Fundamental Insights into Deactivation by Leaching during Rhenium-Catalyzed Deoxydehydration

Sharkey, Bryan E.; Jentoft, Friederike C.

doi:10.1021/acscatal.9b02806

Title: Fundamental Insights into Deactivation by Leaching during Rhenium-Catalyzed Deoxydehydration

Journal Article · Thu Oct 24 00:00:00 EDT 2019 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.9b02806· OSTI ID:1767644

Sharkey, Bryan E. ^[1];

^[1]

Department of Chemical Engineering, University of Massachusetts Amherst, 686 North Pleasant Street, Amherst, Massachusetts 01003, United States

Not provided.

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI); Univ. of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001004

OSTI ID:: 1767644

Journal Information:: ACS Catalysis, Vol. 9, Issue 12; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (46)

Catalytic conversion of biomass to biofuels Alonso, David Martin; Bond, Jesse Q.; Dumesic, James A. Green Chemistry, Vol. 12, Issue 9, p. 1493-1513 https://doi.org/10.1039/c004654j	journal	January 2010
Toward Nonoxidative Routes to Oxygenated Organics: Stereospecific Deoxydehydration of Diols and Polyols to Alkenes and Allylic Alcohols Catalyzed by the Metal Oxo Complex (C ₅ Me ₅ )ReO ₃ Cook, Gerald K.; Andrews, Mark A. Journal of the American Chemical Society, Vol. 118, Issue 39 https://doi.org/10.1021/ja9620604	journal	January 1996
Catalytic Deoxydehydration of Diols to Olefins by using a Bulky Cyclopentadiene-based Trioxorhenium Catalyst Raju, Suresh; Jastrzebski, Johann T. B. H.; Lutz, Martin ChemSusChem, Vol. 6, Issue 9 https://doi.org/10.1002/cssc.201300364	journal	July 2013
Molybdenum-Catalyzed Deoxydehydration of Vicinal Diols Dethlefsen, Johannes R.; Lupp, Daniel; Oh, Byung-Chang ChemSusChem, Vol. 7, Issue 2 https://doi.org/10.1002/cssc.201300945	journal	January 2014
Molybdenum-Catalyzed Conversion of Diols and Biomass-Derived Polyols to Alkenes Using Isopropyl Alcohol as Reductant and Solvent Dethlefsen, Johannes R.; Lupp, Daniel; Teshome, Ayele ACS Catalysis, Vol. 5, Issue 6 https://doi.org/10.1021/acscatal.5b00427	journal	May 2015
DFT Studies on the Mechanism of the Vanadium-Catalyzed Deoxydehydration of Diols Galindo, Agustín Inorganic Chemistry, Vol. 55, Issue 5 https://doi.org/10.1021/acs.inorgchem.5b02649	journal	February 2016
Carbon Monoxide (CO)- and Hydrogen-Driven, Vanadium-Catalyzed Deoxydehydration of Glycols Gopaladasu, Tirupathi V.; Nicholas, Kenneth M. ACS Catalysis, Vol. 6, Issue 3 https://doi.org/10.1021/acscatal.5b02667	journal	February 2016
Sulfite-Driven, Oxorhenium-Catalyzed Deoxydehydration of Glycols Ahmad, Irshad; Chapman, Garry; Nicholas, Kenneth M. Organometallics, Vol. 30, Issue 10 https://doi.org/10.1021/om2001662	journal	May 2011
Rhenium-Catalyzed Deoxydehydration of Glycols by Sulfite Vkuturi, Saidi; Chapman, Garry; Ahmad, Irshad Inorganic Chemistry, Vol. 49, Issue 11 https://doi.org/10.1021/ic100467p	journal	June 2010
Hydrogen Gas-Mediated Deoxydehydration/Hydrogenation of Sugar Acids: Catalytic Conversion of Glucarates to Adipates Larson, Reed T.; Samant, Andrew; Chen, Jianbin Journal of the American Chemical Society, Vol. 139, Issue 40 https://doi.org/10.1021/jacs.7b07801	journal	October 2017
Elemental Reductants for the Deoxydehydration of Glycols Michael McClain, J.; Nicholas, Kenneth M. ACS Catalysis, Vol. 4, Issue 7 https://doi.org/10.1021/cs500461v	journal	May 2014
Oxo-Rhenium-Catalyzed Deoxydehydration of Polyols with Hydroaromatic Reductants Boucher-Jacobs, Camille; Nicholas, Kenneth M. Organometallics, Vol. 34, Issue 10 https://doi.org/10.1021/acs.organomet.5b00226	journal	May 2015
Catalytic Deoxydehydration of Glycols with Alcohol Reductants Boucher-Jacobs, Camille; Nicholas, Kenneth M. ChemSusChem, Vol. 6, Issue 4 https://doi.org/10.1002/cssc.201200781	journal	March 2013
Mechanism of MTO-Catalyzed Deoxydehydration of Diols to Alkenes Using Sacrificial Alcohols Liu, Shuo; Senocak, Aysegul; Smeltz, Jessica L. Organometallics, Vol. 32, Issue 11 https://doi.org/10.1021/om400127z	journal	March 2013
