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Radiation-induced accumulation of carboxylic acids in solution of tributyl phosphate in dodecane

Journal Article · · Radiochemistry
OSTI ID:175710
 [1]
  1. Institute of Physical Chemistry, Moscow (Russian Federation)
A study has been made of the molecular composition and concentrations of carboxylic acids formed upon irradiation of the system 30% TBP in dodecane-3 M HNO{sub 3}. Based on these data, a model solution of carboxylic acids in dodecane has been formulated and compared with the irradiated solution in the interfacial tension on the organic phase-alkaline solution interface. Coefficients of carboxylic acid distribution between TBP in dodecane and aqueous solutions of HNO{sub 3}, NaHCO{sub 3} have been determined.
OSTI ID:
175710
Journal Information:
Radiochemistry, Journal Name: Radiochemistry Journal Issue: 5 Vol. 37; ISSN RDIOEO; ISSN 1066-3622
Country of Publication:
United States
Language:
English

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