Effect of Al substitution on the magnetocaloric properties of Ni-Co-Mn-Sn multifunctional alloys

Huang, L.; Cong, D. Y.; Ren, Y.; Wei, K. X.; Wang, Y. D.

doi:10.1016/j.intermet.2020.106706

Title: Effect of Al substitution on the magnetocaloric properties of Ni-Co-Mn-Sn multifunctional alloys

Journal Article · Tue Jan 21 00:00:00 EST 2020 · Intermetallics

DOI:https://doi.org/10.1016/j.intermet.2020.106706· OSTI ID:1756084

Huang, L. ^[1]; Cong, D. Y. ^[2]; Ren, Y. ^[3]; Wei, K. X. ^[1]; Wang, Y. D. ^[2]

Hunan Inst. of Engineering, Xiangtan (China)
Univ. of Science and Technology, Beijing (China)
Argonne National Lab. (ANL), Argonne, IL (United States)

Ni-Mn-based metamagnetic shape memory alloys have been extensively studied due to their multifunctional properties including magnetocaloric effect (MCE), magnetoresistance effect, and magnetic-field-induced strain. However, the large intrinsic thermal hysteresis of these alloys sets a limit on further development for practical applications. Here, with a few atomic percent Al substitution, we greatly reduced the thermal hysteresis and transformation temperature interval while maintaining the large magnetization difference (ΔM) between austenite and martensite. The simultaneous achievement of a large ΔM and low thermal hysteresis leads to a remarkable enhancement in MCE upon Al substitution, and a maximum magnetic entropy change of 31.6 J/kg K is achieved under a field of 5 T in Ni₃₉Co₁₁Mn₄₀Sn₈Al₂. Furthermore, our in situ high-energy X-ray diffraction experiments show that the Ni₃₉Co₁₁Mn₄₀Sn₈Al₂ has good geometric compatibility between austenite and martensite, which accounts for the reduced thermal hysteresis in this alloy. This study is instructive for the development of high-performance magnetocaloric materials in the metamagnetic shape memory alloys.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); Provincial Natural Science Foundation of Hunan; Hunan Province Education Department; State Key Laboratory for Advanced Metals and Materials

Grant/Contract Number:: AC02-06CH11357; 51701070; 51527801; 2019JJ50101; 17A046; 2016-T01

OSTI ID:: 1756084

Alternate ID(s):: OSTI ID: 1778537

Journal Information:: Intermetallics, Vol. 119; ISSN 0966-9795

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (44)