Expanding the Scope of Biomass-Derived Chemicals through Tandem Reactions Based on Oxorhenium-Catalyzed Deoxydehydration Shiramizu, Mika; Toste, F. Dean Angewandte Chemie International Edition, Vol. 52, Issue 49 https://doi.org/10.1002/anie.201307564	journal	November 2013
Mechanism of Sulfite-Driven, MeReO ₃ -Catalyzed Deoxydehydration of Glycols Liu, Peng; Nicholas, Kenneth M. Organometallics, Vol. 32, Issue 6 https://doi.org/10.1021/om301251z	journal	February 2013
Deoxydehydration of Glycols Catalyzed by Carbon-Supported Perrhenate Denning, Alana L.; Dang, Huong; Liu, Zhimin ChemCatChem, Vol. 5, Issue 12 https://doi.org/10.1002/cctc.201300545	journal	August 2013
ReO _x /TiO ₂ : A Recyclable Solid Catalyst for Deoxydehydration Sandbrink, Lennart; Klindtworth, Elisabeth; Islam, Husn-Ubayda ACS Catalysis, Vol. 6, Issue 2 https://doi.org/10.1021/acscatal.5b01936	journal	December 2015
Hydrodeoxygenation of Vicinal OH Groups over Heterogeneous Rhenium Catalyst Promoted by Palladium and Ceria Support Ota, Nobuhiko; Tamura, Masazumi; Nakagawa, Yoshinao Angewandte Chemie International Edition, Vol. 54, Issue 6 https://doi.org/10.1002/anie.201410352	journal	December 2014
Catalytic conversion of sorbitol to gasoline-ranged products without external hydrogen over Pt-modified Ir-ReO x /SiO 2 Liu, Sibao; Okuyama, Yasuyo; Tamura, Masazumi Catalysis Today, Vol. 269 https://doi.org/10.1016/j.cattod.2015.10.023	journal	July 2016
Deoxydehydration with Molecular Hydrogen over Ceria-Supported Rhenium Catalyst with Gold Promoter Tazawa, Shuhei; Ota, Nobuhiko; Tamura, Masazumi ACS Catalysis, Vol. 6, Issue 10 https://doi.org/10.1021/acscatal.6b01864	journal	August 2016
Highly Selective Deoxydehydration of Tartaric Acid over Supported and Unsupported Rhenium Catalysts with Modified Acidities Li, Xiukai; Zhang, Yugen ChemSusChem, Vol. 9, Issue 19 https://doi.org/10.1002/cssc.201600865	journal	August 2016
New solid oxo-rhenium and oxo-molybdenum catalysts for the deoxydehydration of glycols to olefins Sharkey, Bryan E.; Denning, Alana L.; Jentoft, Friederike C. Catalysis Today, Vol. 310 https://doi.org/10.1016/j.cattod.2017.05.090	journal	July 2018
Hydrogen-Free Gas-Phase Deoxydehydration of 2,3-Butanediol to Butene on Silica-Supported Vanadium Catalysts Kwok, Kelvin Mingyao; Choong, Catherine Kai Shin; Ong, Daniel Sze Wei ChemCatChem, Vol. 9, Issue 13 https://doi.org/10.1002/cctc.201700301	journal	June 2017
Supported Molybdenum Catalysts for the Deoxydehydration of 1,4-Anhydroerythritol into 2,5-Dihydrofuran Sandbrink, Lennart; Beckerle, Klaus; Meiners, Isabell ChemSusChem, Vol. 10, Issue 7 https://doi.org/10.1002/cssc.201700010	journal	March 2017
Deactivation of solid catalysts in liquid media: the case of leaching of active sites in biomass conversion reactions Sádaba, Irantzu; López Granados, Manuel; Riisager, Anders Green Chemistry, Vol. 17, Issue 8 https://doi.org/10.1039/C5GC00804B	journal	January 2015
Why Does Industry Not Use Immobilized Transition Metal Complexes as Catalysts? Hübner, Sandra; de Vries, Johannes G.; Farina, Vittorio Advanced Synthesis & Catalysis, Vol. 358, Issue 1 https://doi.org/10.1002/adsc.201500846	journal	December 2015
Understanding active species in catalytic transformations: From molecular catalysis to nanoparticles, leaching, “Cocktails” of catalysts and dynamic systems Eremin, Dmitry B.; Ananikov, Valentine P. Coordination Chemistry Reviews, Vol. 346 https://doi.org/10.1016/j.ccr.2016.12.021	journal	September 2017
Heterogeneous Catalysts for Liquid-Phase Oxidations: Philosophers' Stones or Trojan Horses? Sheldon, Roger A.; Wallau, Martin; Arends, Isabel W. C. E. Accounts of Chemical Research, Vol. 31, Issue 8 https://doi.org/10.1021/ar9700163	journal	August 1998
Strong evidence of solution-phase catalysis associated with palladium leaching from immobilized thiols during Heck and Suzuki coupling of aryl iodides, bromides, and chlorides Richardson, J.; Jones, C. Journal of Catalysis, Vol. 251, Issue 1 https://doi.org/10.1016/j.jcat.2007.07.005	journal	October 2007
Supported Palladium Catalysts for Suzuki Reactions: Structure-Property Relationships, Optimized Reaction Protocol and Control of Palladium Leaching Köhler, Klaus; Heidenreich, Roland G.; Soomro, Saeeda S. Advanced Synthesis & Catalysis, Vol. 350, Issue 18 https://doi.org/10.1002/adsc.200800575	journal	December 2008
