Recycling of multilayer plastic packaging materials by solvent-targeted recovery and precipitation

Walker, Theodore W.; Frelka, Nathan; Shen, Zhizhang; Chew, Alex K.; Banick, Jesse; Grey, Steven; Kim, Min Soo; Dumesic, James A.; Van Lehn, Reid C.; Huber, George W.

doi:10.1126/sciadv.aba7599

Recycling of multilayer plastic packaging materials by solvent-targeted recovery and precipitation

Journal Article · Fri Nov 20 00:00:00 EST 2020 · Science Advances

DOI:https://doi.org/10.1126/sciadv.aba7599· OSTI ID:1764997

^[1]; ^[2]; Shen, Zhizhang ^[2]; ^[2]; Banick, Jesse ^[3]; ^[4]; Kim, Min Soo ^[2]; ^[2]; ^[2]; ^[2]

Univ. of Wisconsin, Madison, WI (United States); University of Wisconsin-Madison Department of Chemical and Biological Engineering
Univ. of Wisconsin, Madison, WI (United States)
Univ. of Wisconsin, Madison, WI (United States); Neenah Innovation Center, Neenah, WI (United States)
Neenah Innovation Center, Neenah, WI (United States)

Many plastic packaging materials manufactured today are composites made of distinct polymer layers (i.e., multilayer films). Billions of pounds of these multilayer films are produced annually, but manufacturing inefficiencies result in large, corresponding postindustrial waste streams. Although relatively clean (as opposed to municipal wastes) and of near-constant composition, no commercially practiced technologies exist to fully deconstruct postindustrial multilayer film wastes into pure, recyclable polymers. Here, we demonstrate a unique strategy we call solvent-targeted recovery and precipitation (STRAP) to deconstruct multilayer films into their constituent resins using a series of solvent washes that are guided by thermodynamic calculations of polymer solubility. We show that the STRAP process is able to separate three representative polymers (polyethylene, ethylene vinyl alcohol, and polyethylene terephthalate) from a commercially available multilayer film with nearly 100% material efficiency, affording recyclable resins that are cost-competitive with the corresponding virgin materials.

View Accepted Manuscript (DOE)

Research Organization:: Great Lakes Bioenergy Research Center, Madison, WI (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: SC0018409

OSTI ID:: 1764997

Journal Information:: Science Advances, Journal Name: Science Advances Journal Issue: 47 Vol. 6; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

References (38)

