March 1986
Oxidative structures in polyolefins: FT–IR method of quantitative determination Domke, W. -D.; Steinke, H. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 24, Issue 10 https://doi.org/10.1002/pola.1986.080241024	journal	October 1986
Gamma-, photo-, and thermally-initiated oxidation of linear low density polyethylene: A quantitative comparison of oxidation products Lacoste, J.; Carlsson, D. J. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 30, Issue 3 https://doi.org/10.1002/pola.1992.080300316	journal	March 1992
Changes in carbonyl index and average molecular weight on embrittlement of enhanced-photodegradable polyethylenes Andrady, A. L.; Pegram, J. E.; Tropsha, Y. Journal of Environmental Polymer Degradation, Vol. 1, Issue 3 https://doi.org/10.1007/BF01458025	journal	July 1993
Application of infrared spectroscopy to the analysis of primary fatty amide mixtures Link, W. E.; Buswell, K. M. Journal of the American Oil Chemists Society, Vol. 39, Issue 1 https://doi.org/10.1007/BF02633348	journal	January 1962
Rigorous experimental confirmation of a theoretical model for diffusion-limited oxidation Gillen, Kenneth T.; Clough, Roger L. Polymer, Vol. 33, Issue 20 https://doi.org/10.1016/0032-3861(92)90280-A	journal	January 1992
Photo-oxidation of thick polymer samples—Part II: The influence of oxygen diffusion on the natural and artificial weathering of polyolefins Cunliffe, A. V.; Davis, A. Polymer Degradation and Stability, Vol. 4, Issue 1 https://doi.org/10.1016/0141-3910(82)90003-9	journal	January 1982
Modulus profiling of polymers Gillen, Kenneth T.; Clough, Roger L.; Quintana, Carlos A. Polymer Degradation and Stability, Vol. 17, Issue 1 https://doi.org/10.1016/0141-3910(87)90046-2	journal	January 1987
Polyolefin oxidation: Quantification of alcohol and hydroperoxide products by nitric oxide reactions Carlsson, D. J.; Brousseau, R.; Zhang, Can Polymer Degradation and Stability, Vol. 17, Issue 4 https://doi.org/10.1016/0141-3910(87)90090-5	journal	January 1987
Polyethylene hydroperoxide decomposition products Lacoste, J.; Carlsson, D. J.; Falicki, S. Polymer Degradation and Stability, Vol. 34, Issue 1-3 https://doi.org/10.1016/0141-3910(91)90125-B	journal	January 1991
An ultrasensitive technique for testing the Arrhenius extrapolation assumption for thermally aged elastomers Wise, J.; Gillen, K. T.; Clough, R. L. Polymer Degradation and Stability, Vol. 49, Issue 3 https://doi.org/10.1016/0141-3910(95)00137-B	journal	January 1995
The thermal oxidation of poly(propylene oxide) and its complexes with LiBr and LiI Costa, L.; Camino, G.; Luda, M. P. Polymer Degradation and Stability, Vol. 53, Issue 3 https://doi.org/10.1016/0141-3910(96)00094-8	journal	September 1996
A review of oxygen uptake techniques for measuring polyolefin oxidation Scheirs, John; Bigger, Stephen W.; Billingham, Norman C. Polymer Testing, Vol. 14, Issue 3 https://doi.org/10.1016/0142-9418(94)00022-7	journal	January 1995
The infra-red spectra and molecular configurations of polyamides Cannon, C. G. Spectrochimica Acta, Vol. 16, Issue 3 https://doi.org/10.1016/0371-1951(60)80092-6	journal	January 1960
Quantitative model for the time development of diffusion-limited oxidation profiles Wise, J.; Gillen, K. T.; Clough, R. L. Polymer, Vol. 38, Issue 8 https://doi.org/10.1016/S0032-3861(96)00716-1	journal	April 1997
Infrared analysis of the photochemical behaviour of segmented polyurethanes Wilhelm, Catherine; Rivaton, Agnès; Gardette, Jean-Luc Polymer, Vol. 39, Issue 5 https://doi.org/10.1016/S0032-3861(97)00353-4	journal	March 1998
Thermal properties of high refractive index epoxy resin system Su, Wei-Fang; Fu, Ya-Ching; Pan, Wei-Ping Thermochimica Acta, Vol. 392-393 https://doi.org/10.1016/S0040-6031(02)00124-7	journal	September 2002
