Mechanical and Dielectric Properties of Aligned Electrospun Fibers

Isaac, Blesson; Taylor, Robert M.; Reifsnider, Kenneth

doi:10.3390/fib9010004

Title: Mechanical and Dielectric Properties of Aligned Electrospun Fibers

Journal Article · Wed Jan 06 00:00:00 EST 2021 · Fibers

DOI:https://doi.org/10.3390/fib9010004· OSTI ID:1756036

^[1];

^[2]; Reifsnider, Kenneth ^[2]

Idaho National Lab. (INL), Idaho Falls, ID (United States)
Univ. of Texas, Arlington, TX (United States)

This review paper examines the current state-of-the-art in fabrication of aligned fibers via electrospinning techniques and the effects of these techniques on the mechanical and dielectric properties of electrospun fibers. Molecular orientation, system configuration to align fibers, and post-drawing treatment, like hot/cold drawing process, contribute to better specific strength and specific stiffness properties of nanofibers. The authors suggest that these improved, aligned nanofibers, when applied in composites, have better mechanical and dielectric properties for many structural and multifunctional applications, including advanced aerospace applications and energy storage devices. For these applications, most fiber alignment electrospinning research has focused on either mechanical property improvement or dielectric property improvement alone, but not both simultaneously. Relative to many other nanofiber formation techniques, the electrospinning technique exhibits superior nanofiber formation when considering cost and manufacturing complexity for many situations. Even though the dielectric property of pure nanofiber mat may not be of general interest, the analysis of the combined effect of mechanical and dielectric properties is relevant to the present analysis of improved and aligned nanofibers. A plethora of nanofibers, in particular, polyacrylonitrile (PAN) electrospun nanofibers, are discussed for their mechanical and dielectric properties. In addition, other types of electrospun nanofibers are explored for their mechanical and dielectric properties. An exploratory study by the author demonstrates the relationship between mechanical and dielectric properties for specimens obtained from a rotating mandrel horizontal setup.

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Research Organization:: Idaho National Lab. (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: AC07-05ID14517

OSTI ID:: 1756036

Report Number(s):: INL/JOU-20-58290-Rev000

Journal Information:: Fibers, Vol. 9, Issue 1; ISSN 2079-6439

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

References (162)

