Tuning the Kinetics of Zinc-Ion Insertion/Extraction in V2O5 by In Situ Polyaniline Intercalation Enables Improved Aqueous Zinc-Ion Storage Performance

Liu, Sucheng; Zhu, He; Zhang, Binghao; Li, Gen; Zhu, Hekang; Ren, Yang; Geng, Hongbo; Yang, Yang; Liu, Qi; Li, Cheng Chao

doi:10.1002/adma.202001113

Title: Tuning the Kinetics of Zinc-Ion Insertion/Extraction in V₂O₅ by In Situ Polyaniline Intercalation Enables Improved Aqueous Zinc-Ion Storage Performance

Journal Article · Wed May 20 00:00:00 EDT 2020 · Advanced Materials

DOI:https://doi.org/10.1002/adma.202001113· OSTI ID:1756167

Liu, Sucheng ^[1]; Zhu, He ^[2]; Zhang, Binghao ^[2]; Li, Gen ^[2]; Zhu, Hekang ^[2]; Ren, Yang ^[3]; Geng, Hongbo ^[1]; Yang, Yang ^[1]; Liu, Qi ^[2];

^[1]

Guangdong Univ. of Technology, Guangzhou (China)
City Univ. of Hong Kong (China)
Argonne National Lab. (ANL), Argonne, IL (United States)

Abstract Rechargeable zinc‐ion batteries (ZIBs) are emerging as a promising alternative for Li‐ion batteries. However, the developed cathodes suffer from sluggish Zn ²⁺ diffusion kinetics, leading to poor rate capability and inadequate cycle life. Herein, an in situ polyaniline (PANI) intercalation strategy is developed to facilitate the Zn ²⁺ (de)intercalation kinetics in V ₂ O ₅ . In this way, a remarkably enlarged interlayer distance (13.90 Å) can be constructed alternatively between the VO layers, offering expediting channels for facile Zn ²⁺ diffusion. Importantly, the electrostatic interactions between the Zn ²⁺ and the host O ²⁻ , which is another key factor in hindering the Zn ²⁺ diffusion kinetics, can be effectively blocked by the unique π‐conjugated structure of PANI. As a result, the PANI‐intercalated V ₂ O ₅ exhibits a stable and highly reversible electrochemical reaction during repetitive Zn ²⁺ insertion and extraction, as demonstrated by in situ synchrotron X‐ray diffraction and Raman studies. Further first‐principles calculations clearly reveal a remarkably lowered binding energy between Zn ²⁺ and host O ²⁻ , which explains the favorable kinetics in PANI‐intercalated V ₂ O ₅ . Benefitting from the above, the overall electrochemical performance of PANI‐intercalated V ₂ O ₅ electrode is remarkable improved, exhibiting excellent high rate capability of 197.1 mAh g ⁻¹ at current density of 20 A g ⁻¹ with capacity retention of 97.6% over 2000 cycles.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1756167

Alternate ID(s):: OSTI ID: 1630212

Journal Information:: Advanced Materials, Vol. 32, Issue 26; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 312 works

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Title: Tuning the Kinetics of Zinc-Ion Insertion/Extraction in V₂O₅ by In Situ Polyaniline Intercalation Enables Improved Aqueous Zinc-Ion Storage Performance