Initial steps and embrittlement in the thermal oxidation of stabilised polypropylene films Fayolle, B.; Audouin, L.; Verdu, J. Polymer Degradation and Stability, Vol. 75, Issue 1 https://doi.org/10.1016/S0141-3910(01)00211-7	journal	January 2002
Re-examination of the thermal oxidation reactions of polymers3. Various reactions in polyethylene and polypropylene Gugumus, F. Polymer Degradation and Stability, Vol. 77, Issue 1 https://doi.org/10.1016/S0141-3910(02)00093-9	journal	January 2002
Microspectrophotometric determinations of product ‘Profiles’ in photooxidized matrices Jouan, Xavier; Adam, Claudie; Fromageot, Dominique Polymer Degradation and Stability, Vol. 25, Issue 2-4 https://doi.org/10.1016/S0141-3910(89)81010-9	journal	January 1989
Kinetic study of the thermal oxidation of polypropylene Achimsky, Laurence; Audouin, Ludmila; Verdu, Jacques Polymer Degradation and Stability, Vol. 57, Issue 3 https://doi.org/10.1016/S0141-3910(96)00167-X	journal	September 1997
Oxidation profiles of thermally aged nitrile rubber Celina, M.; Wise, J.; Ottesen, D. K. Polymer Degradation and Stability, Vol. 60, Issue 2-3 https://doi.org/10.1016/S0141-3910(97)00113-4	journal	January 1998
Correlation of chemical and mechanical property changes during oxidative degradation of neoprene Celina, M.; Wise, J.; Ottesen, D. K. Polymer Degradation and Stability, Vol. 68, Issue 2 https://doi.org/10.1016/S0141-3910(99)00183-4	journal	April 2000
Density measurements as a condition monitoring approach for following the aging of nuclear power plant cable materials Gillen, K. T.; Celina, M.; Clough, R. L. Radiation Physics and Chemistry, Vol. 56, Issue 4 https://doi.org/10.1016/S0969-806X(99)00333-3	journal	October 1999
Radiochemical ageing of poly(ether ether ketone) Richaud, Emmanuel; Ferreira, Paulo; Audouin, Ludmila European Polymer Journal, Vol. 46, Issue 4 https://doi.org/10.1016/j.eurpolymj.2009.12.026	journal	April 2010
A general kinetic model for the photothermal oxidation of polypropylene François-Heude, A.; Richaud, E.; Desnoux, E. Journal of Photochemistry and Photobiology A: Chemistry, Vol. 296 https://doi.org/10.1016/j.jphotochem.2014.08.015	journal	January 2015
Influence of the structure on the γ-irradiation of polypropylene and on the post-irradiation effects Rivaton, A.; Lalande, D.; Gardette, J. -L. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 222, Issue 1-2 https://doi.org/10.1016/j.nimb.2004.02.012	journal	July 2004
Evidence of non-Arrhenius behaviour from laboratory aging and 24-year field aging of polychloroprene rubber materials Gillen, Kenneth T.; Bernstein, Robert; Derzon, Dora K. Polymer Degradation and Stability, Vol. 87, Issue 1 https://doi.org/10.1016/j.polymdegradstab.2004.06.010	journal	January 2005
Non-Arrhenius behavior for oxidative degradation of chlorosulfonated polyethylene materials Gillen, Kenneth T.; Bernstein, Robert; Celina, Mathew Polymer Degradation and Stability, Vol. 87, Issue 2 https://doi.org/10.1016/j.polymdegradstab.2004.09.004	journal	February 2005
Photooxidation of polymers: Relating material properties to chemical changes Larché, J. -F.; Bussière, P. -O.; Thérias, S. Polymer Degradation and Stability, Vol. 97, Issue 1 https://doi.org/10.1016/j.polymdegradstab.2011.10.020	journal	January 2012
Co-oxidation kinetic model for the thermal oxidation of polyethylene-unsaturated substrate systems Richaud, Emmanuel; Fayolle, Bruno; Verdu, Jacques Polymer Degradation and Stability, Vol. 98, Issue 5 https://doi.org/10.1016/j.polymdegradstab.2013.01.008	journal	May 2013
Review of polymer oxidation and its relationship with materials performance and lifetime prediction Celina, Mathew C. Polymer Degradation and Stability, Vol. 98, Issue 12 https://doi.org/10.1016/j.polymdegradstab.2013.06.024	journal	December 2013