Magnetic-field-induced shape recovery by reverse phase transformation Kainuma, R.; Imano, Y.; Ito, W. Nature, Vol. 439, Issue 7079 https://doi.org/10.1038/nature04493	journal	February 2006
Magnetic Field-Induced Phase Transformation in NiMnCoIn Magnetic Shape-Memory Alloys-A New Actuation Mechanism with Large Work Output Karaca, Haluk E.; Karaman, Ibrahim; Basaran, Burak Advanced Functional Materials, Vol. 19, Issue 7 https://doi.org/10.1002/adfm.200801322	journal	April 2009
Enhanced cyclability of elastocaloric effect in boron-microalloyed Ni-Mn-In magnetic shape memory alloys Yang, Z.; Cong, D. Y.; Sun, X. M. Acta Materialia, Vol. 127 https://doi.org/10.1016/j.actamat.2017.01.025	journal	April 2017
Elastocaloric effect in Ni 50 Fe 19 Ga 27 Co 4 single crystals Xiao, Fei; Jin, Mingjiang; Liu, Jian Acta Materialia, Vol. 96 https://doi.org/10.1016/j.actamat.2015.05.054	journal	September 2015
Large magnetoresistance in Ni50Mn34In16 alloy Sharma, V. K.; Chattopadhyay, M. K.; Shaeb, K. H. B. Applied Physics Letters, Vol. 89, Issue 22 https://doi.org/10.1063/1.2399365	journal	November 2006
Observation of large magnetoresistance of magnetic Heusler alloy Ni50Mn36Sn14 in high magnetic fields Koyama, Keiichi; Okada, Hironari; Watanabe, Kazuo Applied Physics Letters, Vol. 89, Issue 18 https://doi.org/10.1063/1.2374868	journal	October 2006
Large magnetocaloric effect at low magnetic field in Ni _50−x Co _x Mn ₃₅ In ₁₅ ribbons Guan, W.; Liu, Q. R.; Gao, B. Journal of Applied Physics, Vol. 109, Issue 7 https://doi.org/10.1063/1.3540649	journal	April 2011
Inverse magnetocaloric effect in ferromagnetic Ni–Mn–Sn alloys Krenke, Thorsten; Duman, Eyüp; Acet, Mehmet Nature Materials, Vol. 4, Issue 6 https://doi.org/10.1038/nmat1395	journal	May 2005
Giant magnetic refrigeration capacity near room temperature in Ni ₄₀ Co ₁₀ Mn ₄₀ Sn ₁₀ multifunctional alloy Huang, L.; Cong, D. Y.; Suo, H. L. Applied Physics Letters, Vol. 104, Issue 13 https://doi.org/10.1063/1.4870771	journal	March 2014
Caloric materials near ferroic phase transitions Moya, X.; Kar-Narayan, S.; Mathur, N. D. Nature Materials, Vol. 13, Issue 5 https://doi.org/10.1038/nmat3951	journal	April 2014
Large magnetic‐field‐induced strains in Ni ₂ MnGa single crystals Ullakko, K.; Huang, J. K.; Kantner, C. Applied Physics Letters, Vol. 69, Issue 13 https://doi.org/10.1063/1.117637	journal	September 1996
Giant magnetic-field-induced strain in NiMnGa seven-layered martensitic phase Sozinov, A.; Likhachev, A. A.; Lanska, N. Applied Physics Letters, Vol. 80, Issue 10 https://doi.org/10.1063/1.1458075	journal	March 2002
Giant magnetic-field-induced strains in polycrystalline Ni–Mn–Ga foams Chmielus, M.; Zhang, X. X.; Witherspoon, C. Nature Materials, Vol. 8, Issue 11 https://doi.org/10.1038/nmat2527	journal	September 2009
Large Exchange Bias after Zero-Field Cooling from an Unmagnetized State Wang, B. M.; Liu, Y.; Ren, P. Physical Review Letters, Vol. 106, Issue 7 https://doi.org/10.1103/PhysRevLett.106.077203	journal	February 2011
Magnetic and martensitic transformations of NiMnX(X=In,Sn,Sb) ferromagnetic shape memory alloys Sutou, Y.; Imano, Y.; Koeda, N. Applied Physics Letters, Vol. 85, Issue 19 https://doi.org/10.1063/1.1808879	journal	January 2004
Direct measure of giant magnetocaloric entropy contributions in Ni–Mn–In Chen, Jing-Han; Bruno, Nickolaus M.; Karaman, Ibrahim Acta Materialia, Vol. 105 https://doi.org/10.1016/j.actamat.2015.11.053	journal	February 2016
Direct measurement of large reversible magnetic-field-induced strain in Ni–Co–Mn–In metamagnetic shape memory alloys Monroe, J. A.; Karaman, I.; Basaran, B. Acta Materialia, Vol. 60, Issue 20 https://doi.org/10.1016/j.actamat.2012.07.040	journal	December 2012
Magnetic superelasticity and inverse magnetocaloric effect in Ni-Mn-In Krenke, Thorsten; Duman, Eyüp; Acet, Mehmet Physical Review B, Vol. 75, Issue 10 https://doi.org/10.1103/PhysRevB.75.104414	journal	March 2007
Materials Challenges for High Performance Magnetocaloric Refrigeration Devices Smith, Anders; Bahl, Christian R. H.; Bjørk, Rasmus Advanced Energy Materials, Vol. 2, Issue 11 https://doi.org/10.1002/aenm.201200167	journal	September 2012
The effect of Co substitution on the magnetic properties of the Heusler alloy Ni50Mn33Sn17 Umetsu, R. Y.; Sheikh, A.; Ito, W. Applied Physics Letters, Vol. 98, Issue 4 https://doi.org/10.1063/1.3548558	journal	January 2011
Magnetic properties and structural transformations in Ni–Co–Mn–Sn multifunctional alloys Cong, D. Y.; Roth, S.; Schultz, L. Acta Materialia, Vol. 60, Issue 13-14 https://doi.org/10.1016/j.actamat.2012.06.034	journal	August 2012
Optimizing Magnetocaloric Properties of Heusler-Type Magnetic Shape Memory Alloys by Tuning Magnetostructural Transformation Parameters Huang, Lian; Qu, Yuhai; Cong, Daoyong Shape Memory and Superelasticity, Vol. 3, Issue 3 https://doi.org/10.1007/s40830-017-0116-1	journal	August 2017