Water absorption in EVOH films and its influence on glass transition temperature Zhang, Zhongbin; Britt, Ian J.; Tung, Marvin A. Journal of Polymer Science Part B: Polymer Physics, Vol. 37, Issue 7 https://doi.org/10.1002/(SICI)1099-0488(19990401)37:7<691::AID-POLB20>3.0.CO;2-V	journal	April 1999
Oxygenated commodity chemicals from chemo-catalytic conversion of biomass derived heterocycles Krishna, Siddarth H.; Huang, Kefeng; Barnett, Kevin J. AIChE Journal, Vol. 64, Issue 6 https://doi.org/10.1002/aic.16172	journal	April 2018
Fast solvent screening via quantum chemistry: COSMO-RS approach Eckert, Frank; Klamt, Andreas AIChE Journal, Vol. 48, Issue 2 https://doi.org/10.1002/aic.690480220	journal	February 2002
Beyond Mechanical Recycling: Giving New Life to Plastic Waste Vollmer, Ina; Jenks, Michael J. F.; Roelands, Mark C. P. Angewandte Chemie International Edition, Vol. 59, Issue 36 https://doi.org/10.1002/anie.201915651	journal	June 2020
Prediction of aqueous solubility of drugs and pesticides with COSMO-RS Klamt, Andreas; Eckert, Frank; Hornig, Martin Journal of Computational Chemistry, Vol. 23, Issue 2 https://doi.org/10.1002/jcc.1168	journal	January 2002
Development and testing of a general amber force field Wang, Junmei; Wolf, Romain M.; Caldwell, James W. Journal of Computational Chemistry, Vol. 25, Issue 9 https://doi.org/10.1002/jcc.20035	journal	January 2004
Crystallization of polyethylene terephthalate Cobbs, W. H.; Burton, R. L. Journal of Polymer Science, Vol. 10, Issue 3 https://doi.org/10.1002/pol.1953.120100302	journal	March 1953
The selective dissolution/precipitation technique for polymer recycling: a pilot unit application Pappa, Georgia; Boukouvalas, Christos; Giannaris, Constantinos Resources, Conservation and Recycling, Vol. 34, Issue 1 https://doi.org/10.1016/S0921-3449(01)00092-1	journal	December 2001
Mechanical and thermal properties of thermoplastic acetylated starch/poly(ethylene-co-vinyl alcohol) blends Jiang, Wenbo; Qiao, Xiuying; Sun, Kang Carbohydrate Polymers, Vol. 65, Issue 2 https://doi.org/10.1016/j.carbpol.2005.12.038	journal	July 2006
Techno-economic analysis of gasification routes for ammonia production from Victorian brown coal Habgood, David C. C.; Hoadley, Andrew F. A.; Zhang, Lian Chemical Engineering Research and Design, Vol. 102 https://doi.org/10.1016/j.cherd.2015.06.008	journal	October 2015
Determination of volatile organic compounds in recycled polyethylene terephthalate and high-density polyethylene by headspace solid phase microextraction gas chromatography mass spectrometry to evaluate the efficiency of recycling processes Dutra, Camila; Pezo, Davinson; Freire, Maria Teresa de Alvarenga Journal of Chromatography A, Vol. 1218, Issue 10 https://doi.org/10.1016/j.chroma.2010.12.099	journal	March 2011
A Cost-effectiveness Analysis for Incineration or Recycling of Dutch Household Plastic Waste Gradus, Raymond H. J. M.; Nillesen, Paul H. L.; Dijkgraaf, Elbert Ecological Economics, Vol. 135 https://doi.org/10.1016/j.ecolecon.2016.12.021	journal	May 2017
Chemical recycling of plastic wastes made from polyethylene (LDPE and HDPE) and polypropylene (PP) Achilias, D. S.; Roupakias, C.; Megalokonomos, P. Journal of Hazardous Materials, Vol. 149, Issue 3 https://doi.org/10.1016/j.jhazmat.2007.06.076	journal	November 2007
Automatic atom type and bond type perception in molecular mechanical calculations Wang, Junmei; Wang, Wei; Kollman, Peter A. Journal of Molecular Graphics and Modelling, Vol. 25, Issue 2 https://doi.org/10.1016/j.jmgm.2005.12.005	journal	October 2006
Combining Reclaimed PET with Bio-based Monomers Enables Plastics Upcycling Rorrer, Nicholas A.; Nicholson, Scott; Carpenter, Alberta Joule, Vol. 3, Issue 4 https://doi.org/10.1016/j.joule.2019.01.018	journal	April 2019
Material flow analysis of polyethylene terephthalate in the US, 1996–2007 Kuczenski, Brandon; Geyer, Roland Resources, Conservation and Recycling, Vol. 54, Issue 12 https://doi.org/10.1016/j.resconrec.2010.03.013	journal	October 2010
LCA of plastic waste recovery into recycled materials, energy and fuels in Singapore Khoo, Hsien H. Resources, Conservation and Recycling, Vol. 145 https://doi.org/10.1016/j.resconrec.2019.02.010	journal	June 2019
Environmental and health hazard ranking and assessment of plastic polymers based on chemical composition Lithner, Delilah; Larsson, Åke; Dave, Göran Science of The Total Environment, Vol. 409, Issue 18 https://doi.org/10.1016/j.scitotenv.2011.04.038	journal	August 2011
GROMACS: High performance molecular simulations through multi-level parallelism from laptops to supercomputers Abraham, Mark James; Murtola, Teemu; Schulz, Roland SoftwareX, Vol. 1-2 https://doi.org/10.1016/j.softx.2015.06.001	journal	September 2015
