Capture and Decomposition of the Nerve Agent Simulant, DMCP, Using the Zeolitic Imidazolate Framework (ZIF-8)

Ebrahim, Amani M.; Plonka, Anna M.; Rui, Ning; Hwang, Sooyeon; Gordon, Wesley O.; Balboa, Alex; Senanayake, Sanjaya D.; Frenkel, Anatoly I.

doi:10.1021/acsami.0c12985

Capture and Decomposition of the Nerve Agent Simulant, DMCP, Using the Zeolitic Imidazolate Framework (ZIF-8)

Journal Article · Tue Dec 15 23:00:00 EST 2020 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.0c12985· OSTI ID:1764592

^[1]; ^[1]; Rui, Ning ^[2]; ^[2]; ^[3]; Balboa, Alex ^[3]; ^[2]; ^[4]

Stony Brook Univ., NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
U.S. Army Combat Capabilities Development Command Chemical Biological Center, Aberdeen Proving Ground, MD (United States)
Stony Brook Univ., NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Understanding mechanisms of decontamination of chemical warfare agents (CWA) is an area of intense research aimed at developing new filtration materials to protect soldiers and civilians in case of state-sponsored or terrorist attack. In this study, we employed complementary structural, chemical, and dynamic probes and in situ data collection, to elucidate the complex chemistry, capture, and decomposition of the CWA simulant, dimethyl chlorophosphonate (DMCP). Our work reveals key details of the reactive adsorption of DMCP and demonstrates the versatility of zeolitic imidazolate framework (ZIF-8) as a plausible material for CWA capture and decomposition. Here, the in situ synchrotron-based powder X-ray diffraction (PXRD) and pair distribution function (PDF) studies, combined with Fourier transform infrared (FT-IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), zinc K-edge X-ray absorption near edge structure (XANES), and Raman spectroscopies, showed that the unique structure, chemical state, and topology of ZIF-8 enable accessibility, adsorption, and hydrolysis of DMCP into the pores and revealed the importance of linker chemistry and Zn²⁺ sites for nerve agent decomposition. DMCP decontamination and decomposition product(s) formation were observed by thermogravimetric analysis, FT-IR spectroscopy, and phosphorus (P) K-edge XANES studies. Differential PDF analysis indicated that the average structure of ZIF-8 (at the 30 Å scale) remains unchanged after DMCP dosing and provided information on the dynamics of interactions of DMCP with the ZIF-8 framework. Using in situ PXRD and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), we showed that nearly 90% regeneration of the ZIF-8 structure and complete liberation of DMCP and decomposition products occur upon heating.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1764592

Report Number(s):: BNL--220986-2021-JAAM

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 52 Vol. 12; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (69)