Phase transition and magnetocaloric properties of Mn ₅₀ Ni _{42− x} Co _x Sn ₈ (0 ≤ x ≤ 10) melt-spun ribbons Li, Zongbin; Jiang, Yiwen; Li, Zhenzhuang IUCrJ, Vol. 5, Issue 1 https://doi.org/10.1107/S2052252517016220	journal	January 2018
Large magnetic entropy change with small thermal hysteresis near room temperature in metamagnetic alloys Ni51Mn49−xInx Hu, F. X.; Wang, J.; Shen, J. Journal of Applied Physics, Vol. 105, Issue 7 https://doi.org/10.1063/1.3073951	journal	April 2009
Reduction of hysteresis losses in the magnetic refrigerant Gd5Ge2Si2 by the addition of iron Provenzano, Virgil; Shapiro, Alexander J.; Shull, Robert D. Nature, Vol. 429, Issue 6994 https://doi.org/10.1038/nature02657	journal	June 2004
Taming the First-Order Transition in Giant Magnetocaloric Materials Guillou, François; Porcari, Giacomo; Yibole, Hargen Advanced Materials, Vol. 26, Issue 17 https://doi.org/10.1002/adma.201304788	journal	February 2014
Effect of Al doping on the martensitic transition and magnetic entropy change in Ni–Mn–Sn alloys Wang, R. L.; Yan, J. B.; Xu, L. S. Solid State Communications, Vol. 151, Issue 17 https://doi.org/10.1016/j.ssc.2011.04.005	journal	September 2011
Giant low-field magnetocaloric effect in Si alloyed Ni-Co-Mn-In alloys Li, Zongbin; Dong, Shuya; Li, Zhenzhuang Scripta Materialia, Vol. 159 https://doi.org/10.1016/j.scriptamat.2018.09.029	journal	January 2019
Magnetic properties of ${Ni}_{50} {Mn}_{34.8} {In}_{15.2}$ probed by Mössbauer spectroscopy Khovaylo, V. V.; Kanomata, T.; Tanaka, T. Physical Review B, Vol. 80, Issue 14 https://doi.org/10.1103/PhysRevB.80.144409	journal	October 2009
Magnetic correlations in martensitic Ni-Mn-based Heusler shape-memory alloys: Neutron polarization analysis Aksoy, S.; Acet, M.; Deen, P. P. Physical Review B, Vol. 79, Issue 21 https://doi.org/10.1103/PhysRevB.79.212401	journal	June 2009
Superparamagnetic and superspin glass behaviors in the martensitic state of Ni43.5Co6.5Mn39Sn11 magnetic shape memory alloy Cong, D. Y.; Roth, S.; Liu, J. Applied Physics Letters, Vol. 96, Issue 11 https://doi.org/10.1063/1.3367721	journal	March 2010
Entropy change linked to the martensitic transformation in metamagnetic shape memory alloys Recarte, V.; Pérez-Landazábal, J. I.; Sánchez-Alarcos, V. Acta Materialia, Vol. 60, Issue 6-7 https://doi.org/10.1016/j.actamat.2012.02.022	journal	April 2012
Influence of Fe doping and magnetic field on martensitic transition in Ni–Mn–Sn melt-spun ribbons Aguilar-Ortiz, C. O.; Soto-Parra, D.; Álvarez-Alonso, P. Acta Materialia, Vol. 107 https://doi.org/10.1016/j.actamat.2016.01.041	journal	April 2016
Combinatorial search of thermoelastic shape-memory alloys with extremely small hysteresis width Cui, Jun; Chu, Yong S.; Famodu, Olugbenga O. Nature Materials, Vol. 5, Issue 4 https://doi.org/10.1038/nmat1593	journal	March 2006
Enhanced reversibility and unusual microstructure of a phase-transforming material Song, Yintao; Chen, Xian; Dabade, Vivekanand Nature, Vol. 502, Issue 7469 https://doi.org/10.1038/nature12532	journal	October 2013
Giant reversible magnetocaloric effect in MnNiGe-based materials: Minimizing thermal hysteresis via crystallographic compatibility modulation Liu, Jun; Gong, Yuanyuan; You, Yurong Acta Materialia, Vol. 174 https://doi.org/10.1016/j.actamat.2019.05.066	journal	August 2019
Energy barriers and hysteresis in martensitic phase transformations Zhang, Zhiyong; James, Richard D.; Müller, Stefan Acta Materialia, Vol. 57, Issue 15, p. 4332-4352 https://doi.org/10.1016/j.actamat.2009.05.034	journal	September 2009
Ultralow-fatigue shape memory alloy films Chluba, C.; Ge, W.; Lima de Miranda, R. Science, Vol. 348, Issue 6238 https://doi.org/10.1126/science.1261164	journal	May 2015
Hysteresis and unusual magnetic properties in the singular Heusler alloy Ni45Co5Mn40Sn10 Srivastava, Vijay; Chen, Xian; James, Richard D. Applied Physics Letters, Vol. 97, Issue 1 https://doi.org/10.1063/1.3456562	journal	July 2010
Giant caloric effect of low-hysteresis metamagnetic shape memory alloys with exceptional cyclic functionality Zhao, Dewei; Liu, Jian; Chen, Xian Acta Materialia, Vol. 133 https://doi.org/10.1016/j.actamat.2017.05.020	journal	July 2017
Giant magnetocaloric effect driven by structural transitions Liu, Jian; Gottschall, Tino; Skokov, Konstantin P. Nature Materials, Vol. 11, Issue 7 https://doi.org/10.1038/nmat3334	journal	May 2012
Low-field-actuated giant magnetocaloric effect and excellent mechanical properties in a NiMn-based multiferroic alloy Cong, D. Y.; Huang, L.; Hardy, V. Acta Materialia, Vol. 146 https://doi.org/10.1016/j.actamat.2017.12.047	journal	March 2018
Hysteresis of the martensitic phase transition in magnetocaloric-effect Ni-Mn-Sn alloys Shamberger, P. J.; Ohuchi, F. S. Physical Review B, Vol. 79, Issue 14 https://doi.org/10.1103/PhysRevB.79.144407	journal	April 2009
Transformation intervals and elastic strain energies of B2-B19′ martensitic transformation of NiTi Meng, Qinglin; Yang, Hong; Liu, Yinong Intermetallics, Vol. 18, Issue 12 https://doi.org/10.1016/j.intermet.2010.08.038	journal	December 2010

