Materials Data on MgAl by Materials Project
MgAl is beta-prime cadmium gold structured and crystallizes in the orthorhombic Pmma space group. The structure is three-dimensional. Mg is bonded to four equivalent Mg and eight equivalent Al atoms to form a mixture of distorted corner, edge, and face-sharing MgMg4Al8 cuboctahedra. There are two shorter (3.02 Å) and two longer (3.13 Å) Mg–Mg bond lengths. There are a spread of Mg–Al bond distances ranging from 2.94–3.09 Å. Al is bonded in a 12-coordinate geometry to eight equivalent Mg and two equivalent Al atoms. Both Al–Al bond lengths are 2.92 Å.
- Research Organization:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Contributing Organization:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231
- OSTI ID:
- 1751669
- Report Number(s):
- mp-1094987
- Country of Publication:
- United States
- Language:
- English
Catalytic oxidation of thiophenes and thioethers with hydrogen peroxide in the presence of W-containing layered double hydroxides
|
journal | October 2006 |
Adsorption of cholate anions on layered double hydroxides: effects of temperature, ionic strength and pH
|
journal | November 2008 |
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