Vitreous solid electrolyte sheets of Li ion conducting sulfur-based glass and associated structures, cells and methods

Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.; Katz, Bruce D.; Nimon, Vitaliy

Vitreous solid electrolyte sheets of Li ion conducting sulfur-based glass and associated structures, cells and methods

Patent · Tue Nov 17 04:00:00 EST 2020

OSTI ID:1771650

Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.; Katz, Bruce D.; Nimon, Vitaliy

A lithium ion-conductive solid electrolyte including a freestanding inorganic vitreous sheet of sulfide-based lithium ion conducting glass is capable of high performance in a lithium metal battery by providing a high degree of lithium ion conductivity while being highly resistant to the initiation and/or propagation of lithium dendrites. Such an electrolyte is also itself manufacturable, and readily adaptable for battery cell and cell component manufacture, in a cost-effective, scalable manner.

View Patent

Research Organization:: PolyPlus Battery Co., Berkeley, CA (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

DOE Contract Number:: AR0000349; AR0000772

Assignee:: PolyPlus Battery Company (Berkeley, CA)

Patent Number(s):: 10,840,546

Application Number:: 16/179,803

OSTI ID:: 1771650

Country of Publication:: United States

Language:: English

References (41)

Solid state batteries using vitreous solid electrolytes Akridge, J.; Vourlis, H. Solid State Ionics, Vol. 18-19 https://doi.org/10.1016/0167-2738(86)90313-9	journal	January 1986
Electrical and electrochemical properties of glass–ceramic electrolytes in the systems Li2S–P2S5–P2S3 and Li2S–P2S5–P2O5 Minami, Keiichi; Hayashi, Akitoshi; Ujiie, Satoshi Solid State Ionics, Vol. 192, Issue 1 https://doi.org/10.1016/j.ssi.2010.06.018	journal	June 2011
Mechanochemical synthesis of Li2S–P2S5 glass electrolytes with lithium salts Minami, Keiichi; Hayashi, Akitoshi; Tatsumisago, Masahiro Solid State Ionics, Vol. 181, Issue 33-34 https://doi.org/10.1016/j.ssi.2010.08.021	journal	October 2010
Lithium ion conducting solid electrolytes prepared from Li2S, elemental P and S Mizuno, F.; Ohtomo, T.; Hayashi, A. Solid State Ionics, Vol. 177, Issue 26-32 https://doi.org/10.1016/j.ssi.2006.04.024	journal	October 2006
Superionic conduction in Li 2 S - P 2 S 5 - LiI - glasses Mercier, René; Malugani, Jean-Pierre; Fahys, Bernard Solid State Ionics, Vol. 5 https://doi.org/10.1016/0167-2738(81)90341-6	journal	October 1981
Formation of superionic crystals from mechanically milled Li2S–P2S5 glasses Hayashi, Akitoshi; Hama, Shigenori; Minami, Tsutomu Electrochemistry Communications, Vol. 5, Issue 2 https://doi.org/10.1016/S1388-2481(02)00555-6	journal	February 2003
Ionically conductive glasses based on SiS2 Kennedy, J. H. Materials Chemistry and Physics, Vol. 23, Issue 1-2 https://doi.org/10.1016/0254-0584(89)90015-1	journal	August 1989
Glassy materials based on Li2S for all-solid-state lithium secondary batteries Tatsumisago, M. Solid State Ionics, Vol. 175, Issue 1-4 https://doi.org/10.1016/j.ssi.2004.09.012	journal	November 2004
Glass–ceramic Li2S–P2S5 electrolytes prepared by a single step ball billing process and their application for all-solid-state lithium–ion batteries Trevey, James; Jang, Jum Suk; Jung, Yoon Seok Electrochemistry Communications, Vol. 11, Issue 9 https://doi.org/10.1016/j.elecom.2009.07.028	journal	September 2009
New lithium ion conductors based on Li2S-SiS2 system Kondo, S.; Takada, K.; Yamamura, Y. Solid State Ionics, Vol. 53-56 https://doi.org/10.1016/0167-2738(92)90310-L	journal	July 1992
Electrical properties of amorphous lithium electrolyte thin films Bates, J. B.; Dudney, N. J.; Gruzalski, G. R. Solid State Ionics, Vol. 53-56, Issue Part 1, p. 647-654 https://doi.org/10.1016/0167-2738(92)90442-R	journal	July 1992
