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In situ polymerized succinonitrile-based solid polymer electrolytes for lithium ion batteries

Journal Article · · Solid State Ionics
 [1];  [2];  [3];  [4];  [5];  [6];  [7];  [3]
  1. Tianjin Univ. (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
  2. Tianjin Univ. (China)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  5. National Key Laboratory of Science and Technology on Power Sources, Tianjin (China)
  6. Tianjin Univ. (China); National Key Laboratory of Science and Technology on Power Sources, Tianjin (China)
  7. Tianjin Univ. (China); Shihezi Univ. (China)
+ Show Author Affiliations
Novel solid polymer electrolytes based on succinonitrile (SN) plastic crystal electrolyte (SN-PCE) and polymerized ionic liquid (PIL) has been successfully synthesized via an in-situ method. The fabricated electrolyte (PIL-SN-PCE) is uniformly inlayed into the supporting matrix of polyimide, which effectively ameliorates the mechanical properties of the electrolyte. PIL can effectively enhance the thermal stability of electrolytes up to 300 °C and mitigate the parasitic reactions between the electrolytes and the electrodes. PIL-SN-PCE exhibits a remarkable oxidation ability up to 5.4 V vs Li/Li+ and a high room temperature ionic conductivity of 6.54 × 10-4 S cm-1. Furthermore, in-situ formed interface in PIL-SN-PCE guarantee an excellent compatibility with different electrodes, which can effectively improve the cycle stability and rate performances of both half-cells and full cells. Finally, PIL-SN-PCE is considered as a promising electrolyte for high energy density lithium-ion batteries.
Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China (NNSFC); Program for Chang jiang Scholars and Innovative Research Team in University; Foundation of National Key Laboratory of Science and Technology on Power Sources
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1761672
Alternate ID(s):
OSTI ID: 1698105
Journal Information:
Solid State Ionics, Journal Name: Solid State Ionics Journal Issue: 1 Vol. 345; ISSN 0167-2738
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

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Related Subjects

25 ENERGY STORAGE
in-situ method
lithium-ion batteries
polymerized ionic liquid
succinonitrile