Photo- and thermal-oxidation of polyethylene: Comparison of mechanisms and influence of unsaturation content Gardette, Mélanie; Perthue, Anthony; Gardette, Jean-Luc Polymer Degradation and Stability, Vol. 98, Issue 11 https://doi.org/10.1016/j.polymdegradstab.2013.07.017	journal	November 2013
Molecular and macromolecular structure changes in polyamide 11 during thermal oxidation Okamba-Diogo, Octavie; Richaud, Emmanuel; Verdu, Jacques Polymer Degradation and Stability, Vol. 108 https://doi.org/10.1016/j.polymdegradstab.2014.05.028	journal	October 2014
Oxidation of unvulcanized, unstabilized polychloroprene: A kinetic study Le Gac, Pierre Yves; Roux, Gérard; Verdu, Jacques Polymer Degradation and Stability, Vol. 109 https://doi.org/10.1016/j.polymdegradstab.2014.06.019	journal	November 2014
Is carbonyl index a quantitative probe to monitor polypropylene photodegradation? Rouillon, C.; Bussiere, P. -O.; Desnoux, E. Polymer Degradation and Stability, Vol. 128 https://doi.org/10.1016/j.polymdegradstab.2015.12.011	journal	June 2016
Influence of temperature and stabilization on oxygen diffusion limited oxidation profiles of polyamide 6 Gijsman, Pieter; Dong, Weifu; Quintana, Adam Polymer Degradation and Stability, Vol. 130 https://doi.org/10.1016/j.polymdegradstab.2016.05.024	journal	August 2016
Predictive ageing of elastomers: Oxidation driven modulus changes for polychloroprene Le Gac, Pierre Yves; Celina, Mathew; Roux, Gérard Polymer Degradation and Stability, Vol. 130 https://doi.org/10.1016/j.polymdegradstab.2016.06.014	journal	August 2016
Thermal oxidation of epoxies: Influence of diamine hardener Ernault, Esteve; Richaud, Emmanuel; Fayolle, Bruno Polymer Degradation and Stability, Vol. 134 https://doi.org/10.1016/j.polymdegradstab.2016.09.030	journal	December 2016
High temperature polymer degradation: Rapid IR flow-through method for volatile quantification Giron, Nicholas H.; Celina, Mathew C. Polymer Degradation and Stability, Vol. 145 https://doi.org/10.1016/j.polymdegradstab.2017.05.013	journal	November 2017
Overview of DLO modeling and approaches to predict heterogeneous oxidative polymer degradation Quintana, Adam; Celina, Mathew C. Polymer Degradation and Stability, Vol. 149 https://doi.org/10.1016/j.polymdegradstab.2017.11.014	journal	March 2018
Diffusion-limited oxidation of polyamide: Three stages of fracture behavior Wei, Xin-Feng; Kallio, Kai J.; Bruder, Stefan Polymer Degradation and Stability, Vol. 154 https://doi.org/10.1016/j.polymdegradstab.2018.05.024	journal	August 2018
IR spectroscopic quantification of small molecule transport and desorption phenomena in polymers Linde, Erik; Celina, Mathew C. Polymer Degradation and Stability, Vol. 162 https://doi.org/10.1016/j.polymdegradstab.2019.02.017	journal	April 2019
Prediction of stress induced by heterogeneous oxidation: Case of epoxy/amine networks Ernault, Esteve; Dirrenberger, Justin; Richaud, Emmanuel Polymer Degradation and Stability, Vol. 162 https://doi.org/10.1016/j.polymdegradstab.2019.02.019	journal	April 2019
Thermal oxidation of aromatic epoxy-diamine networks Delozanne, Justine; Desgardin, Nancy; Cuvillier, Nicolas Polymer Degradation and Stability, Vol. 166 https://doi.org/10.1016/j.polymdegradstab.2019.05.030	journal	August 2019
Multiscale analysis of the thermal degradation of polyamide 6,6: Correlating chemical structure to mechanical properties Pliquet, M.; Rapeaux, M.; Delange, F. Polymer Degradation and Stability, Vol. 185 https://doi.org/10.1016/j.polymdegradstab.2021.109496	journal	March 2021
Use of a respirometer to measure oxidation rates of polymeric materials at ambient temperatures Assink, Roger A.; Celina, Mathew; Skutnik, Julie M. Polymer, Vol. 46, Issue 25 https://doi.org/10.1016/j.polymer.2005.09.069	journal	November 2005
