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Understanding interface stability in solid-state batteries

Journal Article · · Nature Reviews. Materials
 [1];  [2];  [3];  [4];  [2];  [1]
  1. Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  2. Samsung Research America, Burlington, MA (United States)
  3. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Shanghai Jiao Tong Univ. (China)
  4. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Stevens Institute of Technology, Hoboken, NJ (United States)
Solid-state batteries (SSBs) using a solid electrolyte show potential for providing improved safety as well as higher energy and power density compared with conventional Li-ion batteries. However, two critical bottlenecks remain: the development of solid electrolytes with ionic conductivities comparable to or higher than those of conventional liquid electrolytes and the creation of stable interfaces between SSB components, including the active material, solid electrolyte and conductive additives. Although the first goal has been achieved in several solid ionic conductors, the high impedance at various solid/solid interfaces remains a challenge. Recently, computational models based on ab initio calculations have successfully predicted the stability of solid electrolytes in various systems. In addition, a large amount of experimental data has been accumulated for different interfaces in SSBs. Here, we summarize the experimental findings for various classes of solid electrolytes and relate them to computational predictions, with the aim of providing a deeper understanding of the interfacial reactions and insight for the future design and engineering of interfaces in SSBs. We find that, in general, the electrochemical stability and interfacial reaction products can be captured with a small set of chemical and physical principles.
Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
Samsung Advanced Inst. of Technology; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1765555
Journal Information:
Nature Reviews. Materials, Journal Name: Nature Reviews. Materials Journal Issue: 2 Vol. 5; ISSN 2058-8437
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English

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