Properties of Pertechnic Acid

Soderquist, Chuck; Weaver, Jamie; Cho, Herman; McNamara, Bruce; Sinkov, Sergey; McCloy, John

doi:10.1021/acs.inorgchem.9b01999

Properties of Pertechnic Acid

Journal Article · Mon Sep 09 00:00:00 EDT 2019 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.9b01999· OSTI ID:1749878

^[1]; Weaver, Jamie ^[2]; Cho, Herman ^[3]; McNamara, Bruce ^[3]; Sinkov, Sergey ^[3]; ^[2]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Washington State University
Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Washington State Univ., Pullman, WA (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Dilute aqueous pertechnic acid has long been known as strong monoprotic acid that behaves as a simple pertechnetate ion in aqueous solution. As pertechnic acid concentrates by evaporation, it becomes yellow and then dark red, and dark-red crystalline material may ultimately be obtained. We show that as pertechnic acid concentrates, at least three compounds are formed: a yellow viscous liquid, a colorless (not red) crystalline solid, and a small amount of an intensely colored red–purple compound. Here, the colorless crystalline compound melts at 118 °C and can be melted and recrystallized several times with little decomposition. The red–purple compound is apparently not stable at room temperature and quickly decomposes if it is isolated. UV–vis spectra show that Beer’s law does not hold as pertechnic acid concentrates by evaporation. We report densities, ⁹⁹Tc nuclear magnetic resonance spectra, and ultraviolet–visible absorption spectra for highly pure aqueous pertechnic acid (accompanied by the other technetium compounds that form) ranging from 1 to 14 M in technetium concentration.

View Accepted Manuscript (DOE)

Research Organization:: Rutgers Univ., New Brunswick, NJ (United States)

Sponsoring Organization:: USDOE Office of Environmental Management (EM); USDOE Office of Nuclear Energy (NE), Nuclear Energy University Program (NEUP); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC05-76RL01830; NE0008597

OSTI ID:: 1749878

Alternate ID(s):: OSTI ID: 1614873

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 20 Vol. 58; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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