Improved stability for the SiS2-P2S5-Li2S-LiI glass system Kennedy, John H.; Zhang, Zhengming Solid State Ionics, Vol. 28-30 https://doi.org/10.1016/S0167-2738(88)80133-4	journal	September 1988
Preparation and conductivity measurements of SiS2Li2S glasses doped with LiBr and LiCl Kennedy, J.; Sahami, S.; Shea, S. Solid State Ionics, Vol. 18-19 https://doi.org/10.1016/0167-2738(86)90142-6	journal	January 1986
Fast Li+ ion transport in iodine-thioborate glasses Burckhardt, W.; Makyta, M.; Levasseur, A. Materials Research Bulletin, Vol. 19, Issue 8 https://doi.org/10.1016/0025-5408(84)90224-1	journal	August 1984
Superionic conductivity of glass-ceramics in the system Li 2 O- Al 2 O 3 -TiO 2 -P 2 O 5 Fu, Jie Solid State Ionics, Vol. 96, Issue 3-4 https://doi.org/10.1016/S0167-2738(97)00018-0	journal	April 1997
Recent Advances in Inorganic Solid Electrolytes for Lithium Batteries Cao, Can; Li, Zhuo-Bin; Wang, Xiao-Liang Frontiers in Energy Research, Vol. 2 https://doi.org/10.3389/fenrg.2014.00025	journal	June 2014
Recent development of sulfide solid electrolytes and interfacial modification for all-solid-state rechargeable lithium batteries Tatsumisago, Masahiro; Nagao, Motohiro; Hayashi, Akitoshi Journal of Asian Ceramic Societies, Vol. 1, Issue 1 https://doi.org/10.1016/j.jascer.2013.03.005	journal	March 2013
Electrical and electrochemical properties of Li₂S–P₂S₅–P₂O₅ glass–ceramic electrolytes Ohtomo, Takamasa; Mizuno, Fuminori; Hayashi, Akitoshi Journal of Power Sources, Vol. 146, Issue 1-2, p. 715-718 https://doi.org/10.1016/j.jpowsour.2005.03.063	journal	August 2005
Preparation and Structure of Lithium-Ion-Conducting Mixed-Anion Glasses in the System LiBO2-LiBS2 Tatsumisago, Masahiro; Yoneda, Kazuya; Minami, Tsutomu Journal of the American Ceramic Society, Vol. 71, Issue 9 https://doi.org/10.1111/j.1151-2916.1988.tb06411.x	journal	September 1988
Preparation and electrical properties of the 0,37Li2S-0,18P2S5-0,45LiI glass Malugani, J.; Robert, G. Solid State Ionics, Vol. 1, Issue 5-6 https://doi.org/10.1016/0167-2738(80)90048-X	journal	December 1980
Sulfide Solid Electrolyte with Favorable Mechanical Property for All-Solid-State Lithium Battery Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02261	journal	July 2013
Mechanochemical synthesis of amorphous solid electrolytes using SiS2 and various lithium compounds Hayashi, A. Solid State Ionics, Vol. 175, Issue 1-4 https://doi.org/10.1016/j.ssi.2003.12.040	journal	November 2004
Complex Plane and 7Li NMR Studies of Arsenic Sulfide-Based Lithium Glasses Visco, Steven J. Journal of The Electrochemical Society, Vol. 132, Issue 7 https://doi.org/10.1149/1.2114208	journal	January 1985
Mechanochemical synthesis of lithium ion conducting glasses and glass–ceramics in the system Li2S–P–S Ohtomo, Takamasa; Mizuno, Fuminori; Hayashi, Akitoshi Solid State Ionics, Vol. 176, Issue 31-34 https://doi.org/10.1016/j.ssi.2005.03.025	journal	October 2005
Fabrication of electrode–electrolyte interfaces in all-solid-state rechargeable lithium batteries by using a supercooled liquid state of the glassy electrolytes Kitaura, Hirokazu; Hayashi, Akitoshi; Ohtomo, Takamasa J. Mater. Chem., Vol. 21, Issue 1 https://doi.org/10.1039/C0JM01090A	journal	January 2011
Complex Plane and 7Li NMR Studies of Highly Conductive Sulfide-Based Lithium Glasses Visco, Steven J. Journal of The Electrochemical Society, Vol. 132, Issue 4 https://doi.org/10.1149/1.2113952	journal	January 1985
Preparation and characterization of lithium ion conducting Li2S–P2S5–GeS2 glasses and glass-ceramics Minami, Keiichi; Hayashi, Akitoshi; Tatsumisago, Masahiro Journal of Non-Crystalline Solids, Vol. 356, Issue 44-49 https://doi.org/10.1016/j.jnoncrysol.2010.05.016	journal	October 2010