The Effect of Pressure on ZIF-8: Increasing Pore Size with Pressure and the Formation of a High-Pressure Phase at 1.47 GPa Moggach, Stephen A.; Bennett, Thomas D.; Cheetham, Anthony K. Angewandte Chemie International Edition, Vol. 48, Issue 38 https://doi.org/10.1002/anie.200902643	journal	September 2009
Adsorption of CO ₂ , CH ₄ , and N ₂ on Zeolitic Imidazolate Frameworks: Experiments and Simulations Pérez-Pellitero, Javier; Amrouche, Hedi; Siperstein, Flor R. Chemistry - A European Journal, Vol. 16, Issue 5 https://doi.org/10.1002/chem.200902144	journal	February 2010
Zeolitic Imidazolate Framework‐8 as pH‐Sensitive Nanocarrier for “Arsenic Trioxide” Drug Delivery Ettlinger, Romy; Moreno, Natalia; Volkmer, Dirk Chemistry – A European Journal, Vol. 25, Issue 57 https://doi.org/10.1002/chem.201902599	journal	September 2019
The influence of the size and position of the alkyl groups in alkylimidazole molecules on their acid-base properties Lenarcik, Beniamin; Ojczenasz, Piotr Journal of Heterocyclic Chemistry, Vol. 39, Issue 2 https://doi.org/10.1002/jhet.5570390206	journal	March 2002
An attempt to assess functionally minimal acetylcholinesterase activity necessary for survival of rats intoxicated with nerve agents Bajgar, Jiri; Fusek, Josef; Kassa, Jiri Chemico-Biological Interactions, Vol. 175, Issue 1-3 https://doi.org/10.1016/j.cbi.2008.05.015	journal	September 2008
Key mechanistic details of paraoxon decomposition by polyoxometalates: Critical role of para-nitro substitution Kaledin, Alexey L.; Troya, Diego; Karwacki, Christopher J. Chemical Physics, Vol. 518 https://doi.org/10.1016/j.chemphys.2018.11.013	journal	February 2019
Ultra-fast catalytic detoxification of organophosphates by nano-zeolitic imidazolate frameworks Ebrahimi, Arash; Nassireslami, Ehsan; Zibaseresht, Ramin Molecular Catalysis, Vol. 490 https://doi.org/10.1016/j.mcat.2020.110965	journal	July 2020
Rapid adsorption and removal of sulfur mustard with zeolitic imidazolate frameworks ZIF-8 and ZIF-67 Son, Ye-Rim; Ryu, Sam Gon; Kim, Hyun Sung Microporous and Mesoporous Materials, Vol. 293 https://doi.org/10.1016/j.micromeso.2019.109819	journal	February 2020
Mechanisms of Degradation of Toxic Nerve Agents: Quantum-chemical Insight into Interactions of Sarin and Soman with Molybdenum Dioxide Tsyshevsky, Roman; Head, Ashley R.; Trotochaud, Lena Surface Science, Vol. 700 https://doi.org/10.1016/j.susc.2020.121639	journal	October 2020
Effect of Carbon Dioxide on the Degradation of Chemical Warfare Agent Simulant in the Presence of Zr Metal Organic Framework MOF-808 Plonka, Anna M.; Grissom, Tyler G.; Musaev, Djamaladdin G. Chemistry of Materials, Vol. 31, Issue 23 https://doi.org/10.1021/acs.chemmater.9b04565	journal	November 2019
Metal–Organic Frameworks against Toxic Chemicals Islamoglu, Timur; Chen, Zhijie; Wasson, Megan C. Chemical Reviews, Vol. 120, Issue 16 https://doi.org/10.1021/acs.chemrev.9b00828	journal	March 2020
Irreversible Change of the Pore Structure of ZIF-8 in Carbon Dioxide Capture with Water Coexistence Liu, Huang; Guo, Ping; Regueira, Teresa The Journal of Physical Chemistry C, Vol. 120, Issue 24 https://doi.org/10.1021/acs.jpcc.6b03772	journal	June 2016
Structure and Electronic Properties of a Continuous Random Network Model of an Amorphous Zeolitic Imidazolate Framework (a-ZIF) Adhikari, Puja; Xiong, Mo; Li, Neng The Journal of Physical Chemistry C, Vol. 120, Issue 28 https://doi.org/10.1021/acs.jpcc.6b06337	journal	July 2016
Mechanism and Kinetics for Reaction of the Chemical Warfare Agent Simulant, DMMP( g ), with Zirconium(IV) MOFs: An Ultrahigh-Vacuum and DFT Study Wang, G.; Sharp, C.; Plonka, A. M. The Journal of Physical Chemistry C, Vol. 121, Issue 21 https://doi.org/10.1021/acs.jpcc.7b00070	journal	May 2017
