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Title: Synthesis and Characterization of Anion-Exchange Membranes Using Semicrystalline Triblock Copolymers in Ordered and Disordered States

Journal Article · · Macromolecules

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
DOE Contract Number:
Report Number(s):
Journal Information:
Macromolecules, Vol. 53, Issue 19
Country of Publication:
United States

References (84)

Proton Conductivity:  Materials and Applications journal January 1996
Soft material for soft actuators journal September 2017
Membrane electrolysis—History, current status and perspective journal August 2016
A review of platinum-based catalyst layer degradation in proton exchange membrane fuel cells journal December 2009
Anion exchange membranes: Current status and moving forward
  • Hickner, Michael A.; Herring, Andrew M.; Coughlin, E. Bryan
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 24, p. 1727-1735
journal October 2013
Anion exchange membranes for alkaline fuel cells: A review journal July 2011
Anion Exchange Membranes’ Evolution toward High Hydroxide Ion Conductivity and Alkaline Resiliency journal June 2018
Nickel as a catalyst for the electro-oxidation of methanol in alkaline medium journal August 2004
Anion Exchange Fuel Cell Membranes Prepared from C–H Borylation and Suzuki Coupling Reactions journal March 2014
Developing a polysulfone-based alkaline anion exchange membrane for improved ionic conductivity journal April 2009
Imidazolium-Functionalized Poly(arylene ether sulfone) Anion-Exchange Membranes Densely Grafted with Flexible Side Chains for Fuel Cells journal September 2016
Anion Conductive Block Poly(arylene ether)s: Synthesis, Properties, and Application in Alkaline Fuel Cells journal July 2011
Poly(2,6-dimethyl-1,4-phenylene oxide)- b -poly(vinylbenzyltrimethylammonium) Diblock Copolymers for Highly Conductive Anion Exchange Membranes journal June 2015
Cationic Side-Chain Attachment to Poly(Phenylene Oxide) Backbones for Chemically Stable and Conductive Anion Exchange Membranes journal May 2017
Anion exchange membranes with clusters of alkyl ammonium group for mitigating water swelling but not ionic conductivity journal March 2018
Poly(terphenylene) Anion Exchange Membranes: The Effect of Backbone Structure on Morphology and Membrane Property journal April 2017
High Hydroxide Ion Conductivity with Enhanced Alkaline Stability of Partially Fluorinated and Quaternized Aromatic Copolymers as Anion Exchange Membranes journal May 2017
Synthesis and Characterization of Poly(phenylene)-Based Anion Exchange Membranes for Alkaline Fuel Cells journal November 2009
Alkaline Chemical Stability and Ion Transport in Polymerized Ionic Liquids with Various Backbones and Cations journal April 2016
Synthesis and properties of quaternized polyolefins with bulky poly(4-phenyl-1-butene) moieties as anion exchange membranes journal November 2017
Cross-Linked Poly(vinylbenzyl chloride) Anion Exchange Membranes with Long Flexible Multihead for Fuel Cells journal June 2018
Poly(olefin)-Based Anion Exchange Membranes Prepared Using Ziegler–Natta Polymerization journal May 2019
Anion exchange membranes based on quaternized polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene for direct methanol alkaline fuel cells journal March 2010
Polyethylene-Based Block Copolymers for Anion Exchange Membranes journal September 2015
Polymerized ionic liquid diblock copolymer as an ionomer and anion exchange membrane for alkaline fuel cells journal November 2016
Stable Elastomeric Anion Exchange Membranes Based on Quaternary Ammonium-Tethered Polystyrene-b-poly(ethylene-co-butylene)-b-polystyrene Triblock Copolymers journal September 2015
Ion transport in hydroxide conducting block copolymers journal January 2019
Strategies for Developing New Anion Exchange Membranes and Electrode Ionomers journal January 2017
Review of cell performance in anion exchange membrane fuel cells journal January 2018
Ion Transport by Nanochannels in Ion-Containing Aromatic Copolymers journal February 2014
Transport in Proton Conductors for Fuel-Cell Applications:  Simulations, Elementary Reactions, and Phenomenology journal October 2004
A study of linear versus angled rigid rod polymers for proton conducting membranes using sulfonated polyimides journal May 2006
Effects of block length and solution-casting conditions on the final morphology and properties of disulfonated poly(arylene ether sulfone) multiblock copolymer films for proton exchange membranes journal November 2009
Synthesis and characterization of multiblock partially fluorinated hydrophobic poly(arylene ether sulfone)-hydrophilic disulfonated poly(arylene ether sulfone) copolymers for proton exchange membranes journal February 2013
Controlling Microstructure–Transport Interplay in Highly Phase-Separated Perfluorosulfonated Aromatic Multiblock Ionomers via Molecular Architecture Design journal January 2017
Exploring Different Cationic Alkyl Side Chain Designs for Enhanced Alkaline Stability and Hydroxide Ion Conductivity of Anion-Exchange Membranes journal August 2015
High Performance Anion Exchange Membrane Fuel Cells Enabled by Fluoropoly(olefin) Membranes journal March 2019
Ion Transport in Pendant and Backbone Polymerized Ionic Liquids journal August 2019