Cellulose Nanofiber Orientation in Nanopaper and Nanocomposites by Cold Drawing Sehaqui, Houssine; Ezekiel Mushi, Ngesa; Morimune, Seira ACS Applied Materials & Interfaces, Vol. 4, Issue 2 https://doi.org/10.1021/am2016766	journal	February 2012
Deformation of isolated single-wall carbon nanotubes in electrospun polymer nanofibres Kannan, Prabhakaran; Eichhorn, Stephen J.; Young, Robert J. Nanotechnology, Vol. 18, Issue 23 https://doi.org/10.1088/0957-4484/18/23/235707	journal	May 2007
Stem cell differentiation to epidermal lineages on electrospun nanofibrous substrates for skin tissue engineering Jin, Guorui; Prabhakaran, Molamma P.; Ramakrishna, Seeram Acta Biomaterialia, Vol. 7, Issue 8 https://doi.org/10.1016/j.actbio.2011.04.017	journal	August 2011
Emulsion electrospinning: Fundamentals, food applications and prospects Zhang, Cen; Feng, Fengqin; Zhang, Hui Trends in Food Science & Technology, Vol. 80 https://doi.org/10.1016/j.tifs.2018.08.005	journal	October 2018
Next-Generation Fibrous Media for Water Treatment Kaur, Satinderpal; Gopal, Renuga; Ng, Wun Jern MRS Bulletin, Vol. 33, Issue 1 https://doi.org/10.1557/mrs2008.10	journal	January 2008
The effect of processing on the structure and properties of carbon fibers Edie, D. D. Carbon, Vol. 36, Issue 4 https://doi.org/10.1016/S0008-6223(97)00185-1	journal	January 1998
Highly Aligned Poly(vinylidene fluoride-co-hexafluoro propylene) Nanofibers via Electrospinning Technique Han, Tae-Hwan; Nirmala, R.; Kim, Tae Woo Journal of Nanoscience and Nanotechnology, Vol. 16, Issue 1 https://doi.org/10.1166/jnn.2016.10692	journal	January 2016
Electrospun TiO ₂ –Graphene Composite Nanofibers as a Highly Durable Insertion Anode for Lithium Ion Batteries Zhang, Xiang; Suresh Kumar, Palaniswamy; Aravindan, Vanchiappan The Journal of Physical Chemistry C, Vol. 116, Issue 28 https://doi.org/10.1021/jp302574g	journal	July 2012
Fabrication of Aligned Poly(L-lactide) Fibers by Electrospinning and Drawing Afifi, Amalina M.; Nakajima, Hajime; Yamane, Hideki Macromolecular Materials and Engineering, Vol. 294, Issue 10 https://doi.org/10.1002/mame.200900101	journal	October 2009
Electrospinning: A fascinating fiber fabrication technique Bhardwaj, Nandana; Kundu, Subhas C. Biotechnology Advances, Vol. 28, Issue 3 https://doi.org/10.1016/j.biotechadv.2010.01.004	journal	May 2010
Recent Developments in Electrospinning of Nanofiber Yarns Shuakat, Muhammad Nadeem; Lin, Tong Journal of Nanoscience and Nanotechnology, Vol. 14, Issue 2 https://doi.org/10.1166/jnn.2014.9197	journal	February 2014
Electrospinning materials for energy-related applications and devices Dong, Zexuan; Kennedy, Scott J.; Wu, Yiquan Journal of Power Sources, Vol. 196, Issue 11 https://doi.org/10.1016/j.jpowsour.2011.01.090	journal	June 2011
Electrodynamic control of the nanofiber alignment during electrospinning Grasl, Christian; Arras, Matthias M. L.; Stoiber, Martin Applied Physics Letters, Vol. 102, Issue 5 https://doi.org/10.1063/1.4790632	journal	February 2013
Tensile test of a single nanofiber using an atomic force microscope tip Tan, E. P. S.; Goh, C. N.; Sow, C. H. Applied Physics Letters, Vol. 86, Issue 7 https://doi.org/10.1063/1.1862337	journal	January 2005
Fabrication of styrene–acrylonitrile random copolymer nanofiber membranes from N,N -dimethyl formamide by electrospinning Senthil, T.; Anandhan, S. Journal of Elastomers & Plastics, Vol. 47, Issue 4 https://doi.org/10.1177/0095244313514987	journal	December 2013
Simplified modeling of the electrospinning process from the stable jet region to the unstable region for predicting the final nanofiber diameter Ismail, Nagham; Maksoud, Fouad Junior; Ghaddar, Nesreen Journal of Applied Polymer Science, Vol. 133, Issue 43 https://doi.org/10.1002/app.44112	journal	July 2016
Production of Uniaxially Aligned Nanofibers Using a Modified Electrospinning Method: Rotating Jet Dabirian, Farzad; Sarkeshik, Sarahsadat; Kianiha, Aboutaleb Current Nanoscience, Vol. 5, Issue 3 https://doi.org/10.2174/157341309788921417	journal	August 2009
PGS:Gelatin nanofibrous scaffolds with tunable mechanical and structural properties for engineering cardiac tissues Kharaziha, Mahshid; Nikkhah, Mehdi; Shin, Su-Ryon Biomaterials, Vol. 34, Issue 27 https://doi.org/10.1016/j.biomaterials.2013.04.045	journal	September 2013
Review for application of electrospinning and electrospun nanofibers technology in textile industry Mirjalili, Mohammad; Zohoori, Salar Journal of Nanostructure in Chemistry, Vol. 6, Issue 3 https://doi.org/10.1007/s40097-016-0189-y	journal	March 2016
Solubility parameter-based analysis of polyacrylonitrile solutions in N,N-dimethyl formamide and dimethyl sulfoxide Eom, Youngho; Kim, Byoung Chul Polymer, Vol. 55, Issue 10 https://doi.org/10.1016/j.polymer.2014.03.047	journal	May 2014
A review on nanomaterials for environmental remediation Khin, Mya Mya; Nair, A. Sreekumaran; Babu, V. Jagadeesh Energy & Environmental Science, Vol. 5, Issue 8 https://doi.org/10.1039/c2ee21818f	journal	January 2012
The formation of highly ordered graphitic interphase around embedded CNTs controls the mechanics of ultra-strong carbonized nanofibers Cai, Jizhe; Naraghi, Mohammad Acta Materialia, Vol. 162 https://doi.org/10.1016/j.actamat.2018.09.047	journal	January 2019
Nanofibrous biologic laminates replicate the form and function of the annulus fibrosus Nerurkar, Nandan L.; Baker, Brendon M.; Sen, Sounok Nature Materials, Vol. 8, Issue 12 https://doi.org/10.1038/nmat2558	journal	October 2009