Palladium leaching dependent on reaction parameters in Suzuki–Miyaura coupling reactions catalyzed by palladium supported on alumina under mild reaction conditions Soomro, Saeeda S.; Ansari, Farzana L.; Chatziapostolou, Konstantinos Journal of Catalysis, Vol. 273, Issue 2 https://doi.org/10.1016/j.jcat.2010.05.007	journal	July 2010
A Matter of Life(time) and Death ACS Catalysis, Vol. 8, Issue 9 https://doi.org/10.1021/acscatal.8b03199	journal	August 2018
In Situ Spectroscopic Investigation of the Rhenium-Catalyzed Deoxydehydration of Vicinal Diols Dethlefsen, Johannes R.; Fristrup, Peter ChemCatChem, Vol. 7, Issue 7 https://doi.org/10.1002/cctc.201403012	journal	March 2015
Perrhenate-Catalyzed Deoxydehydration of a Vicinal Diol: A Comparative Density Functional Theory Study Shakeri, Jamaladin; Hadadzadeh, Hassan; Farrokhpour, Hossein The Journal of Physical Chemistry A, Vol. 121, Issue 45 https://doi.org/10.1021/acs.jpca.7b08884	journal	November 2017
Enhanced Metathesis Activity and Stability of Methyltrioxorhenium on a Mostly Amorphous Alumina: Role of the Local Grafting Environment Zhang, Fan; Szeto, Kai C.; Taoufik, Mostafa Journal of the American Chemical Society, Vol. 140, Issue 42 https://doi.org/10.1021/jacs.8b08630	journal	September 2018
Raman and IR studies of surface metal oxide species on oxide supports: Supported metal oxide catalysts Wachs, Israel E. Catalysis Today, Vol. 27, Issue 3-4 https://doi.org/10.1016/0920-5861(95)00203-0	journal	February 1996
Palladium-catalyzed homogeneous and heterogeneous Heck reactions in NMP and water-mixed solvents using organic, inorganic and mixed bases Zhao, Fengyu; Shirai, Masayuki; Arai, Masahiko Journal of Molecular Catalysis A: Chemical, Vol. 154, Issue 1-2 https://doi.org/10.1016/S1381-1169(99)00369-6	journal	March 2000
Control of Pd leaching in Heck reactions of bromoarenes catalyzed by Pd supported on activated carbon Heidenreich, Roland G.; Krauter, Jürgen G. E.; Pietsch, Jörg Journal of Molecular Catalysis A: Chemical, Vol. 182-183 https://doi.org/10.1016/S1381-1169(01)00499-X	journal	May 2002
Highly Active Palladium/Activated Carbon Catalysts for Heck Reactions: Correlation of Activity, Catalyst Properties, and Pd Leaching Köhler, Klaus; Heidenreich, Roland G.; Krauter, Jürgen G. E. Chemistry - A European Journal, Vol. 8, Issue 3 https://doi.org/10.1002/1521-3765(20020201)8:3<622::AID-CHEM622>3.0.CO;2-0	journal	February 2002
In Situ Generation of Highly Active Dissolved Palladium Species from Solid Catalysts—A Concept for the Activation of Aryl Chlorides in the Heck Reaction Pröckl, Sandra S.; Kleist, Wolfgang; Gruber, Markus A. Angewandte Chemie International Edition, Vol. 43, Issue 14 https://doi.org/10.1002/anie.200353473	journal	March 2004
Pd Nanoclusters in CC Coupling Reactions: Proof of Leaching Thathagar, Mehul B.; ten Elshof, Johan E.; Rothenberg, Gadi Angewandte Chemie International Edition, Vol. 45, Issue 18 https://doi.org/10.1002/anie.200504321	journal	April 2006
Poly(4-vinylpyridine) and Quadrapure TU as Selective Poisons for Soluble Catalytic Species in Palladium-Catalyzed Coupling Reactions – Application to Leaching from Polymer-Entrapped Palladium Richardson, John M.; Jones, Christopher W. Advanced Synthesis & Catalysis, Vol. 348, Issue 10-11 https://doi.org/10.1002/adsc.200606021	journal	July 2006
On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review Phan, Nam T. S.; Van Der Sluys, Matthew; Jones, Christopher W. Advanced Synthesis & Catalysis, Vol. 348, Issue 6 https://doi.org/10.1002/adsc.200505473	journal	April 2006
On the Stability and Recyclability of Supported Metal–Ligand Complex Catalysts: Myths, Misconceptions and Critical Research Needs Jones, Christopher W. Topics in Catalysis, Vol. 53, Issue 13-14 https://doi.org/10.1007/s11244-010-9513-9	journal	May 2010
The solubility of water in low-dielectric solvents Kirchnerová, Jitka; Cave, Genille C. B. Canadian Journal of Chemistry, Vol. 54, Issue 24 https://doi.org/10.1139/v76-562	journal	December 1976

