Cobalt-Based Nitride-Core Oxide-Shell Oxygen Reduction Electrocatalysts

Yang, Yao; Zeng, Rui; Xiong, Yin; DiSalvo, Francis J.; Abruña, Héctor D.

doi:10.1021/jacs.9b10809

Cobalt-Based Nitride-Core Oxide-Shell Oxygen Reduction Electrocatalysts

Journal Article · Tue Nov 19 00:00:00 EST 2019 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.9b10809· OSTI ID:1767665

^[1]; ^[2]; Xiong, Yin ^[2]; DiSalvo, Francis J. ^[2]; ^[2]

Cornell Univ., Ithaca, NY (United States); OSTI
Cornell Univ., Ithaca, NY (United States)

Developing high-performance, low-cost, and conductive nonprecious electrocatalysts for the oxygen reduction reaction (ORR) has been a key challenge for advancing fuel cell technologies. Here, we report on a novel family of cobalt nitrides (Co_xN/C, x = 2, 3, 4) as ORR electrocatalysts in alkaline fuel cells. Co₄N/C exhibited the highest ORR activity among the three types of cobalt nitrides studied, with a half-wave potential (E_1/2) of 0.875 V vs RHE in 1 M KOH, rivaling that of commercial Pt/C (0.89 V). Moreover, Co₄N/C showed an 8-fold improvement in mass activity at 0.85 V, when compared to cobalt oxide, Co₃O₄/C, and a negligible degradation (ΔE_1/2 = 14 mV) after 10 000 potential cycles. The superior performance was ascribed to the formation of a conductive nitride core surrounded by a naturally formed thin oxide shell (about 2 nm). Finally, the conductive nitride core effectively mitigated the low conductivity of the metal oxide, and the thin oxide shell on the surface provided the active sites for the ORR. Strategies developed herein represent a promising approach for the design of other novel metal nitrides as electrocatalysts for fuel cells.

View Accepted Manuscript (DOE)

Research Organization:: Cornell Univ., Ithaca, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Alkaline-Based Energy Solutions (CABES)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019445

OSTI ID:: 1767665

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 49 Vol. 141; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Cobalt-Based Nitride-Core Oxide-Shell Oxygen Reduction Electrocatalysts

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