Alkaline stability of poly(phenylene)-based anion exchange membranes with various cations
  • Hibbs, Michael R.; Hickner, Michael A.; Coughlin, E. Bryan
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 24, p. 1736-1742
journal August 2012
Water sorption, desorption and transport in Nafion membranes journal September 2007
Operation of Nafion®-based PEM fuel cells with no external humidification: influence of operating conditions and gas diffusion layers journal September 2004
Temperature- and Humidity-Controlled SAXS Analysis of Proton-Conductive Ionomer Membranes for Fuel Cells journal February 2014
Water Uptake Study of Anion Exchange Membranes journal April 2018
Ordered Structure in Blends of Block Copolymers.2.Self-Assembly for Immiscible Lamella-Forming Copolymers journal November 1994
Block Copolymers for Fuel Cells journal January 2011
Correlations between Salt-Induced Crystallization, Morphology, Segmental Dynamics, and Conductivity in Amorphous Block Copolymer Electrolytes journal February 2018
Block Copolymer Thermodynamics: Theory and Experiment journal October 1990
Recent progress in block copolymer crystallization journal December 2018
Order-disorder transition: diblock versus triblock copolymers journal January 1992
Rheology and the Microphase Separation Transition in Styrene-Isoprene Block Copolymers journal October 1994
Equilibrium behavior of symmetric ABA triblock copolymer melts journal October 1999
Transport Properties of Sulfonated Poly(styrene- b -isobutylene- b -styrene) Triblock Copolymers at High Ion-Exchange Capacities journal January 2006
Theory of Microphase Separation in Block Copolymers journal November 1980
Anisotropic Proton Conduction in Aligned Block Copolymer Electrolyte Membranes at Equilibrium with Humid Air journal January 2010
Highly conductive and chemically stable alkaline anion exchange membranes via ROMP of trans -cyclooctene derivatives journal April 2019
Microstructure and Mechanical Properties of Semicrystalline−Rubbery−Semicrystalline Triblock Copolymers journal July 2005
The Effects of Crystallinity on the Mechanical Properties of PEEK Polymer and Graphite Fiber Reinforced PEEK journal November 1987
Non-fluorinated proton-exchange membranes based on melt extruded SEBS/HDPE blends journal December 2008
Novel Design Solving the Conductivity vs Water-Uptake Trade-Off for Polymer Electrolyte Membrane by Bicontinuous Crystalline/Amorphous Morphology of Block Copolymer journal September 2009
Effect of hydration on the mechanical properties and ion conduction in a polyethylene-b-poly(vinylbenzyl trimethylammonium) anion exchange membrane journal January 2016
Stability of the Gyroid Phase in Diblock Copolymers at Strong Segregation journal April 2006
Phase Behavior of Symmetric Sulfonated Block Copolymers journal May 2008
Microphase Separation in Sulfonated Block Copolymers Studied by Monte Carlo Simulations journal November 2009
Fluctuations, Order, and Disorder in Short Diblock Copolymers journal February 2013
Laboratory‐scale setup for anionic polymerization under inert atmosphere journal February 1995
Anionic Polymerization: Principles and Practical Applications reference-book March 1996
Structure of Poly(styrene- b -ethylene- alt -propylene) Diblock Copolymer Micelles in Squalane journal October 2009
Synthesis of Acid-Cleavable Light Isotope-Coded Affinity Tags (ICAT- L ) for Potential Use in Proteomic Expression Profiling Analysis journal January 2006
Ionic Functionalization of Polystyrene- b -poly(ethylene- co -butylene)- b -polystyrene via Friedel-Crafts Bromoalkylation and Its Application for Anion Exchange Membranes journal August 2017
Functionalization of Syndiotactic Polystyrene via Superacid-Catalyzed Friedel–Crafts Alkylation journal March 2018
Synthesis of Aromatic Anion Exchange Membranes by Friedel–Crafts Bromoalkylation and Cross-Linking of Polystyrene Block Copolymers journal February 2019
Fiji: an open-source platform for biological-image analysis journal June 2012
The metathetic degradation of polyisoprene and polybutadiene in block copolymers using Grubbs second generation catalyst journal June 2011
Highly Efficient Acyclic Diene Metathesis Depolymerization Using a Ruthenium Catalyst Containing a N-Heterocyclic Carbene Ligand journal November 2001
The Scherrer equation versus the 'Debye-Scherrer equation' journal August 2011
Atomic form factors, incoherent scattering functions, and photon scattering cross sections journal July 1975
Triblock copolymer ionomer membranes journal March 2004
Nucleation and Anisotropic Growth of Lamellar Microdomains in Block Copolymers journal June 1995
Ordering Dynamics of a Symmetric Polystyrene- block -polyisoprene. 2. Real-Space Analysis on the Formation of Lamellar Microdomain journal June 1998
Transition Behavior of Block Copolymer Thin Films on Preferential Surfaces journal December 2008
Scalable Fabrication of Polymer Membranes with Vertically Aligned 1 nm Pores by Magnetic Field Directed Self-Assembly journal November 2014
Polydispersity-Induced Stabilization of a Disordered Bicontinuous Morphology in ABA Triblock Copolymers journal October 2010
Unexpected Consequences of Block Polydispersity on the Self-Assembly of ABA Triblock Copolymers journal February 2012
Block Copolymer Nanostructures Mapped by Far-Field Optics journal June 2009