A Review on Challenges and Successes in Atomic-Scale Design of Catalysts for Electrochemical Synthesis of Hydrogen Peroxide

Siahrostami, Samira; Villegas, Santiago Jimenez; Bagherzadeh Mostaghimi, Amir Hassan; Back, Seoin; Farimani, Amir Barati; Wang, Haotian; Persson, Kristin Aslaug; Montoya, Joseph

doi:10.1021/acscatal.0c01641

Title: A Review on Challenges and Successes in Atomic-Scale Design of Catalysts for Electrochemical Synthesis of Hydrogen Peroxide

Journal Article · Wed Jun 10 00:00:00 EDT 2020 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.0c01641· OSTI ID:1766499

^[1]; Villegas, Santiago Jimenez ^[1]; Bagherzadeh Mostaghimi, Amir Hassan ^[1]; Back, Seoin ^[2];

^[3];

^[4];

^[5]; Montoya, Joseph ^[6]

Univ. of Calgary, AB (Canada)
Sogang Univ. Univ., Seoul (South Korea)
Carnegie Mellon Univ., Pittsburgh, PA (United States)
Rice Univ., Houston, TX (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Toyota Research Inst., Los Altos, CA (United States)

Hydrogen peroxide is a valuable chemical oxidant with a wide range of applications in a variety of industrial processes, especially in water sanitization. Electrochemical synthesis of hydrogen peroxide (H₂O₂) through a two-electron oxygen reduction reaction (2e-ORR) or a two-electron water oxidation reaction (2e-WOR) has emerged as an appealing process for onsite production of this chemically valuable oxidant. On-site produced H₂O₂ can be applied for wastewater treatment in remote locations or any applications where H₂O₂ is needed as an oxidizing agent. Overall, this Review studies the theoretical efforts in understanding the challenges in catalysis for electrochemical synthesis of H₂O₂ as well as providing design principles for more efficient catalyst materials.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1766499

Journal Information:: ACS Catalysis, Vol. 10, Issue 14; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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