Fabrication of Aligned PAN Nanofiber by Electrospinning with Parallel Electrode Liu, Hong Ying; Xu, Lan; Tang, Xiao Peng Advanced Materials Research, Vol. 905 https://doi.org/10.4028/www.scientific.net/AMR.905.19	journal	April 2014
High Strength and High Modulus Electrospun Nanofibers Yao, Jian; Bastiaansen, Cees; Peijs, Ton Fibers, Vol. 2, Issue 2 https://doi.org/10.3390/fib2020158	journal	April 2014
Efficacy of a poly glycolic acid (PGA)/collagen composite nanofibre scaffold on cell migration and neovascularisation in vivo skin defect model Sekiya, Naomi; Ichioka, Shigeru; Terada, Dohiko Journal of Plastic Surgery and Hand Surgery https://doi.org/10.3109/2000656X.2013.788507	journal	April 2013
Fundamental parameters affecting electrospinning of PAN nanofibers as uniaxially aligned fibers Jalili, Rouhollah; Morshed, Mohammad; Ravandi, Seyed Abdolkarim Hosseini Journal of Applied Polymer Science, Vol. 101, Issue 6 https://doi.org/10.1002/app.24290	journal	January 2006
Fabrication of oriented polymeric nanofibers on planar surfaces by electrospinning Kameoka, Jun; Craighead, H. G. Applied Physics Letters, Vol. 83, Issue 2 https://doi.org/10.1063/1.1592638	journal	July 2003
Excellent mechanical properties of carbon fiber semi-aligned electrospun carbon nanofiber hybrid polymer composites Dhakate, S. R.; Chaudhary, A.; Gupta, A. RSC Advances, Vol. 6, Issue 43 https://doi.org/10.1039/C6RA02672A	journal	January 2016
Structure of PAN fibres and its relationship to resulting carbon fibre properties Bahl, O. P.; Mathur, R. B.; Kundra, K. D. Fibre Science and Technology, Vol. 15, Issue 2 https://doi.org/10.1016/0015-0568(81)90067-1	journal	September 1981
Functional 3-D cardiac co-culture model using bioactive chitosan nanofiber scaffolds Hussain, Ali; Collins, George; Yip, Derek Biotechnology and Bioengineering, Vol. 110, Issue 2 https://doi.org/10.1002/bit.24727	journal	October 2012
3D-Printing of Lightweight Cellular Composites Compton, Brett G.; Lewis, Jennifer A. Advanced Materials, Vol. 26, Issue 34, p. 5930-5935 https://doi.org/10.1002/adma.201401804	journal	June 2014
Ultrafine Electrospun Polyamide-6 Fibers: Effect of Solution Conditions on Morphology and Average Fiber Diameter Mit-uppatham, Chidchanok; Nithitanakul, Manit; Supaphol, Pitt Macromolecular Chemistry and Physics, Vol. 205, Issue 17 https://doi.org/10.1002/macp.200400225	journal	November 2004
Continuous Electrospinning of Aligned Polymer Nanofibers onto a Wire Drum Collector Katta, P.; Alessandro, M.; Ramsier, R. D. Nano Letters, Vol. 4, Issue 11 https://doi.org/10.1021/nl0486158	journal	November 2004
Pd _x Co _y Nanoparticle/Carbon Nanofiber Composites with Enhanced Electrocatalytic Properties Liu, Dong; Guo, Qiaohui; Hou, Haoqing ACS Catalysis, Vol. 4, Issue 6 https://doi.org/10.1021/cs5000153	journal	April 2014
Feasibility study of adhesive bonding reinforcement by electrospun nanofibers Musiari, F.; Pirondi, A.; Moroni, F. Procedia Structural Integrity, Vol. 2 https://doi.org/10.1016/j.prostr.2016.06.015	journal	January 2016
Electrospun poly(lactic acid-co-glycolic acid) scaffolds for skin tissue engineering Kumbar, Sangamesh G.; Nukavarapu, Syam P.; James, Roshan Biomaterials, Vol. 29, Issue 30 https://doi.org/10.1016/j.biomaterials.2008.06.028	journal	October 2008
Effect of heat treatment on ZrO2-embedded electrospun carbon fibers used for efficient electromagnetic interference shielding Im, Ji Sun; Kim, Jong Gu; Bae, Tae-Sung Journal of Physics and Chemistry of Solids, Vol. 72, Issue 10 https://doi.org/10.1016/j.jpcs.2011.07.012	journal	October 2011
Electrospinning versus fibre production methods: from specifics to technological convergence Luo, C. J.; Stoyanov, Simeon D.; Stride, E. Chemical Society Reviews, Vol. 41, Issue 13 https://doi.org/10.1039/c2cs35083a	journal	January 2012
Fabrication of aligned electrospun nanofibers by inclined gap method Park, Suk Hee; Yang, Dong-Yol Journal of Applied Polymer Science, Vol. 120, Issue 3 https://doi.org/10.1002/app.33395	journal	December 2010
Electrospinning of polyurethane fibers Demir, M. M.; Yilgor, I.; Yilgor, E. Polymer, Vol. 43, Issue 11 https://doi.org/10.1016/S0032-3861(02)00136-2	journal	May 2002
Ultra-low dielectric performance of polymer electrospun nanofiber mats Li, Yongxin; Lu, Xiaofeng; Liu, Xincai Applied Physics A, Vol. 100, Issue 1 https://doi.org/10.1007/s00339-010-5577-4	journal	February 2010
Enhancing thermal and ionic conductivities of electrospun PAN and PMMA nanofibers by graphene nanoflake additions for battery-separator applications: Electrospun battery separator Khan, W. S.; Asmatulu, R.; Rodriguez, V. International Journal of Energy Research, Vol. 38, Issue 15 https://doi.org/10.1002/er.3188	journal	April 2014
Enhanced alignment and mechanical properties through the use of hydroxyethyl cellulose in solvent-free native cellulose spun filaments Hooshmand, Saleh; Aitomäki, Yvonne; Berglund, Linn Composites Science and Technology, Vol. 150 https://doi.org/10.1016/j.compscitech.2017.07.011	journal	September 2017
Microstructural evolution and mechanical investigation of hot stretched graphene oxide reinforced polyacrylonitrile nanofiber yarns Yu, Yuxi; Tan, Zekai; Zhang, Jibin Polymers for Advanced Technologies, Vol. 31, Issue 9 https://doi.org/10.1002/pat.4918	journal	April 2020
A review of the electrical and mechanical properties of carbon nanofiller-reinforced polymer composites Li, Yichao; Huang, Xianrong; Zeng, Lijian Journal of Materials Science, Vol. 54, Issue 2 https://doi.org/10.1007/s10853-018-3006-9	journal	October 2018