A perspective on the inherent oxidation sensitivity of epoxy materials Celina, Mathew C.; Dayile, Angela R.; Quintana, Adam Polymer, Vol. 54, Issue 13 https://doi.org/10.1016/j.polymer.2013.04.042	journal	June 2013
Oxygen diffusivity and permeation through polymers at elevated temperature Celina, Mathew C.; Quintana, Adam Polymer, Vol. 150 https://doi.org/10.1016/j.polymer.2018.06.047	journal	August 2018
FTIR characterization of aged XLPE Gulmine, J. V.; Akcelrud, L. Polymer Testing, Vol. 25, Issue 7 https://doi.org/10.1016/j.polymertesting.2006.05.014	journal	October 2006
Identification of carbonyl species of weathered LDPE films by curve fitting and derivative analysis of IR spectra Yagoubi, W.; Abdelhafidi, A.; Sebaa, M. Polymer Testing, Vol. 44 https://doi.org/10.1016/j.polymertesting.2015.03.008	journal	July 2015
Dielectric spectroscopy as a condition monitoring technique for cable insulation based on crosslinked polyethylene Linde, E.; Verardi, L.; Fabiani, D. Polymer Testing, Vol. 44 https://doi.org/10.1016/j.polymertesting.2015.04.004	journal	July 2015
Non-destructive condition monitoring of aged ethylene-propylene copolymer cable insulation samples using dielectric spectroscopy and NMR spectroscopy Linde, E.; Verardi, L.; Pourmand, P. Polymer Testing, Vol. 46 https://doi.org/10.1016/j.polymertesting.2015.07.002	journal	September 2015
Thermal and radio-oxidation of epoxy coatings Galant, C.; Fayolle, B.; Kuntz, M. Progress in Organic Coatings, Vol. 69, Issue 4 https://doi.org/10.1016/j.porgcoat.2010.07.005	journal	December 2010
Thermo-oxidative aging of epoxy coating systems Zahra, Y.; Djouani, F.; Fayolle, B. Progress in Organic Coatings, Vol. 77, Issue 2 https://doi.org/10.1016/j.porgcoat.2013.10.011	journal	February 2014
Radiochemical ageing of epoxy coating for nuclear plants Queiroz, D. P. R.; Fraïsse, F.; Fayolle, B. Radiation Physics and Chemistry, Vol. 79, Issue 3 https://doi.org/10.1016/j.radphyschem.2009.08.034	journal	March 2010
Degradation of epoxy coatings under gamma irradiation Djouani, F.; Zahra, Y.; Fayolle, B. Radiation Physics and Chemistry, Vol. 82 https://doi.org/10.1016/j.radphyschem.2012.09.008	journal	January 2013
Quantitative calibration of spectroscopic signals in combined TG-FTIR system Eigenmann, F.; Maciejewski, M.; Baiker, A. Thermochimica Acta, Vol. 440, Issue 1 https://doi.org/10.1016/j.tca.2005.10.018	journal	January 2006
Deconvolution as a tool to remove fringes from an FT-IR spectrum Pistorius, Arthur M. A.; DeGrip, Willem J. Vibrational Spectroscopy, Vol. 36, Issue 1 https://doi.org/10.1016/j.vibspec.2004.04.001	journal	October 2004
Effective Path Length in Attenuated Total Reflection Spectroscopy Averett, Lacey A.; Griffiths, Peter R.; Nishikida, Koichi Analytical Chemistry, Vol. 80, Issue 8 https://doi.org/10.1021/ac7025892	journal	March 2008
The Beer-Lambert Law Swinehart, D. F. Journal of Chemical Education, Vol. 39, Issue 7 https://doi.org/10.1021/ed039p333	journal	July 1962
FTIR study of the solvent influence on the carbonyl absorption peak of ethyl acetate Kolling, Orland W. The Journal of Physical Chemistry, Vol. 96, Issue 15 https://doi.org/10.1021/j100194a025	journal	July 1992
Peroxides. VIII. The Mechanism for the Thermal Decomposition of n-Butyl Hydroperoxide and n-Butyl 1-Hydroxybutyl Peroxide ¹ Durham, Lois J.; Wurster, Charles F.; Mosher, Harry S. Journal of the American Chemical Society, Vol. 80, Issue 2 https://doi.org/10.1021/ja01535a020	journal	January 1958
Refractive indices of transparent solvents MacRae, Robert A.; Arakawa, Edward T.; Williams, Mary W. Journal of Chemical & Engineering Data, Vol. 23, Issue 3 https://doi.org/10.1021/je60078a024	journal	July 1978
Oxygen Permeability Measurements on Elastomers at Temperatures up to 225 °C Celina, M.; Gillen, K. T. Macromolecules, Vol. 38, Issue 7 https://doi.org/10.1021/ma0487913	journal	April 2005