Design, Synthesis, and Characterization of Metal–Organic Frameworks for Enhanced Sorption of Chemical Warfare Agent Simulants Ruffley, Jonathan P.; Goodenough, Isabella; Luo, Tian-Yi The Journal of Physical Chemistry C, Vol. 123, Issue 32 https://doi.org/10.1021/acs.jpcc.9b05574	journal	July 2019
Correlated Multimodal Approach Reveals Key Details of Nerve-Agent Decomposition by Single-Site Zr-Based Polyoxometalates Tian, Yiyao; Plonka, Anna M.; Ebrahim, Amani M. The Journal of Physical Chemistry Letters, Vol. 10, Issue 9 https://doi.org/10.1021/acs.jpclett.9b01002	journal	April 2019
Determining Diffusion Coefficients of Chemical Warfare Agents in Metal–Organic Frameworks Agrawal, Mayank; Boulfelfel, Salah E.; Sava Gallis, Dorina F. The Journal of Physical Chemistry Letters, Vol. 10, Issue 24 https://doi.org/10.1021/acs.jpclett.9b03119	journal	November 2019
Nucleophilic Polymers and Gels in Hydrolytic Degradation of Chemical Warfare Agents Bromberg, Lev; Creasy, William R.; McGarvey, David J. ACS Applied Materials & Interfaces, Vol. 7, Issue 39 https://doi.org/10.1021/acsami.5b06905	journal	September 2015
Poly High Internal Phase Emulsion for the Immobilization of Chemical Warfare Agents Wright, Alexander J.; Main, Marcus J.; Cooper, Nicholas J. ACS Applied Materials & Interfaces, Vol. 9, Issue 37 https://doi.org/10.1021/acsami.7b09188	journal	September 2017
Carbon Textiles Modified with Copper-Based Reactive Adsorbents as Efficient Media for Detoxification of Chemical Warfare Agents Florent, Marc; Giannakoudakis, Dimitrios A.; Wallace, Rajiv ACS Applied Materials & Interfaces, Vol. 9, Issue 32 https://doi.org/10.1021/acsami.7b10682	journal	August 2017
Environmental Effects on Zirconium Hydroxide Nanoparticles and Chemical Warfare Agent Decomposition: Implications of Atmospheric Water and Carbon Dioxide Balow, Robert B.; Lundin, Jeffrey G.; Daniels, Grant C. ACS Applied Materials & Interfaces, Vol. 9, Issue 45 https://doi.org/10.1021/acsami.7b10902	journal	October 2017
Triazine-Based Covalent Organic Framework: A Promising Sorbent for Efficient Elimination of the Hydrocarbon Backgrounds of Organic Sample for GC–MS and ¹ H NMR Analysis of Chemical Weapons Convention Related Compounds Sinha Roy, Kanchan; Goud D., Raghavender; Mazumder, Avik ACS Applied Materials & Interfaces, Vol. 11, Issue 17 https://doi.org/10.1021/acsami.9b02354	journal	April 2019
Swell and Destroy: A Metal–Organic Framework-Containing Polymer Sponge That Immobilizes and Catalytically Degrades Nerve Agents Kalinovskyy, Yaroslav; Wright, Alexander J.; Hiscock, Jennifer R. ACS Applied Materials & Interfaces, Vol. 12, Issue 7 https://doi.org/10.1021/acsami.9b18478	journal	January 2020
Insights into Catalytic Gas-Phase Hydrolysis of Organophosphate Chemical Warfare Agents by MOF-Supported Bimetallic Metal-Oxo Clusters Chen, Haoyuan; Snurr, Randall Q. ACS Applied Materials & Interfaces, Vol. 12, Issue 13 https://doi.org/10.1021/acsami.9b19484	journal	January 2020
Multimodal Characterization of Materials and Decontamination Processes for Chemical Warfare Protection Ebrahim, Amani M.; Plonka, Anna M.; Tian, Yiyao ACS Applied Materials & Interfaces, Vol. 12, Issue 13 https://doi.org/10.1021/acsami.9b19494	journal	December 2019
Zirconium-Based Metal–Organic Frameworks for the Catalytic Hydrolysis of Organophosphorus Nerve Agents Kirlikovali, Kent O.; Chen, Zhijie; Islamoglu, Timur ACS Applied Materials & Interfaces, Vol. 12, Issue 13 https://doi.org/10.1021/acsami.9b20154	journal	January 2020