Electrical properties of new glasses based on the Li₂S–SiS₂ system Bartholomew, Roger F.; Young, Dianna M.; Ellison, Adam J. G. Journal of Non-Crystalline Solids, Vol. 256-257, p. 242-247 https://doi.org/10.1016/S0022-3093(99)00486-X	journal	October 1999
A thin-film solid-state microbattery Jones, Steven D.; Akridge, James R. Journal of Power Sources, Vol. 44, Issue 1-3 https://doi.org/10.1016/0378-7753(93)80196-V	journal	April 1993
Preparation and ionic conductivity of Li₇P₃S_11−z glass-ceramic electrolytes Hayashi, Akitoshi; Minami, Keiichi; Ujiie, Satoshi Journal of Non-Crystalline Solids, Vol. 356, Issue 44-49, p. 2670-2673 https://doi.org/10.1016/j.jnoncrysol.2010.04.048	journal	October 2010
Characterization of Li2S?P2S5 glass-ceramics as a solid electrolyte for lithium secondary batteries Hayashi, A. Solid State Ionics, Vol. 175, Issue 1-4 https://doi.org/10.1016/j.ssi.2004.08.036	journal	November 2004
Ionically conductive sulfide-based lithium glasses Kennedy, John H.; Zhang, Zhengming; Eckert, Hellmut Journal of Non-Crystalline Solids, Vol. 123, Issue 1-3 https://doi.org/10.1016/0022-3093(90)90804-U	journal	August 1990
Fast Li+ ion conducting glass-ceramics in the system Li2O–Al2O3–GeO2–P2O5 Fu, J. Solid State Ionics, Vol. 104, Issue 3-4 https://doi.org/10.1016/S0167-2738(97)00434-7	journal	December 1997
Electrical properties of lithium conductive silicon sulfide glasses prepared by twin roller quenching Pradel, A.; Ribes, M. Solid State Ionics, Vol. 18-19 https://doi.org/10.1016/0167-2738(86)90139-6	journal	January 1986
All-solid-state lithium secondary batteries using the 75Li2S·25P2S5 glass and the 70Li2S·30P2S5 glass–ceramic as solid electrolytes Ohtomo, Takamasa; Hayashi, Akitoshi; Tatsumisago, Masahiro Journal of Power Sources, Vol. 233 https://doi.org/10.1016/j.jpowsour.2013.01.090	journal	July 2013
Thin-film rechargeable lithium batteries Bates, J. B.; Dudney, N. J.; Lubben, D. C. Journal of Power Sources, Vol. 54, Issue 1, p. 58-62 https://doi.org/10.1016/0378-7753(94)02040-A	journal	March 1995
Cyclic voltammetry studies of the lithiumthioborate glass—indium interface Rudolph, B.; Burckhardt, W.; Staikov, G. Electrochimica Acta, Vol. 34, Issue 11 https://doi.org/10.1016/0013-4686(89)87035-5	journal	November 1989
Fast Li+ Ion Conduction in Li₂O-Al₂O₃-TiO₂-SiO₂-P₂O₂ Glass-Ceramics Fu, Jie Journal of the American Ceramic Society, Vol. 80, Issue 7, p. 1901-1903 https://doi.org/10.1111/j.1151-2916.1997.tb03070.x	journal	July 1997
Membranes in Lithium Ion Batteries Yang, Min; Hou, Junbo Membranes, Vol. 2, Issue 3, p. 367-383 https://doi.org/10.3390/membranes2030367	journal	July 2012
Preparation and characterization of lithium ion-conducting oxysulfide glasses Minami, T. Solid State Ionics, Vol. 136-137, Issue 1-2 https://doi.org/10.1016/S0167-2738(00)00555-5	journal	November 2000
Preparation and Conductivity Measurements of SiS[sub 2]-Li[sub 2]S-LiBr Lithium Ion Conductive Glasses Sahami, Saeed Journal of The Electrochemical Society, Vol. 132, Issue 4 https://doi.org/10.1149/1.2114001	journal	January 1985

Similar Records

Vitreous solid electrolyte sheets of Li ion conducting sulfur-based glass and associated structures, cells and methods

Patent · Mon Dec 24 23:00:00 EST 2018 · OSTI ID:1497863

Vitreous solid electrolyte sheets of Li ion conducting sulfur-based glass and associated structures, cells and methods

Patent · Tue May 09 00:00:00 EDT 2023 · OSTI ID:1998364

Vitreous solid electrolyte sheets of Li ion conducting sulfur-based glass and associated structures, cells and methods

Patent · Mon Dec 30 23:00:00 EST 2024 · OSTI ID:2542961

Vitreous solid electrolyte sheets of Li ion conducting sulfur-based glass and associated structures, cells and methods

Citation Formats

References (41)

Similar Records

Related Subjects