An asymmetric electrically conducting self-aligned graphene/polymer composite thin film for efficient electromagnetic interference shielding Kumar, Pradip; Kumar, Asheesh; Cho, Kie Yong AIP Advances, Vol. 7, Issue 1 https://doi.org/10.1063/1.4973535	journal	January 2017
Bioinspired nanofibers support chondrogenesis for articular cartilage repair Coburn, J. M.; Gibson, M.; Monagle, S. Proceedings of the National Academy of Sciences, Vol. 109, Issue 25 https://doi.org/10.1073/pnas.1121605109	journal	June 2012
Continuous Carbon Nanofibers For Nanofiber Composites Dzenis, Yuris; Wen, Yongkui MRS Proceedings, Vol. 702 https://doi.org/10.1557/PROC-702-U5.4.1	journal	January 2001
Dramatically improved dielectric properties of polymer composites by controlling the alignment of carbon nanotubes in matrix Ning, Nanying; Bai, Xue; Yang, Dan RSC Adv., Vol. 4, Issue 9 https://doi.org/10.1039/C3RA45769A	journal	January 2014
Influence of Electrospinning Parameters on Fiber Diameter and Mechanical Properties of Poly(3-Hydroxybutyrate) (PHB) and Polyanilines (PANI) Blends El-hadi, Ahmed; Al-Jabri, Fatma Polymers, Vol. 8, Issue 3 https://doi.org/10.3390/polym8030097	journal	March 2016
Hierarchical electrospun nanofibers for energy harvesting, production and environmental remediation Kumar, Palaniswamy Suresh; Sundaramurthy, Jayaraman; Sundarrajan, Subramanian Energy Environ. Sci., Vol. 7, Issue 10 https://doi.org/10.1039/C4EE00612G	journal	January 2014
The effect of nanofiber-guided cell alignment on the preferential differentiation of neural stem cells Lim, Shawn H.; Liu, Xingyu Y.; Song, Hongjun Biomaterials, Vol. 31, Issue 34 https://doi.org/10.1016/j.biomaterials.2010.08.021	journal	December 2010
Alignment of Boron Nitride Nanotubes in Polymeric Composite Films for Thermal Conductivity Improvement Terao, Takeshi; Zhi, Chunyi; Bando, Yoshio The Journal of Physical Chemistry C, Vol. 114, Issue 10 https://doi.org/10.1021/jp911431f	journal	March 2010
Polymer Nanocomposites—A Comparison between Carbon Nanotubes, Graphene, and Clay as Nanofillers Bhattacharya, Mrinal Materials, Vol. 9, Issue 4 https://doi.org/10.3390/ma9040262	journal	April 2016
A review on electrospinning for membrane fabrication: Challenges and applications Ahmed, Farah Ejaz; Lalia, Boor Singh; Hashaikeh, Raed Desalination, Vol. 356 https://doi.org/10.1016/j.desal.2014.09.033	journal	January 2015
Anisotropic Characterizations of Electrospun PAN Nanofiber Mats Using Design of Experiments Isaac, Blesson; Taylor, Robert M.; Reifsnider, Kenneth Nanomaterials, Vol. 10, Issue 11 https://doi.org/10.3390/nano10112273	journal	November 2020
In situ transmission electron microscope tensile testing reveals structure–property relationships in carbon nanofibers Beese, Allison M.; Papkov, Dimitry; Li, Shuyou Carbon, Vol. 60 https://doi.org/10.1016/j.carbon.2013.04.018	journal	August 2013
A Review of Electrospun Carbon Fibers as Electrode Materials for Energy Storage Mao, Xianwen; Hatton, T.; Rutledge, Gregory Current Organic Chemistry, Vol. 17, Issue 13 https://doi.org/10.2174/1385272811317130006	journal	June 2013
Electrospun fine-textured scaffolds for heart tissue constructs Zong, X.; Bien, H.; Chung, C. Biomaterials, Vol. 26, Issue 26 https://doi.org/10.1016/j.biomaterials.2005.01.052	journal	September 2005
Process optimization and empirical modeling for electrospun polyacrylonitrile (PAN) nanofiber precursor of carbon nanofibers Gu, S. Y.; Ren, J.; Vancso, G. J. European Polymer Journal, Vol. 41, Issue 11 https://doi.org/10.1016/j.eurpolymj.2005.05.008	journal	November 2005
Centrifugal electrospinning of highly aligned polymer nanofibers over a large area Edmondson, Dennis; Cooper, Ashleigh; Jana, Soumen Journal of Materials Chemistry, Vol. 22, Issue 35 https://doi.org/10.1039/c2jm33877g	journal	January 2012
Electrostatic alignment of electrospun PEO fibers by the gap method increases individual fiber modulus in comparison to non-aligned fibers of similar diameter Fryer, Christopher; Scharnagl, Meghan; Helms, Christine AIP Advances, Vol. 8, Issue 6 https://doi.org/10.1063/1.5027812	journal	June 2018
Improved Graphitic Structure of Continuous Carbon Nanofibers via Graphene Oxide Templating Papkov, Dimitry; Goponenko, Alexander; Compton, Owen C. Advanced Functional Materials, Vol. 23, Issue 46 https://doi.org/10.1002/adfm.201300653	journal	June 2013
Effect of collector design on the morphological properties of polycaprolactone electrospun fibers Alfaro De Prá, Manuel A.; Ribeiro-do-Valle, Rosa M.; Maraschin, M. Materials Letters, Vol. 193 https://doi.org/10.1016/j.matlet.2017.01.102	journal	April 2017
Effects of biopolyimide molecular design on their silica hybrids thermo-mechanical, optical and electrical properties Dwivedi, S.; Sakamoto, S.; Kato, S. RSC Advances, Vol. 8, Issue 25 https://doi.org/10.1039/C8RA01965G	journal	January 2018
High Throughput Preparation of Aligned Nanofibers Using an Improved Bubble-Electrospinning Yu, Liang; Shao, Zhongbiao; Xu, Lan Polymers, Vol. 9, Issue 12 https://doi.org/10.3390/polym9120658	journal	November 2017
High performance dye-sensitized solar cells with record open circuit voltage using tin oxide nanoflowers developed by electrospinning Kumar, E. Naveen; Jose, R.; Archana, P. S. Energy Environ. Sci., Vol. 5, Issue 1 https://doi.org/10.1039/C1EE02703D	journal	January 2012
Morphology, polymorphism behavior and molecular orientation of electrospun poly(vinylidene fluoride) fibers Yee, Wu Aik; Kotaki, Masaya; Liu, Ye Polymer, Vol. 48, Issue 2 https://doi.org/10.1016/j.polymer.2006.11.036	journal	January 2007