Metal–Organic Framework- and Polyoxometalate-Based Sorbents for the Uptake and Destruction of Chemical Warfare Agents Grissom, Tyler G.; Plonka, Anna M.; Sharp, Conor H. ACS Applied Materials & Interfaces, Vol. 12, Issue 13 https://doi.org/10.1021/acsami.9b20833	journal	January 2020
High-Throughput Screening of MOFs for Breakdown of V-Series Nerve Agents Palomba, Joseph M.; Harvey, Steven P.; Kalaj, Mark ACS Applied Materials & Interfaces, Vol. 12, Issue 13 https://doi.org/10.1021/acsami.9b21693	journal	January 2020
Bio-Inspired Polydopamine-Mediated Zr-MOF Fabrics for Solar Photothermal-Driven Instantaneous Detoxification of Chemical Warfare Agent Simulants Yao, Aonan; Jiao, Xiuling; Chen, Dairong ACS Applied Materials & Interfaces, Vol. 12, Issue 16 https://doi.org/10.1021/acsami.9b22242	journal	March 2020
Decomposition of Chemical Warfare Agent Simulants Utilizing Pyrolyzed Cotton Balls as Wicks Lagasse, Bryan A.; McCann, Laura; Kidwell, Timothy ACS Omega, Vol. 5, Issue 32 https://doi.org/10.1021/acsomega.0c01619	journal	July 2020
Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks Phan, Anh; Doonan, Christian J.; Uribe-Romo, Fernando J. Accounts of Chemical Research, Vol. 43, Issue 1, p. 58-67 https://doi.org/10.1021/ar900116g	journal	January 2010
Interactions of histidine and other imidazole derivatives with transition metal ions in chemical and biological systems Sundberg, Richard J.; Martin, R. Bruce Chemical Reviews, Vol. 74, Issue 4 https://doi.org/10.1021/cr60290a003	journal	August 1974
Indoor Sorption of Surrogates for Sarin and Related Nerve Agents Singer, Brett C.; Hodgson, Alfred T.; Destaillats, Hugo Environmental Science & Technology, Vol. 39, Issue 9 https://doi.org/10.1021/es049144u	journal	May 2005
Imidazole and Imidazolate Iron Complexes: On the Way for Tuning 3D-Structural Characteristics and Reactivity. Redox Interconversions Controlled by Protonation State Lambert, François; Policar, Clotilde; Durot, Stephanie Inorganic Chemistry, Vol. 43, Issue 14 https://doi.org/10.1021/ic0498687	journal	July 2004
The Tautomeric Character of the Imidazole Ring Green, Harry; Day, Allan R. Journal of the American Chemical Society, Vol. 64, Issue 5 https://doi.org/10.1021/ja01257a047	journal	May 1942
Capture of Volatile Iodine, a Gaseous Fission Product, by Zeolitic Imidazolate Framework-8 Sava, Dorina F.; Rodriguez, Mark A.; Chapman, Karena W. Journal of the American Chemical Society, Vol. 133, Issue 32 https://doi.org/10.1021/ja204757x	journal	August 2011
Evidence of Pressure Enhanced CO ₂ Storage in ZIF-8 Probed by FTIR Spectroscopy Hu, Yue; Liu, Zhenxian; Xu, Jun Journal of the American Chemical Society, Vol. 135, Issue 25 https://doi.org/10.1021/ja403635b	journal	June 2013
Thermochemical Evidence for Strong Iodine Chemisorption by ZIF-8 Hughes, James T.; Sava, Dorina F.; Nenoff, Tina M. Journal of the American Chemical Society, Vol. 135, Issue 44 https://doi.org/10.1021/ja406081r	journal	October 2013
Highly Tunable Molecular Sieving and Adsorption Properties of Mixed-Linker Zeolitic Imidazolate Frameworks Eum, Kiwon; Jayachandrababu, Krishna C.; Rashidi, Fereshteh Journal of the American Chemical Society, Vol. 137, Issue 12 https://doi.org/10.1021/jacs.5b00803	journal	March 2015
Scalable and Template-Free Aqueous Synthesis of Zirconium-Based Metal–Organic Framework Coating on Textile Fiber Ma, Kaikai; Islamoglu, Timur; Chen, Zhijie Journal of the American Chemical Society, Vol. 141, Issue 39 https://doi.org/10.1021/jacs.9b07301	journal	September 2019
Infrared Spectra and Binding Energies of Chemical Warfare Nerve Agent Simulants on the Surface of Amorphous Silica Wilmsmeyer, Amanda R.; Gordon, Wesley O.; Davis, Erin Durke The Journal of Physical Chemistry C, Vol. 117, Issue 30 https://doi.org/10.1021/jp404265s	journal	July 2013