Similar Records

Low-field-actuated giant magnetocaloric effect and excellent mechanical properties in a NiMn-based multiferroic alloy

Journal Article · Tue Jan 09 00:00:00 EST 2018 · Acta Materialia · OSTI ID:1756084

Cong, D. Y.; Huang, L.; Hardy, V.; +7 more

Manipulation of magnetostructural transition and realization of prominent multifunctional magnetoresponsive properties in NiCoMnIn alloys

Journal Article · Mon Mar 11 00:00:00 EDT 2019 · Physical Review Materials · OSTI ID:1756084

Sun, X. M.; Cong, D. Y.; Li, Z.; +10 more

Effect of niobium addition on the martensitic transformation and magnetocaloric effect in low hysteresis NiCoMnSn magnetic shape memory alloys

Journal Article · Mon Dec 08 00:00:00 EST 2014 · Applied Physics Letters · OSTI ID:1756084

Emre, Baris; Bruno, Nickolaus M.; Yuce Emre, Suheyla; +1 more

Related Subjects

36 MATERIALS SCIENCE
field-induced strains
shape-memory alloys

Title: Effect of Al substitution on the magnetocaloric properties of Ni-Co-Mn-Sn multifunctional alloys

Citation Formats

References (44)

Similar Records

Related Subjects