Perspectives on Low-Temperature Electrolysis and Potential for Renewable Hydrogen at Scale

Ayers, Katherine; Danilovic, Nemanja; Ouimet, Ryan; Carmo, Marcelo; Pivovar, Bryan; Bornstein, Marius

doi:10.1146/annurev-chembioeng-060718-030241

Title: Perspectives on Low-Temperature Electrolysis and Potential for Renewable Hydrogen at Scale

Journal Article · Fri Jun 07 00:00:00 EDT 2019 · Annual Review of Chemical and Biomolecular Engineering

DOI:https://doi.org/10.1146/annurev-chembioeng-060718-030241· OSTI ID:1769305

Ayers, Katherine ^[1]; Danilovic, Nemanja ^[2]; Ouimet, Ryan ^[3]; Carmo, Marcelo ^[4]; Pivovar, Bryan ^[5]; Bornstein, Marius ^[6]

Proton OnSite, Wallingford, CT (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of Connecticut, Storrs, CT (United States)
Forschungszentrum Juelich (Germany)
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Nel ASA, Oslo (Norway)

Hydrogen is an important part of any discussion on sustainability and reduction in emissions across major energy sectors. In addition to being a feedstock and process gas for many industrial processes, hydrogen is emerging as a fuel alternative for transportation applications. Renewable sources of hydrogen are therefore required to increase in capacity. Low-temperature electrolysis of water is currently the most mature method for carbon-free hydrogen generation and is reaching relevant scales to impact the energy landscape. However, costs still need to be reduced to be economical with traditional hydrogen sources. Operating cost reductions are enabled by the recent availability of low-cost sources of renewable energy, and the potential exists for a large reduction in capital cost withmaterial and manufacturing optimization. This article focuses on the current status and development needs by component for the low-temperature electrolysis options.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Fuel Cell Technologies Program

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1769305

Journal Information:: Annual Review of Chemical and Biomolecular Engineering, Vol. 10, Issue 1; ISSN 1947-5438

Publisher:: Annual ReviewsCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 167 works

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Fe (Oxy)hydroxide Oxygen Evolution Reaction Electrocatalysis: Intrinsic Activity and the Roles of Electrical Conductivity, Substrate, and Dissolution Zou, Shihui; Burke, Michaela S.; Kast, Matthew G. Chemistry of Materials, Vol. 27, Issue 23 https://doi.org/10.1021/acs.chemmater.5b03404	journal	November 2015
A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles Suntivich, J.; May, K. J.; Gasteiger, H. A. Science, Vol. 334, Issue 6061 https://doi.org/10.1126/science.1212858	journal	October 2011
CuCo ₂ O ₄ ORR/OER Bi-Functional Catalyst: Influence of Synthetic Approach on Performance Serov, Alexey; Andersen, Nalin I.; Roy, Aaron J. Journal of The Electrochemical Society, Vol. 162, Issue 4 https://doi.org/10.1149/2.0921504jes	journal	January 2015
Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M. Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/ja510442p	journal	March 2015
Electrochemical tuning of layered lithium transition metal oxides for improvement of oxygen evolution reaction Lu, Zhiyi; Wang, Haotian; Kong, Desheng Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5345	journal	July 2014
Charge-Transfer Effects in Ni–Fe and Ni–Fe–Co Mixed-Metal Oxides for the Alkaline Oxygen Evolution Reaction Bates, Michael K.; Jia, Qingying; Doan, Huong ACS Catalysis, Vol. 6, Issue 1 https://doi.org/10.1021/acscatal.5b01481	journal	December 2015
Nickel-rich layered LiNi _1−x M _x O ₂ (M = Mn, Fe, and Co) electrocatalysts with high oxygen evolution reaction activity Augustyn, Veronica; Therese, Soosairaj; Turner, Travis C. Journal of Materials Chemistry A, Vol. 3, Issue 32 https://doi.org/10.1039/C5TA04637H	journal	January 2015
Structural basis for differing electrocatalytic water oxidation by the cubic, layered and spinel forms of lithium cobalt oxides Gardner, Graeme; Al-Sharab, Jafar; Danilovic, Nemanja Energy & Environmental Science, Vol. 9, Issue 1 https://doi.org/10.1039/C5EE02195B	journal	January 2016
Electrocatalysis of Perovskites: The Influence of Carbon on the Oxygen Evolution Activity Mohamed, Rhiyaad; Cheng, Xi; Fabbri, Emiliana Journal of The Electrochemical Society, Vol. 162, Issue 6 https://doi.org/10.1149/2.0861506jes	journal	January 2015

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Self-supported nanostructured iridium-based networks as highly active electrocatalysts for oxygen evolution in acidic media Jensen, Anders W.; Sievers, Gustav W.; Jensen, Kim D. Royal Society of Chemistry https://doi.org/10.48350/140811	text	January 2020
Self-supported nanostructured iridium-based networks as highly active electrocatalysts for oxygen evolution in acidic media Jensen, Anders W.; Sievers, Gustav W.; Jensen, Kim D. Journal of Materials Chemistry A, Vol. 8, Issue 3 https://doi.org/10.1039/c9ta12796h	journal	January 2020
Improving the Efficiency of PEM Electrolyzers through Membrane-Specific Pressure Optimization Scheepers, Fabian; Stähler, Markus; Stähler, Andrea Energies, Vol. 13, Issue 3 https://doi.org/10.3390/en13030612	journal	February 2020
Electrolyte Effects on the Electrocatalytic Performance of Iridium‐Based Nanoparticles for Oxygen Evolution in Rotating Disc Electrodes Arminio‐Ravelo, José Alejandro; Jensen, Anders W.; Jensen, Kim D. ChemPhysChem, Vol. 20, Issue 22 https://doi.org/10.1002/cphc.201900902	journal	November 2019
Improving the Efficiency of PEM Electrolyzers through Membrane-Specific Pressure Optimization Scheepers, Fabian; Stähler, Markus; Stähler, Andrea RWTH Aachen University https://doi.org/10.18154/rwth-2020-04380	text	January 2020
Electrolyzer Durability at Low Catalyst Loading and with Dynamic Operation Alia, Shaun M.; Stariha, Sarah; Borup, Rod L. Journal of The Electrochemical Society, Vol. 166, Issue 15 https://doi.org/10.1149/2.0231915jes	journal	January 2019

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