Temperature Induced Structural Transformations and Gas Adsorption in the Zeolitic Imidazolate Framework ZIF-8: A Raman Study Kumari, Gayatri; Jayaramulu, Kolleboyina; Maji, Tapas Kumar The Journal of Physical Chemistry A, Vol. 117, Issue 43 https://doi.org/10.1021/jp407792a	journal	October 2013
Understanding Gas-Induced Structural Deformation of ZIF-8 Ania, Conchi O.; García-Pérez, E.; Haro, M. The Journal of Physical Chemistry Letters, Vol. 3, Issue 9 https://doi.org/10.1021/jz300292y	journal	April 2012
Interactions and Binding Energies of Dimethyl Methylphosphonate and Dimethyl Chlorophosphate with Amorphous Silica Wilmsmeyer, Amanda R.; Uzarski, Joshua; Barrie, Patrick J. Langmuir, Vol. 28, Issue 30 https://doi.org/10.1021/la301938f	journal	July 2012
Destruction of chemical warfare agents using metal–organic frameworks Mondloch, Joseph E.; Katz, Michael J.; Isley III, William C. Nature Materials, Vol. 14, Issue 5 https://doi.org/10.1038/nmat4238	journal	March 2015
Understanding the adsorption process in ZIF-8 using high pressure crystallography and computational modelling Hobday, Claire L.; Woodall, Christopher H.; Lennox, Matthew J. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03878-6	journal	April 2018
Proton mediated spin state transition of cobalt heme analogs Zhao, Jianping; Peng, Qian; Wang, Zijian Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10357-z	journal	May 2019
Atomic-Level Structural Dynamics of Polyoxoniobates during DMMP Decomposition Wang, Qi; Chapleski, Robert C.; Plonka, Anna M. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-00772-x	journal	April 2017
Gate-opening effect in ZIF-8: the first experimental proof using inelastic neutron scattering Casco, M. E.; Cheng, Y. Q.; Daemen, L. L. Chemical Communications, Vol. 52, Issue 18 https://doi.org/10.1039/C5CC10222G	journal	January 2016
Diffusion as a function of guest molecule length and functionalization in flexible metal–organic frameworks Zheng, B.; Wang, L. L.; Du, L. Materials Horizons, Vol. 3, Issue 4 https://doi.org/10.1039/C6MH00047A	journal	January 2016
Adsorption mechanism on metal organic frameworks of Cu-BTC, Fe-BTC and ZIF-8 for CO ₂ capture investigated by X-ray absorption fine structure Du, Meng; Li, Lina; Li, Mingxing RSC Advances, Vol. 6, Issue 67 https://doi.org/10.1039/C6RA07582G	journal	January 2016
Metal–organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents Bobbitt, N. Scott; Mendonca, Matthew L.; Howarth, Ashlee J. Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C7CS00108H	journal	January 2017
Early stage structural development of prototypical zeolitic imidazolate framework (ZIF) in solution Terban, Maxwell W.; Banerjee, Debasis; Ghose, Sanjit Nanoscale, Vol. 10, Issue 9 https://doi.org/10.1039/C7NR07949D	journal	January 2018
Flux melting of metal–organic frameworks Longley, Louis; Collins, Sean M.; Li, Shichun Chemical Science, Vol. 10, Issue 12 https://doi.org/10.1039/C8SC04044C	journal	January 2019
An effective “precursor-transformation” route toward the high-yield synthesis of ZIF-8 tubes Liu, Ziyi; Wu, Aiping; Yan, Haijing Chemical Communications, Vol. 56, Issue 19 https://doi.org/10.1039/C9CC08724A	journal	January 2020
Degradation of ZIF-8 in phosphate buffered saline media Velásquez-Hernández, Miriam de J.; Ricco, Raffaele; Carraro, Francesco CrystEngComm, Vol. 21, Issue 31 https://doi.org/10.1039/C9CE00757A	journal	January 2019
Amorphization of the prototypical zeolitic imidazolate framework ZIF-8 by ball-milling Cao, Shuai; Bennett, Thomas D.; Keen, David A. Chemical Communications, Vol. 48, Issue 63 https://doi.org/10.1039/c2cc33773h	journal	January 2012
