An industrial perspective on catalysts for low-temperature CO2 electrolysis

Masel, Richard I.; Liu, Zengcai; Yang, Hongzhou; Kaczur, Jerry J.; Carrillo, Daniel; Ren, Shaoxuan; Salvatore, Danielle; Berlinguette, Curtis P.

doi:10.1038/s41565-020-00823-x

An industrial perspective on catalysts for low-temperature CO₂ electrolysis

Journal Article · Sun Jan 10 23:00:00 EST 2021 · Nature Nanotechnology

DOI:https://doi.org/10.1038/s41565-020-00823-x· OSTI ID:1756565

^[1]; ^[2]; ^[2]; Kaczur, Jerry J. ^[2]; Carrillo, Daniel ^[2]; ^[3]; Salvatore, Danielle ^[3]; ^[3]

Dioxide Materials, Boca Raton, FL (United States); Dioxide Materials, Inc
Dioxide Materials, Boca Raton, FL (United States)
Univ. of British Columbia, Vancouver, BC (Canada)

Electrochemical conversion of CO₂ to useful products at temperatures below 100 °C are nearing the commercial scale. Pilot units for CO₂ conversion to CO are already in testing. Units to convert CO₂ to formic acid are projected to reach pilot scale in the next year. Further, several investigators are starting to observe industrially relevant rates of the electrochemical conversion of CO₂ conversion to ethanol and ethylene with the needed hydrogen coming from water. In each case, Faradaic efficiencies of 80% or more and currents above 200 mA/cm^–2 can be reproducibly achieved. In this study we describe the key advances in nano catalysts that lead to the impressive performance, indicate where additional work is needed and provide benchmarks that others can use to compare their results.

View Accepted Manuscript (DOE)

Research Organization:: Dioxide Materials, Boca Raton, FL (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE), Clean Coal and Carbon Management

Grant/Contract Number:: FE0031706

OSTI ID:: 1756565

Journal Information:: Nature Nanotechnology, Journal Name: Nature Nanotechnology Journal Issue: 2 Vol. 16; ISSN 1748-3387

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Carbon Dioxide and Water Electrolysis Using New Alkaline Stable Anion Membranes Kaczur, Jerry J.; Yang, Hongzhou; Liu, Zengcai Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00263	journal	July 2018
A Review of the Use of Immobilized Ionic Liquids in the Electrochemical Conversion of CO2 Kaczur, Jerry J.; Yang, Hongzhou; Liu, Zengcai C — Journal of Carbon Research, Vol. 6, Issue 2 https://doi.org/10.3390/c6020033	journal	May 2020
Towards Higher Rate Electrochemical CO2 Conversion: From Liquid-Phase to Gas-Phase Systems Song, Jun; Song, Hakhyeon; Kim, Beomil Catalysts, Vol. 9, Issue 3 https://doi.org/10.3390/catal9030224	journal	March 2019
Electrochemical Reduction of CO2 to Formate on Easily Prepared Carbon-Supported Bi Nanoparticles Ávila-Bolívar, Beatriz; García-Cruz, Leticia; Montiel, Vicente Molecules, Vol. 24, Issue 11 https://doi.org/10.3390/molecules24112032	journal	May 2019
Copper–Silver Bimetallic Nanowire Arrays for Electrochemical Reduction of Carbon Dioxide Wang, Yuanxing; Niu, Cailing; Zhu, Yachuan Nanomaterials, Vol. 9, Issue 2 https://doi.org/10.3390/nano9020173	journal	January 2019

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10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Carbon dioxide utilization
carbon capture and storage
carbon dioxide electrolysis
electrocatalysis
electrocatalysts
nanocatalysts
nanoparticles
nanowires
organometallic chemistry

An industrial perspective on catalysts for low-temperature CO2 electrolysis

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An industrial perspective on catalysts for low-temperature CO₂ electrolysis