Materials Data on ReRu2(NCl)10 by Materials Project
ReCl6(RuN3Cl2)2(N2)2 crystallizes in the monoclinic C2/m space group. The structure is one-dimensional and consists of two hexachlororhenium molecules; four nitrogen molecules; and two RuN3Cl2 ribbons oriented in the (0, 1, 0) direction. In each RuN3Cl2 ribbon, Ru+4.50+ is bonded in a trigonal non-coplanar geometry to three N+0.60- atoms. There is two shorter (1.71 Å) and one longer (1.82 Å) Ru–N bond length. There are two inequivalent N+0.60- sites. In the first N+0.60- site, N+0.60- is bonded in a single-bond geometry to one Ru+4.50+ and one Cl1- atom. The N–Cl bond length is 3.32 Å. In the second N+0.60- site, N+0.60- is bonded in a bent 150 degrees geometry to one Ru+4.50+ and one Cl1- atom. The N–Cl bond length is 1.60 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 1-coordinate geometry to two equivalent N+0.60- and one Cl1- atom. The Cl–Cl bond length is 1.99 Å. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one N+0.60- atom.
- Research Organization:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Contributing Organization:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231
- OSTI ID:
- 1759930
- Report Number(s):
- mp-1191105
- Country of Publication:
- United States
- Language:
- English
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