Flexibility and swing effect on the adsorption of energy-related gases on ZIF-8: combined experimental and simulation study Fairen-Jimenez, David; Galvelis, Raimondas; Torrisi, Antonio Dalton Transactions, Vol. 41, Issue 35 https://doi.org/10.1039/c2dt30774j	journal	January 2012
Comparison of the complexing processes of 1-butyl-2-hydroxymethylimidazole and 1-butyl-2-methylimidazole in aqueous solution Barszcz, Barbara; Kulig, Jacek Journal of the Chemical Society, Dalton Transactions, Issue 10 https://doi.org/10.1039/dt9930001559	journal	January 1993
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks Park, K. S.; Ni, Z.; Cote, A. P. Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191 https://doi.org/10.1073/pnas.0602439103	journal	June 2006
Characterization of the Zirconium Metal-Organic Framework (MOF) UiO-66-NH ₂ for the Decomposition of Nerve Agents in Solid-State Conditions Using Phosphorus-31 Solid State-Magic Angle Spinning Nuclear Magnetic Resonance ( ³¹ P SS-MAS NMR) and Gas Chromatography – Mass Spectrometry (GC-MS) Jung, Hyunsook; Kim, Min-Kun; Lee, Juno Analytical Letters, Vol. 54, Issue 3 https://doi.org/10.1080/00032719.2020.1768399	journal	May 2020
PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals Farrow, C. L.; Juhas, P.; Liu, J. W. Journal of Physics: Condensed Matter, Vol. 19, Issue 33 https://doi.org/10.1088/0953-8984/19/33/335219	journal	July 2007
Chemical warfare agents Geoghegan, James; Tong, Jeffrey L. Continuing Education in Anaesthesia Critical Care & Pain, Vol. 6, Issue 6 https://doi.org/10.1093/bjaceaccp/mkl052	journal	December 2006
Metal ion-dependent hydrolysis of RNA phosphodiester bonds within hairpin loops. A comparative kinetic study on chimeric ribo/2'-O-methylribo oligonucleotides Zagorowska, I.; Kuusela, S.; Lonnberg, H. Nucleic Acids Research, Vol. 26, Issue 14 https://doi.org/10.1093/nar/26.14.3392	journal	July 1998
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
FIT2D : a multi-purpose data reduction, analysis and visualization program Hammersley, A. P. Journal of Applied Crystallography, Vol. 49, Issue 2 https://doi.org/10.1107/S1600576716000455	journal	March 2016
Effects of the Metal Ion on the Mechanism of Phosphodiester Hydrolysis Catalyzed by Metal-Cyclen Complexes Hu, Qiaoyu; Jayasinghe-Arachchige, Vindi M.; Zuchniarz, Joshua Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00195	journal	April 2019
Chemical warfare agents Ganesan, K.; Raza, Sk; Vijayaraghavan, R. Journal of Pharmacy and Bioallied Sciences, Vol. 2, Issue 3 https://doi.org/10.4103/0975-7406.68498	journal	January 2010

Similar Records

Correlated Multimodal Approach Reveals Key Details of Nerve-Agent Decomposition by Single-Site Zr-Based Polyoxometalates

Journal Article · Fri Apr 19 00:00:00 EDT 2019 · Journal of Physical Chemistry Letters · OSTI ID:1525399

Effect of Carbon Dioxide on the Degradation of Chemical Warfare Agent Simulant in the Presence of Zr Metal Organic Framework MOF-808

Journal Article · Sun Nov 10 23:00:00 EST 2019 · Chemistry of Materials · OSTI ID:1577425

An investigation on the structural stability of $\mathrm{ZIF}$-8 in water versus water-derived oxidative species in aqueous environment

Journal Article · Thu Dec 21 23:00:00 EST 2023 · Microporous and Mesoporous Materials · OSTI ID:2324578

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
ZIF-8
adsorption
chemical warfare agents
decomposition
desorption
in situ multimodal
metal organic frameworks
organic reactions
physical and chemical processes
regeneration

Capture and Decomposition of the Nerve Agent Simulant, DMCP, Using the Zeolitic Imidazolate Framework (ZIF-8)

Citation Formats

References (69)

Similar Records

Related Subjects