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Materials Data on Yb(CoP3)4 by Materials Project

Dataset ·
DOI:https://doi.org/10.17188/1742995· OSTI ID:1742995
Yb(CoP3)4 crystallizes in the cubic Im-3 space group. The structure is three-dimensional. Yb3+ is bonded to twelve equivalent P1- atoms to form YbP12 cuboctahedra that share faces with eight equivalent CoP6 octahedra. All Yb–P bond lengths are 2.98 Å. Co+2.25+ is bonded to six equivalent P1- atoms to form CoP6 octahedra that share corners with six equivalent CoP6 octahedra and faces with two equivalent YbP12 cuboctahedra. The corner-sharing octahedral tilt angles are 60°. All Co–P bond lengths are 2.25 Å. P1- is bonded in a 2-coordinate geometry to one Yb3+, two equivalent Co+2.25+, and two equivalent P1- atoms. There are one shorter (2.28 Å) and one longer (2.31 Å) P–P bond lengths.
Research Organization:
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Organization:
The Materials Project; MIT; UC Berkeley; Duke; U Louvain
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1742995
Report Number(s):
mp-1105652
Country of Publication:
United States
Language:
English

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