The Photodegradation of Polypropylene Films. II. Photolysis of Ketonic Oxidation Products Carlsson, D. J.; Wiles, D. M. Macromolecules, Vol. 2, Issue 6 https://doi.org/10.1021/ma60012a006	journal	November 1969
The infra-red spectrum of ethylene polymers Cross, L. H.; Richards, R. B.; Willis, H. A. Discussions of the Faraday Society, Vol. 9 https://doi.org/10.1039/df9500900235	journal	January 1950
The carbonyl group frequency. Part I. Aliphatic ketones Morgan, K. J.; Unwin, N. Journal of the Chemical Society B: Physical Organic https://doi.org/10.1039/j29670001336	journal	January 1967
Molar extinction coefficients of certain functional groupings with special reference to compounds containing carbonyl Cross, L. H.; Rolfe, A. C. Transactions of the Faraday Society, Vol. 47 https://doi.org/10.1039/tf9514700354	journal	January 1951
Internal Reflection Spectroscopy Mirabella, F. M. Applied Spectroscopy Reviews, Vol. 21, Issue 1-2 https://doi.org/10.1080/05704928508060428	journal	March 1985
In situ study of the epoxy cure process using a fibre-optic sensor Chailleux, E.; Salvia, M.; Jaffrezic-Renault, N. Smart Materials and Structures, Vol. 10, Issue 2 https://doi.org/10.1088/0964-1726/10/2/304	journal	April 2001
Kinetic studies in the chemistry of rubber and related materials. I. The thermal oxidation of ethyl linoleate Bolland, J. L. Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 186, Issue 1005, p. 218-236 https://doi.org/10.1098/rspa.1946.0040	journal	July 1946
L'azote n'est pas le site basique des amides encombrés Laurence, Christian; Helbert, Maryvonne; Lachkar, Abdeljalil Canadian Journal of Chemistry, Vol. 71, Issue 2 https://doi.org/10.1139/v93-036	journal	February 1993
Study of thermal and optical properties of epoxy/organically modified silicate hybrids Wu, Kuo-Hui; Cheng, Ken-Fa; Wang, Chung-Ren Materials Express, Vol. 6, Issue 1 https://doi.org/10.1166/mex.2016.1271	journal	February 2016
Controlling the Refractive Index of Epoxy Adhesives Messinger, John M.; Lansbury, Peter T. Journal of the American Institute for Conservation, Vol. 28, Issue 2 https://doi.org/10.1179/019713689806046219	journal	January 1989
Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006) Braslavsky, S. E. Pure and Applied Chemistry, Vol. 79, Issue 3 https://doi.org/10.1351/pac200779030293	journal	January 2007
Optical and physical parameters of Plexiglas 55 and Lexan Waxler, Roy M.; Horowitz, Deane; Feldman, Albert Applied Optics, Vol. 18, Issue 1 https://doi.org/10.1364/AO.18.000101	journal	January 1979
Measurement of change in refractive index in polymeric flexible substrates using wide field interferometry and digital fringe analysis Singh, Gyanendra; Mehta, Dalip Singh Applied Optics, Vol. 51, Issue 35 https://doi.org/10.1364/AO.51.008413	journal	January 2012
Infrared refractive index of diamond Edwards, David F.; Ochoa, Ellen Journal of the Optical Society of America, Vol. 71, Issue 5 https://doi.org/10.1364/JOSA.71.000607	journal	January 1981
Effective absorption coefficient and effective thickness in attenuated total reflection spectroscopy Mendoza-Galván, A.; Méndez-Lara, J. G.; Mauricio-Sánchez, R. A. Optics Letters, Vol. 46, Issue 4 https://doi.org/10.1364/OL.418277	journal	January 2021
Optical Contact in ATR/FT-IR Spectroscopy Ekgasit, Sanong; Padermshoke, Adchara Applied Spectroscopy, Vol. 55, Issue 10 https://doi.org/10.1366/0003702011953478	journal	October 2001
Quantitative Gas Analysis with FT-IR: A Method for CO Calibration Using Partial Least-Squares with Linearized Data Bak, Jimmy; Larsen, Anders Applied Spectroscopy, Vol. 49, Issue 4 https://doi.org/10.1366/0003702953964237	journal	April 1995

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Carbonyl Identification and Quantification Uncertainties for Oxidative Polymer Degradation

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