Recycling and recovery routes of plastic solid waste (PSW): A review Al-Salem, S. M.; Lettieri, P.; Baeyens, J. Waste Management, Vol. 29, Issue 10 https://doi.org/10.1016/j.wasman.2009.06.004	journal	October 2009
Plastic flexible films waste management – A state of art review Horodytska, O.; Valdés, F. J.; Fullana, A. Waste Management, Vol. 77 https://doi.org/10.1016/j.wasman.2018.04.023	journal	July 2018
Solvent Selection for the Separation of Lignin-Derived Monomers Using the Conductor-like Screening Model for Real Solvents Shen, Zhizhang; Van Lehn, Reid C. Industrial & Engineering Chemistry Research, Vol. 59, Issue 16 https://doi.org/10.1021/acs.iecr.9b06086	journal	March 2020
Method for Efficient Recovery of High-Purity Polycarbonates from Electronic Waste Weeden, George S.; Soepriatna, Nicholas H.; Wang, Nien-Hwa Linda Environmental Science & Technology, Vol. 49, Issue 4 https://doi.org/10.1021/es5055786	journal	January 2015
Prediction of Solubilities and Partition Coefficients in Polymers Using COSMO-RS Loschen, Christoph; Klamt, Andreas Industrial & Engineering Chemistry Research, Vol. 53, Issue 28 https://doi.org/10.1021/ie501669z	journal	July 2014
Selective Conversion of D -Fructose to 5-Hydroxymethylfurfural by Ion-Exchange Resin in Acetone/Dimethyl sulfoxide Solvent Mixtures Qi, Xinhua; Watanabe, Masaru; Aida, Taku M. Industrial & Engineering Chemistry Research, Vol. 47, Issue 23 https://doi.org/10.1021/ie801016s	journal	December 2008
Conductor-like Screening Model for Real Solvents: A New Approach to the Quantitative Calculation of Solvation Phenomena Klamt, Andreas The Journal of Physical Chemistry, Vol. 99, Issue 7 https://doi.org/10.1021/j100007a062	journal	February 1995
Polyglyoxylates: A Versatile Class of Triggerable Self-Immolative Polymers from Readily Accessible Monomers Fan, Bo; Trant, John F.; Wong, Andrew D. Journal of the American Chemical Society, Vol. 136, Issue 28 https://doi.org/10.1021/ja504727u	journal	June 2014
Refinement and Parametrization of COSMO-RS Klamt, Andreas; Jonas, Volker; Bürger, Thorsten The Journal of Physical Chemistry A, Vol. 102, Issue 26 https://doi.org/10.1021/jp980017s	journal	June 1998
Self-Immolative Polymers Containing Rapidly Cyclizing Spacers: Toward Rapid Depolymerization Rates Chen, Eric K. Y.; McBride, Ryan A.; Gillies, Elizabeth R. Macromolecules, Vol. 45, Issue 18 https://doi.org/10.1021/ma301667c	journal	September 2012
Methanol Absorption in Ethylene−Vinyl Alcohol Copolymers: Relation between Solvent Diffusion and Changes in Glass Transition Temperature in Glassy Polymeric Materials Samus, Marsha A.; Rossi, Giuseppe Macromolecules, Vol. 29, Issue 6 https://doi.org/10.1021/ma950767p	journal	January 1996
Classify plastic waste as hazardous Rochman, Chelsea M.; Browne, Mark Anthony; Halpern, Benjamin S. Nature, Vol. 494, Issue 7436 https://doi.org/10.1038/494169a	journal	February 2013
Advanced chemical recycling of poly(ethylene terephthalate) through organocatalytic aminolysis Fukushima, Kazuki; Lecuyer, Julien M.; Wei, Di S. Polym. Chem., Vol. 4, Issue 5 https://doi.org/10.1039/C2PY20793A	journal	January 2013
The transitions of polyethylene terephthalate Thompson, A. B.; Woods, D. W. Transactions of the Faraday Society, Vol. 52 https://doi.org/10.1039/tf9565201383	journal	January 1956
Waste to Wealth: The Circular Economy Advantage Lacy, Peter; Rutqvist, Jakob https://doi.org/10.1057/9781137530707	book	January 2015
Preparation and characterization of reactive blends of poly(lactic acid), poly(ethylene-co-vinyl alcohol), and poly(ethylene-co-glycidyl methacrylate) Warangkhana, Phromma; C., Jana Sadhan; Rathanawan, Magaraphan PROCEEDINGS OF PPS-30: The 30th International Conference of the Polymer Processing Society – Conference Papers, AIP Conference Proceedings https://doi.org/10.1063/1.4918397	conference	January 2015
The future of plastics recycling Garcia, Jeannette M.; Robertson, Megan L. Science, Vol. 358, Issue 6365 https://doi.org/10.1126/science.aaq0324	journal	November 2017
Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels. Thermochemical Research Pathways with In Situ and Ex Situ Upgrading of Fast Pyrolysis Vapors Dutta, Abhijit; Sahir, Asad; Tan, Eric https://doi.org/10.2172/1215007	report	March 2015
Optimal Method for Production of Amorphous Cellulose with Increased Enzymatic Digestibility Ioelovich, Michael Organic Polymer Material Research, Vol. 1, Issue 1 https://doi.org/10.30564/opmr.v1i1.1301	journal	October 2019

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