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Materials Data on Cs4Sr3(PO3)12 by Materials Project

Dataset ·
DOI:https://doi.org/10.17188/1754702· OSTI ID:1754702
Cs4Sr3(PO3)12 crystallizes in the cubic I-43d space group. The structure is three-dimensional. Cs is bonded in a 6-coordinate geometry to six O atoms. There are three shorter (3.20 Å) and three longer (3.33 Å) Cs–O bond lengths. Sr is bonded in a 8-coordinate geometry to eight O atoms. There are four shorter (2.59 Å) and four longer (2.71 Å) Sr–O bond lengths. P is bonded to four O atoms to form corner-sharing PO4 tetrahedra. There are a spread of P–O bond distances ranging from 1.50–1.63 Å. There are three inequivalent O sites. In the first O site, O is bonded in a distorted single-bond geometry to one Cs, one Sr, and one P atom. In the second O site, O is bonded in a bent 120 degrees geometry to two equivalent P atoms. In the third O site, O is bonded in a distorted single-bond geometry to one Cs, one Sr, and one P atom.
Research Organization:
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Organization:
The Materials Project; MIT; UC Berkeley; Duke; U Louvain
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1754702
Report Number(s):
mp-1203903
Country of Publication:
United States
Language:
English

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