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Enhanced long-term cyclability in Li-Rich layered oxides by electrochemically constructing a LixTM3-xO4-type spinel shell

Journal Article · · Nano Energy
 [1];  [2];  [3];  [2];  [2];  [2];  [2];  [3];  [2]
  1. Peking Univ., Beijing (China); Univ. of Chicago, IL (United States)
  2. Peking Univ., Beijing (China)
  3. Argonne National Lab. (ANL), Argonne, IL (United States)

The poor long-term cycling stability, including the fast capacity fade and the severe voltage decay, has become the main concern hindering the practical application of Li-rich layered oxides, a promising cathode for high- energy-density Li-ion battery. Herein, we design and electrochemically construct a ~10 nm-thick LixTM3-xO4- type (TM ¼Ni, Co, Mn, 0 3O4-type spinel phase and the good Liþconductivity of LiMn2O4-type spinel phase. Systemic structural and electrochemical analysis demonstrate that, it slows down the activation rate of Li2MnO3 component and efficiently alleviates the lattice O loss at high voltage (>4.5 V) and Mn dissolution, thereby suppressing the structural degradation from the layered phase to the spinel phase in the bulk, eventually significantly enhancing the long-term cycling stability. This study adds richness into the Mn-based spinel phase system and provides a new heterostructure design strategy to improve the electrochemical performance of Li-rich layered cathodes and beyond.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Science Foundation (NSF); National Key Research and Development Program of China
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1768872
Alternate ID(s):
OSTI ID: 1809802
Journal Information:
Nano Energy, Journal Name: Nano Energy Vol. 77; ISSN 2211-2855
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

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