Li–O₂ and Li–S batteries with high energy storage Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J. Nature Materials, Vol. 11, Issue 1, p. 19-29 https://doi.org/10.1038/nmat3191	journal	January 2012
Evolution of fiber morphology during electrospinning Fang, Jian; Wang, Hongxia; Niu, Haitao Journal of Applied Polymer Science, Vol. 118, Issue 5 https://doi.org/10.1002/app.32569	journal	June 2010
Phenol contaminated water treatment by photocatalytic degradation on electrospun Ag/TiO2 nanofibers: Optimization by the response surface method Norouzi, Mahtab; Fazeli, Ali; Tavakoli, Omid Journal of Water Process Engineering, Vol. 37 https://doi.org/10.1016/j.jwpe.2020.101489	journal	October 2020
Orientational order and mechanical properties of poly(amide-block-aramid) alternating block copolymer films and fibers de Ruijter, Christiaan; Mendes, Eduardo; Boerstoel, Hanneke Polymer, Vol. 47, Issue 26 https://doi.org/10.1016/j.polymer.2006.10.006	journal	December 2006
A first report on the fabrication of vertically aligned anatase TiO2 nanowires by electrospinning: Preferred architecture for nanostructured solar cells Krishnamoorthy, Thirumal; Thavasi, Velmurugan; Subodh G., Mhaisalkar Energy & Environmental Science, Vol. 4, Issue 8 https://doi.org/10.1039/c1ee01315g	journal	January 2011
Preparation of ultra-low dielectric constant silica/polyimide nanofiber membranes by electrospinning Liu, Leipeng; Lv, Fengzhu; Li, Penggang Composites Part A: Applied Science and Manufacturing, Vol. 84 https://doi.org/10.1016/j.compositesa.2016.02.002	journal	May 2016
An Alternative Electrospinning Approach With Varying Electric Field for 2-D-Aligned Nanofibers Karatay, Okan; Dogan, Mustafa; Uyar, Tansel IEEE Transactions on Nanotechnology, Vol. 13, Issue 1 https://doi.org/10.1109/TNANO.2013.2293704	journal	January 2014
Lightweight 3D cellular composites inspired by balsa Malek, Sardar; Raney, Jordan R.; Lewis, Jennifer A. Bioinspiration & Biomimetics, Vol. 12, Issue 2 https://doi.org/10.1088/1748-3190/aa6028	journal	March 2017
Neurite Outgrowth on Electrospun Nanofibers with Uniaxial Alignment: The Effects of Fiber Density, Surface Coating, and Supporting Substrate Xie, Jingwei; Liu, Wenying; MacEwan, Matthew R. ACS Nano, Vol. 8, Issue 2 https://doi.org/10.1021/nn406363j	journal	January 2014
Nanometre diameter fibres of polymer, produced by electrospinning Reneker, Darrell H.; Chun, Iksoo Nanotechnology, Vol. 7, Issue 3 https://doi.org/10.1088/0957-4484/7/3/009	journal	September 1996
Characterization of nano-structured poly(ε-caprolactone) nonwoven mats via electrospinning Lee, K. H.; Kim, H. Y.; Khil, M. S. Polymer, Vol. 44, Issue 4 https://doi.org/10.1016/S0032-3861(02)00820-0	journal	February 2003
The change of bead morphology formed on electrospun polystyrene fibers Lee, K. H.; Kim, H. Y.; Bang, H. J. Polymer, Vol. 44, Issue 14 https://doi.org/10.1016/S0032-3861(03)00345-8	journal	June 2003
Transparent Nanocomposites with Ultrathin, Electrospun Nylon-4,6 Fiber Reinforcement Bergshoef, M. M.; Vancso, G. J. Advanced Materials, Vol. 11, Issue 16 https://doi.org/10.1002/(SICI)1521-4095(199911)11:16<1362::AID-ADMA1362>3.0.CO;2-X	journal	November 1999
Progress in electrospun polymeric nanofibrous membranes for water treatment: Fabrication, modification and applications Liao, Yuan; Loh, Chun-Heng; Tian, Miao Progress in Polymer Science, Vol. 77 https://doi.org/10.1016/j.progpolymsci.2017.10.003	journal	February 2018
Synthesis of Perovskite-Based Porous La _0.75 Sr _0.25 MnO ₃ Nanotubes as a Highly Efficient Electrocatalyst for Rechargeable Lithium-Oxygen Batteries Xu, Ji-Jing; Xu, Dan; Wang, Zhong-Li Angewandte Chemie International Edition, Vol. 52, Issue 14 https://doi.org/10.1002/anie.201210057	journal	February 2013
Synthesis, Morphology Control and Electromagnetic Wave Absorption Properties of Electrospun FeCo Alloy Nanofibers Lee, Young-In; Jang, Dae-Hwan; Choa, Yong-Ho Journal of Nanoscience and Nanotechnology, Vol. 16, Issue 5 https://doi.org/10.1166/jnn.2016.12269	journal	May 2016
Electrostatic field-assisted alignment of electrospun nanofibres Theron, A.; Zussman, E.; Yarin, A. L. Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1088/0957-4484/12/3/329	journal	August 2001
Experimental study on relationship between jet instability and formation of beaded fibers during electrospinning Zuo, Weiwei; Zhu, Meifang; Yang, Wen Polymer Engineering & Science, Vol. 45, Issue 5 https://doi.org/10.1002/pen.20304	journal	January 2005
Electrospinning process parameters optimization for biofunctional curcumin/gelatin nanofibers Kanu, Nand Jee; Gupta, Eva; Vates, Umesh Kumar Materials Research Express, Vol. 7, Issue 3 https://doi.org/10.1088/2053-1591/ab7f60	journal	March 2020
Fabrication and properties of poly(tetrafluoroethylene) nanofibres via sea-island spinning Zhang, Zhifei; Tu, Wei; Peijs, Ton Polymer, Vol. 109 https://doi.org/10.1016/j.polymer.2016.12.060	journal	January 2017
Tracking the origins of size dependency in the mechanical properties of polymeric nanofibers at the atomistic scale Peng, Kaiyuan; Nain, Amrinder; Mirzaeifar, Reza Polymer, Vol. 175 https://doi.org/10.1016/j.polymer.2019.05.014	journal	June 2019
Controlling Surface Morphology of Electrospun Polystyrene Fibers: Effect of Humidity and Molecular Weight in the Electrospinning Process Casper, Cheryl L.; Stephens, Jean S.; Tassi, Nancy G. Macromolecules, Vol. 37, Issue 2 https://doi.org/10.1021/ma0351975	journal	January 2004
