Bipolar membrane polarization behavior with systematically varied interfacial areas in the junction region

Kole, Subarna; Venugopalan, Gokul; Bhattacharya, Deepra; Zhang, Le; Cheng, John; Pivovar, Bryan; Arges, Christopher G.

doi:10.1039/d0ta10602j

Bipolar membrane polarization behavior with systematically varied interfacial areas in the junction region

Journal Article · Wed Dec 23 00:00:00 EST 2020 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/d0ta10602j· OSTI ID:1768327

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Louisiana State Univ., Baton Rouge, LA (United States)
National Renewable Energy Lab. (NREL), Golden, CO (United States)

The palette of applications for bipolar membranes (BPMs) has expanded recently beyond electrodialysis as they are now being considered for fuel cell and electrolysis applications. Their deployment in emerging electrochemical technologies arises from the need to have a membrane separator that provides disparate pH environments and to prevent species crossover. Most materials research for BPMs has focused on water dissociation catalysts and less emphasis has been given to the design of the polycation–polyanion interface for improving BPM performance. Here, soft lithography fabricated a series of micropatterned BPMs with precise control over the interfacial area in the bipolar junction. Polarization experiments showed that a 2.28× increase in interfacial area led to a 250 mV reduction in the onset potential. Additionally, the same increase in interfacial area yielded marginal improvements in current density due to the junction region being under kinetics-diffusion control. A simple physics model based on the electric field of the junction region rationalized the reduction in the overpotential for water dissociation as a function of interfacial area. Finally, the soft lithography approach was also conducive for fabricating BPMs with different chemistries ranging from perfluorinated polymer backbones to alkaline stable poly(arylene) hydrocarbon polymers. These polymer chemistries are better suited for fuel cell and electrolysis applications. The BPM featuring the alkaline stable poly(terphenyl) anion exchange membrane had an onset potential of 0.84 V, which was near the thermodynamic limit, and was about 150 mV lower than a commercially available variant.

View Accepted Manuscript (DOE)

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Hydrogen and Fuel Cell Technologies Office

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1768327

Alternate ID(s):: OSTI ID: 1755967

Report Number(s):: NREL/JA--5900-79255; MainId:33481; UUID:ed2be1ad-ad36-4311-8ec5-b84eb5e3719f; MainAdminID:19775

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 4 Vol. 9; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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