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Title: Coated U3Si2 pellets with enhanced water and steam oxidation resistance

Patent ·
OSTI ID:1771507

A method of forming a water resistant boundary on a fissile material for use in a water cooled nuclear reactor is described. The method comprises coating the fissile material, such as a pellet of U3Si2 and/or the grain boundaries, to a desired thickness with a suitable coating material, such as atomic layer deposition or a thermal spray process. The coating material may be any non-reactive material with a solubility at least as low as that of UO2. Exemplary coating materials include ZrSiO4, FeCrAl, Cr, Zr, Al—Cr, CrAl, ZrO2, CeO2, TiO2, SiO2, UO2, ZrB2, Na2O—B2O3—SiO2—Al2O3 glass, Al2O3, Cr2O3, carbon, and SiC, and combinations thereof. The water resistant layer may be overlayed with a burnable absorber layer, such as ZrB2 or B2O3—SiO2 glass.

Research Organization:
Westinghouse Electric Co., LLC, Cranberry Township, PA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
NE0008222
Assignee:
Westinghouse Electric Company LLC (Cranberry Township, PA)
Patent Number(s):
10,803,999
Application Number:
15/898,308
OSTI ID:
1771507
Resource Relation:
Patent File Date: 02/16/2018
Country of Publication:
United States
Language:
English

References (9)

High-density, Solid Solution Nuclear Fuel and Fuel Block Utilizing Same patent-application March 2007
Methods of making a drilling tool with low friction coatings to reduce balling and friction patent-application June 2014
Burnable neutron absorber element patent June 1988
Nuclear fuel cladding with hydrogen absorbing inner liner patent December 1995
Method and apparatus for a fret resistant fuel rod for a light water reactor (LWR) nuclear fuel bundle patent-application July 2014
Disposition of a Protective Coating Including Metal-Containing and Chromium-Containing Layers on Zirconium Alloy for Nuclear Power Applications patent-application December 2015
Granular particle gripping surface patent-application September 2002
Internal fuel rod coating comprising metal silicates patent June 1994
Designed porosity materials in nuclear reactor components patent-application March 2015

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