Mechanical properties of polymer nanofibers revealed by interaction with streams of air Lin, Yinan; Clark, Daniel M.; Yu, Xiang Polymer, Vol. 53, Issue 3 https://doi.org/10.1016/j.polymer.2011.12.043	journal	February 2012
Characterization of gelatin nanofiber prepared from gelatin–formic acid solution Ki, Chang Seok; Baek, Doo Hyun; Gang, Kyung Don Polymer, Vol. 46, Issue 14 https://doi.org/10.1016/j.polymer.2005.04.040	journal	June 2005
Electrospinning of very long and highly aligned fibers Cai, Xiaomei; Zhu, Ping; Lu, Xizhao Journal of Materials Science, Vol. 52, Issue 24 https://doi.org/10.1007/s10853-017-1529-0	journal	September 2017
Mechanical Properties of Electrospun Silk Fibers Wang, Mao; Jin, Hyoung-Joon; Kaplan, David L. Macromolecules, Vol. 37, Issue 18 https://doi.org/10.1021/ma048988v	journal	September 2004
Electrospun nanofibrous polyurethane membrane as wound dressing Khil, Myung-Seob; Cha, Dong-Il; Kim, Hak-Yong Journal of Biomedical Materials Research, Vol. 67B, Issue 2 https://doi.org/10.1002/jbm.b.10058	journal	October 2003
Electrospinning of Nanofibers and Their Applications for Energy Devices Shi, Xiaomin; Zhou, Weiping; Ma, Delong Journal of Nanomaterials, Vol. 2015 https://doi.org/10.1155/2015/140716	journal	January 2015
Mechanical tests on individual carbon nanofibers reveals the strong effect of graphitic alignment achieved via precursor hot-drawing Chawla, Sneha; Cai, Jizhe; Naraghi, Mohammad Carbon, Vol. 117 https://doi.org/10.1016/j.carbon.2017.02.095	journal	June 2017
Biomimetic poly(lactide) based fibrous scaffolds for ligament tissue engineering Surrao, Denver C.; Waldman, Stephen D.; Amsden, Brian G. Acta Biomaterialia, Vol. 8, Issue 11 https://doi.org/10.1016/j.actbio.2012.07.012	journal	November 2012
Electrochemical energy storage in a sustainable modern society Goodenough, John B. Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE42613K	journal	January 2014
Electrospinning of Polymeric and Ceramic Nanofibers as Uniaxially Aligned Arrays Li, Dan; Wang, Yuliang; Xia, Younan Nano Letters, Vol. 3, Issue 8 https://doi.org/10.1021/nl0344256	journal	August 2003
Electrospinning: Applications in drug delivery and tissue engineering Sill, Travis J.; von Recum, Horst A. Biomaterials, Vol. 29, Issue 13, p. 1989-2006 https://doi.org/10.1016/j.biomaterials.2008.01.011	journal	May 2008
Electrospun Fibrous Nanocomposite Membrane for UV Shielding Applications Anitha, S.; Natarajan, T. S. Journal of Nanoscience and Nanotechnology, Vol. 15, Issue 12 https://doi.org/10.1166/jnn.2015.11641	journal	December 2015
A novel electrospinning target to improve the yield of uniaxially aligned fibers Secasanu, Virgil P.; Giardina, Christopher K.; Wang, Yadong Biotechnology Progress, Vol. 25, Issue 4 https://doi.org/10.1002/btpr.163	journal	July 2009
A review on polymer nanofibers by electrospinning and their applications in nanocomposites Huang, Zheng-Ming; Zhang, Y.-Z.; Kotaki, M. Composites Science and Technology, Vol. 63, Issue 15, p. 2223-2253 https://doi.org/10.1016/S0266-3538(03)00178-7	journal	November 2003
Dielectric and Ferroelectric Properties of BaTiO3 Nanofibers Prepared via Electrospinning Wei, Yan; Song, Yu; Deng, Xuliang Journal of Materials Science & Technology, Vol. 30, Issue 8 https://doi.org/10.1016/j.jmst.2014.03.021	journal	August 2014
Surface modification of polyacrylonitrile nanofibrous membranes with superior antibacterial and easy-cleaning properties through hydrophilic flexible spacers Mei, Yan; Yao, Chen; Fan, Kai Journal of Membrane Science, Vol. 417-418 https://doi.org/10.1016/j.memsci.2012.06.021	journal	November 2012
Physico-Mechanical, Dielectric, and Piezoelectric Properties of PVDF Electrospun Mats Containing Silver Nanoparticles Issa, Ahmed; Al-Maadeed, Mariam; Luyt, Adriaan C, Vol. 3, Issue 4 https://doi.org/10.3390/c3040030	journal	October 2017
Fabrication of Aligned Fibrous Arrays by Magnetic Electrospinning Yang, D.; Lu, B.; Zhao, Y. Advanced Materials, Vol. 19, Issue 21 https://doi.org/10.1002/adma.200700171	journal	November 2007
Controllable fabrication and properties of polypropylene nanofibers Wang, Dong; Sun, Gang; Chiou, Bor-Sen Polymer Engineering & Science, Vol. 47, Issue 11 https://doi.org/10.1002/pen.20896	journal	January 2007
Nano silver-embedded electrospun nanofiber of poly(4-chloro-3-methylphenyl methacrylate): use as water sanitizer Shekh, Mehdihasan I.; Patel, Nirmal N.; Patel, Kaushal P. Environmental Science and Pollution Research, Vol. 24, Issue 6 https://doi.org/10.1007/s11356-016-8254-0	journal	December 2016
An analysis of the tensile properties of nanofiber mats Wan, Lynn Yuqin; Wang, Hongbo; Gao, Weidong Polymer, Vol. 73 https://doi.org/10.1016/j.polymer.2015.07.018	journal	September 2015
Aligned polyvinylpyrrolidone nanofibers with advanced electrospinning for biomedical applications Karayeğen, Gökay; Koçum, İ. Cengiz; Çökeli̇ler Serdaroğlu, Dilek Bio-Medical Materials and Engineering, Vol. 29, Issue 5 https://doi.org/10.3233/BME-181017	journal	October 2018
Electrospun Nb-doped TiO2 nanofiber support for Pt nanoparticles with high electrocatalytic activity and durability Kim, MinJoong; Kwon, ChoRong; Eom, KwangSup Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep44411	journal	March 2017
The effect of embedded carbon nanotubes on the morphological evolution during the carbonization of poly(acrylonitrile) nanofibers Prilutsky, Sabina; Zussman, Eyal; Cohen, Yachin Nanotechnology, Vol. 19, Issue 16 https://doi.org/10.1088/0957-4484/19/16/165603	journal	March 2008
