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Materials Data on TiSiPt by Materials Project

Dataset ·
DOI:https://doi.org/10.17188/1746917· OSTI ID:1746917
TiPtSi crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Ti2+ is bonded to five equivalent Si4- atoms to form distorted TiSi5 trigonal bipyramids that share corners with eight equivalent PtSi4 tetrahedra, corners with eight equivalent TiSi5 trigonal bipyramids, edges with six equivalent PtSi4 tetrahedra, and edges with six equivalent TiSi5 trigonal bipyramids. There are a spread of Ti–Si bond distances ranging from 2.65–2.78 Å. Pt2+ is bonded to four equivalent Si4- atoms to form PtSi4 tetrahedra that share corners with eight equivalent PtSi4 tetrahedra, corners with eight equivalent TiSi5 trigonal bipyramids, edges with two equivalent PtSi4 tetrahedra, and edges with six equivalent TiSi5 trigonal bipyramids. There are a spread of Pt–Si bond distances ranging from 2.40–2.53 Å. Si4- is bonded in a 9-coordinate geometry to five equivalent Ti2+ and four equivalent Pt2+ atoms.
Research Organization:
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Organization:
The Materials Project; MIT; UC Berkeley; Duke; U Louvain
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1746917
Report Number(s):
mp-1102195
Country of Publication:
United States
Language:
English

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