Similar Records

New solid oxo-rhenium and oxo-molybdenum catalysts for the deoxydehydration of glycols to olefins

Journal Article · Sun Jul 01 00:00:00 EDT 2018 · Catalysis Today · OSTI ID:1767644

Sharkey, Bryan E.; Denning, Alana L.; Jentoft, Friederike C.; +3 more

CO Oxidation Catalyzed by Gold Supported on MgO: Spectroscopic Identification of Carbonate-Like Species Bonded to Gold During Catalyst Deactivation

Journal Article · Thu Jan 01 00:00:00 EST 2009 · Journal of Catalysis · OSTI ID:1767644

Hao, Y; Mihaylov, M; Ivanova, E; +3 more

Unraveling the Origin of Photocatalytic Deactivation in CeO₂/Nb₂O₅ Heterostructure Systems during Methanol Oxidation: Insight into the Role of Cerium Species

Journal Article · Wed Jun 02 00:00:00 EDT 2021 · Journal of Physical Chemistry. C · OSTI ID:1767644

Wolski, Lukasz; Lebedev, Oleg I.; Harmer, Colin P.; +5 more

Related Subjects

catalysis (homogeneous)
catalysis (heterogeneous)
biofuels (including algae and biomass)
bio-inspired
hydrogen and fuel cells
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)

Title: Fundamental Insights into Deactivation by Leaching during Rhenium-Catalyzed Deoxydehydration

Citation Formats

References (46)

Similar Records

Related Subjects