Electrospinning of aligned fibers with adjustable orientation using auxiliary electrodes Arras, Matthias M. L.; Grasl, Christian; Bergmeister, Helga Science and Technology of Advanced Materials, Vol. 13, Issue 3 https://doi.org/10.1088/1468-6996/13/3/035008	journal	June 2012
Recent advances in electrospun carbon nanofibers and their application in electrochemical energy storage Zhang, Biao; Kang, Feiyu; Tarascon, Jean-Marie Progress in Materials Science, Vol. 76 https://doi.org/10.1016/j.pmatsci.2015.08.002	journal	March 2016
A Bamboo-Inspired Nanostructure Design for Flexible, Foldable, and Twistable Energy Storage Devices Sun, Yongming; Sills, Ryan B.; Hu, Xianluo Nano Letters, Vol. 15, Issue 6 https://doi.org/10.1021/acs.nanolett.5b00738	journal	May 2015
Nanofiber Assembly by Rotary Jet-Spinning Badrossamay, Mohammad Reza; McIlwee, Holly Alice; Goss, Josue A. Nano Letters, Vol. 10, Issue 6, p. 2257-2261 https://doi.org/10.1021/nl101355x	journal	June 2010
Preparation and Properties of Electrospun Poly (Vinyl Pyrrolidone)/Cellulose Nanocrystal/Silver Nanoparticle Composite Fibers Huang, Siwei; Zhou, Ling; Li, Mei-Chun Materials, Vol. 9, Issue 7 https://doi.org/10.3390/ma9070523	journal	June 2016
Electrospinning jets and polymer nanofibers Reneker, Darrell H.; Yarin, Alexander L. Polymer, Vol. 49, Issue 10 https://doi.org/10.1016/j.polymer.2008.02.002	journal	May 2008
Electrospun Polyacrylonitrile Nanofibers Containing a High Concentration of Well-Aligned Multiwall Carbon Nanotubes Hou, Haoqing; Ge, Jason J.; Zeng, Jun Chemistry of Materials, Vol. 17, Issue 5 https://doi.org/10.1021/cm0484955	journal	March 2005
A review on electrospinning design and nanofibre assemblies Teo, W. E.; Ramakrishna, S. Nanotechnology, Vol. 17, Issue 14 https://doi.org/10.1088/0957-4484/17/14/R01	journal	June 2006
Simultaneously Strong and Tough Ultrafine Continuous Nanofibers Papkov, Dimitry; Zou, Yan; Andalib, Mohammad Nahid ACS Nano, Vol. 7, Issue 4 https://doi.org/10.1021/nn400028p	journal	March 2013
Electrospun Carbon Nanotube-Reinforced Nanofiber Kim, Sung Min; Kim, Sung Hee; Choi, Myong Soo Journal of Nanoscience and Nanotechnology, Vol. 16, Issue 3 https://doi.org/10.1166/jnn.2016.11088	journal	March 2016
Polyacrylonitrile-based nanofibers—A state-of-the-art review Nataraj, S. K.; Yang, K. S.; Aminabhavi, T. M. Progress in Polymer Science, Vol. 37, Issue 3 https://doi.org/10.1016/j.progpolymsci.2011.07.001	journal	March 2012
Electrospun nanofiber reinforced composites: a review Jiang, Shaohua; Chen, Yiming; Duan, Gaigai Polymer Chemistry, Vol. 9, Issue 20 https://doi.org/10.1039/C8PY00378E	journal	January 2018
Alignment of graphene sheets in wax composites for electromagnetic interference shielding improvement Song, Wei-Li; Cao, Mao-Sheng; Lu, Ming-Ming Nanotechnology, Vol. 24, Issue 11 https://doi.org/10.1088/0957-4484/24/11/115708	journal	March 2013
Self-aligned and bundled electrospun fibers prepared from blends of polystyrene (PS) and poly(methyl methacrylate) (PMMA) with a hairy-rod polyphenylene copolymer Uyar, Tamer; Cianga, Ioan; Cianga, Luminita Materials Letters, Vol. 63, Issue 18-19 https://doi.org/10.1016/j.matlet.2009.04.039	journal	July 2009
Super Proton Conductive High-Purity Nafion Nanofibers Dong, Bin; Gwee, Liang; Salas-de la Cruz, David Nano Letters, Vol. 10, Issue 9 https://doi.org/10.1021/nl102581w	journal	September 2010
A critical review on the electrospun nanofibrous membranes for the adsorption of heavy metals in water treatment Zhu, Fan; Zheng, Yu-Ming; Zhang, Bao-Gang Journal of Hazardous Materials, Vol. 401 https://doi.org/10.1016/j.jhazmat.2020.123608	journal	January 2021
A novel manufacturing method for aligned discontinuous fibre composites (High Performance-Discontinuous Fibre method) Yu, H.; Potter, K. D.; Wisnom, M. R. Composites Part A: Applied Science and Manufacturing, Vol. 65 https://doi.org/10.1016/j.compositesa.2014.06.005	journal	October 2014
Electrospinning of Polymeric Nanofibers for Tissue Engineering Applications: A Review Pham, Quynh P.; Sharma, Upma; Mikos, Antonios G. Tissue Engineering, Vol. 12, Issue 5 https://doi.org/10.1089/ten.2006.12.1197	journal	May 2006
Bioresorbable nanofiber-based systems for wound healing and drug delivery: Optimization of fabrication parameters Katti, Dhirendra S.; Robinson, Kyle W.; Ko, Frank K. Journal of Biomedical Materials Research, Vol. 70B, Issue 2 https://doi.org/10.1002/jbm.b.30041	journal	January 2004
Functional Materials for Rechargeable Batteries Cheng, Fangyi; Liang, Jing; Tao, Zhanliang Advanced Materials, Vol. 23, Issue 15 https://doi.org/10.1002/adma.201003587	journal	March 2011
Carbon nanotube membranes for water purification: A bright future in water desalination Das, Rasel; Ali, Md. Eaqub; Hamid, Sharifah Bee Abd Desalination, Vol. 336 https://doi.org/10.1016/j.desal.2013.12.026	journal	March 2014
The effect of temperature and humidity on electrospinning De Vrieze, S.; Van Camp, T.; Nelvig, A. Journal of Materials Science, Vol. 44, Issue 5 https://doi.org/10.1007/s10853-008-3010-6	journal	March 2009
Electrospinning of polymer nanofibers: Effects on oriented morphology, structures and tensile properties Baji, Avinash; Mai, Yiu-Wing; Wong, Shing-Chung Composites Science and Technology, Vol. 70, Issue 5 https://doi.org/10.1016/j.compscitech.2010.01.010	journal	May 2010
TiO2-Doped Electrospun Nanofibrous Membrane for Photocatalytic Water Treatment Blanco, Miren; Monteserín, Cristina; Angulo, Adrián Polymers, Vol. 11, Issue 5 https://doi.org/10.3390/polym11050747	journal	April 2019
Enhancing the mechanical properties of electrospun polyester mats by heat treatment Kancheva, M.; Toncheva, A.; Manolova, N. Express Polymer Letters, Vol. 9, Issue 1 https://doi.org/10.3144/expresspolymlett.2015.6	journal	January 2015
Electrospinning of linear homopolymers of poly(methyl methacrylate): exploring relationships between fiber formation, viscosity, molecular weight and concentration in a good solvent Gupta, Pankaj; Elkins, Casey; Long, Timothy E. Polymer, Vol. 46, Issue 13 https://doi.org/10.1016/j.polymer.2005.04.021	journal	June 2005
Electrospinning of uniform polystyrene fibers: The effect of solvent conductivity Uyar, Tamer; Besenbacher, Flemming Polymer, Vol. 49, Issue 24 https://doi.org/10.1016/j.polymer.2008.09.025	journal	November 2008
Electrospun Ag-TiO ₂ Nanofibers for Photocatalytic Glucose Conversion to High-Value Chemicals Roongraung, Kamonchanok; Chuangchote, Surawut; Laosiripojana, Navadol ACS Omega, Vol. 5, Issue 11 https://doi.org/10.1021/acsomega.9b04076	journal	March 2020
Strong carbon nanofibers from electrospun polyacrylonitrile Arshad, Salman N.; Naraghi, Mohammad; Chasiotis, Ioannis Carbon, Vol. 49, Issue 5 https://doi.org/10.1016/j.carbon.2010.12.056	journal	April 2011
New Insight into Gap Electrospinning: Toward Meter-long Aligned Nanofibers Lei, Tingping; Xu, Zhenjin; Cai, Xiaomei Langmuir, Vol. 34, Issue 45 https://doi.org/10.1021/acs.langmuir.8b03114	journal	October 2018
Role of fibronectin in topographical guidance of neurite extension on electrospun fibers Mukhatyar, Vivek J.; Salmerón-Sánchez, Manuel; Rudra, Soumon Biomaterials, Vol. 32, Issue 16 https://doi.org/10.1016/j.biomaterials.2011.02.015	journal	June 2011
Fabrication of aligned and molecularly oriented electrospun polyacrylonitrile nanofibers and the mechanical behavior of their twisted yarns Fennessey, Sian F.; Farris, Richard J. Polymer, Vol. 45, Issue 12 https://doi.org/10.1016/j.polymer.2004.04.001	journal	May 2004
Porous Electrospun Fibers Embedding TiO ₂ for Adsorption and Photocatalytic Degradation of Water Pollutants Lee, Chang-Gu; Javed, Hassan; Zhang, Danning Environmental Science & Technology, Vol. 52, Issue 7 https://doi.org/10.1021/acs.est.7b06508	journal	February 2018
Beaded nanofibers formed during electrospinning Fong, H.; Chun, I.; Reneker, D. H. Polymer, Vol. 40, Issue 16 https://doi.org/10.1016/S0032-3861(99)00068-3	journal	July 1999
Stress-induced structural changes in electrospun polyvinylidene difluoride nanofibers collected using a modified rotating disk Yee, Wu Aik; Nguyen, Anh Chien; Lee, Pooi See Polymer, Vol. 49, Issue 19 https://doi.org/10.1016/j.polymer.2008.07.032	journal	September 2008
Transport properties of porous membranes based on electrospun nanofibers Gibson, Phillip; Schreuder-Gibson, Heidi; Rivin, Donald Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 187-188 https://doi.org/10.1016/S0927-7757(01)00616-1	journal	August 2001
Molecular Orientation in Electrospun Poly(vinylidene fluoride) Fibers Ma, Xiaoqian; Liu, Jinglin; Ni, Chaoying ACS Macro Letters, Vol. 1, Issue 3 https://doi.org/10.1021/mz3000122	journal	February 2012
Relation of Structure, Properties and Performance of Fibrous Media for Gas Filtration Lawrence, C. A.; Liu, P. Chemical Engineering & Technology, Vol. 29, Issue 8 https://doi.org/10.1002/ceat.200600055	journal	August 2006
Effect of molecular weight on fibrous PVA produced by electrospinning Koski, A.; Yim, K.; Shivkumar, S. Materials Letters, Vol. 58, Issue 3-4 https://doi.org/10.1016/S0167-577X(03)00532-9	journal	January 2004
Modification of the rotating jet method to generate highly aligned electrospun nanofibers Khamforoush, M.; Mahjob, M. Materials Letters, Vol. 65, Issue 3 https://doi.org/10.1016/j.matlet.2010.10.060	journal	February 2011
Electrospinning of Manmade and Biopolymer Nanofibers-Progress in Techniques, Materials, and Applications Agarwal, Seema; Greiner, Andreas; Wendorff, Joachin H. Advanced Functional Materials, Vol. 19, Issue 18 https://doi.org/10.1002/adfm.200900591	journal	September 2009
Potential of Electrospun Nanofibers for Biomedical and Dental Applications Zafar, Muhammad; Najeeb, Shariq; Khurshid, Zohaib Materials, Vol. 9, Issue 2 https://doi.org/10.3390/ma9020073	journal	January 2016
Poly-L-lactide nanofibers by electrospinning – Influence of solution viscosity and electrical conductivity on fiber diameter and fiber morphology Zeng, Jun; Haoqing, Hou; Schaper, Andreas e-Polymers, Vol. 3, Issue 1 https://doi.org/10.1515/epoly.2003.3.1.102	journal	December 2003
Stabilization and carbonization of gel spun polyacrylonitrile/single wall carbon nanotube composite fibers Chae, Han Gi; Minus, Marilyn L.; Rasheed, Asif Polymer, Vol. 48, Issue 13 https://doi.org/10.1016/j.polymer.2007.04.072	journal	June 2007
Carbon Nanotubes in TiO ₂ Nanofiber Photoelectrodes for High-Performance Perovskite Solar Cells Batmunkh, Munkhbayar; Macdonald, Thomas J.; Shearer, Cameron J. Advanced Science, Vol. 4, Issue 4 https://doi.org/10.1002/advs.201600504	journal	January 2017
Characterisation of acrylic fibres used for making carbon fibres Chari, S. S.; Bahl, O. P.; Mathur, R. B. Fibre Science and Technology, Vol. 15, Issue 2 https://doi.org/10.1016/0015-0568(81)90068-3	journal	September 1981
Preparation and properties of electrospun poly(vinylidene fluoride) membranes Zhao, Zhizhen; Li, Jingqing; Yuan, Xiaoyan Journal of Applied Polymer Science, Vol. 97, Issue 2 https://doi.org/10.1002/app.21762	journal	January 2005

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