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Title: Electrochemically mediated deionization: a review

Journal Article · · Molecular Systems Design & Engineering
DOI:https://doi.org/10.1039/D0ME00090F· OSTI ID:1742073

A review detailing existing electrode materials, cell architectures, and charge transfer mechanisms related to electrochemically driven desalination and selective element extraction in aqueous environments.

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
Advanced Materials for Energy-Water Systems (AMEWS) Center, an Energy Frontier Research Center
OSTI ID:
1742073
Journal Information:
Molecular Systems Design & Engineering, Journal Name: Molecular Systems Design & Engineering Vol. 6 Journal Issue: 1; ISSN 2058-9689
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (200)

Preparation and Application of Electrodes in Capacitive Deionization (CDI): a State-of-Art Review journal February 2016
Fabrication and characterization of a carbon electrode coated with cation-exchange polymer for the membrane capacitive deionization applications journal June 2010
Carbon aerogels for electrochemical applications journal April 1998
Rocking Chair Desalination Battery Based on Prussian Blue Electrodes journal April 2017
New concept to remove heavy metals from liquid waste based on electrochemical pH-switchable immobilized ligands journal January 2007
Theoretical evaluation of electrochemical cell architectures using cation intercalation electrodes for desalination journal March 2017
Dual-ions electrochemical deionization: a desalination generator journal January 2017
Conducting polymers and their inorganic composites for advanced Li-ion batteries: a review journal January 2015
Selective Molecularly Mediated Pseudocapacitive Separation of Ionic Species in Solution journal November 2016
Simulation and Optimization of the Dual Lithium Ion Insertion Cell journal January 1994
Continuous ion‐selective separations by shock electrodialysis journal August 2019
Scalable and Continuous Water Deionization by Shock Electrodialysis journal November 2015
Capacitive deionization (CDI) for desalination and water treatment — past, present and future (a review) journal August 2008
On the Propagation of Concentration Polarization from Microchannel−Nanochannel Interfaces Part I: Analytical Model and Characteristic Analysis journal March 2009
Three-dimensional macroporous graphene architectures as high performance electrodes for capacitive deionization journal January 2013
Bismuth as a New Chloride-Storage Electrode Enabling the Construction of a Practical High Capacity Desalination Battery journal August 2017
Enhanced Water Desalination by Increasing the Electroconductivity of Carbon Powders for High-Performance Flow-Electrode Capacitive Deionization journal November 2018
Using Ultramicroporous Carbon for the Selective Removal of Nitrate with Capacitive Deionization journal June 2019
A New High-Energy Cathode for a Na-Ion Battery with Ultrahigh Stability journal September 2013
Electrochemically Nanostructured Polyvinylferrocene/Polypyrrole Hybrids with Synergy for Energy Storage journal June 2015
Ion exchange voltammetry with electroactive ionomers journal January 1989
Nonlinear dynamics of ion concentration polarization in porous media: The leaky membrane model journal August 2013
A study of the effect of carbon characteristics on capacitive deionization (CDI) performance journal May 2018
Aqueous Sodium-Ion Battery using a Na 3 V 2 (PO 4 ) 3 Electrode journal February 2014
Timeline on the application of intercalation materials in Capacitive Deionization journal April 2019
Electrosorption of Chromium Ions on Carbon Aerogel Electrodes as a Means of Remediating Ground Water journal March 1997
Carbon nanotube/graphene composite for enhanced capacitive deionization performance journal August 2013
Extraction of uranium from seawater by polymer-bound macrocyclic hexaketone journal August 1979
High capacity and high rate capability of nitrogen-doped porous hollow carbon spheres for capacitive deionization journal April 2016
The Role of Ion Exchange Membranes in Membrane Capacitive Deionisation journal September 2017
MXene as a Cation-Selective Cathode Material for Asymmetric Capacitive Deionization journal March 2020
Nickel Hexacyanoferrate Electrodes for Continuous Cation Intercalation Desalination of Brackish Water journal November 2017
Chemically exfoliated MoS 2 for capacitive deionization of saline water journal January 2017
Modeling of electrochemical deionization across length scales: Recent accomplishments and new opportunities journal August 2020
Investigation on removal of hardness ions by capacitive deionization (CDI) for water softening applications journal April 2010
The removal of heavy metal ions from wastewater/aqueous solution using polypyrrole-based adsorbents: a review journal January 2016
Adsorption and capacitive regeneration of nitrate using inverted capacitive deionization with surfactant functionalized carbon electrodes journal April 2018
Ion gate electrodes. Polypyrrole as a switchable ion conductor membrane journal June 1984
Ordered mesoporous carbons synthesized by a modified sol–gel process for electrosorptive removal of sodium chloride journal March 2009
Electrically Controlled Anion Exchange Based on Polypyrrole and Carbon Nanotubes Nanocomposite for Perchlorate Removal journal June 2006
Improved performance and long-term stability of activated carbon doped with nitrogen for capacitive deionization journal May 2020
Nonlinear dynamics of capacitive charging and desalination by porous electrodes journal March 2010
CDI ragone plot as a functional tool to evaluate desalination performance in capacitive deionization journal January 2015
Selectivity of ion exchange membranes: A review journal June 2018
Improvement of desalination efficiency in capacitive deionization using a carbon electrode coated with an ion-exchange polymer journal February 2010
Raising the cycling stability of aqueous lithium-ion batteries by eliminating oxygen in the electrolyte journal August 2010
Review on the science and technology of water desalination by capacitive deionization journal October 2013
On the Propagation of Concentration Polarization from Microchannel−Nanochannel Interfaces Part II: Numerical and Experimental Study journal March 2009
Deionization shocks in microstructures journal December 2011
The Efficiency of Toxic Chromate Reduction by a Conducting Polymer (Polypyrrole):  Influence of Electropolymerization Conditions journal May 2000
Mechanism of Selective Ion Removal in Membrane Capacitive Deionization for Water Softening journal April 2019
Ion-Enrichment and Ion-Depletion Effect of Nanochannel Structures journal June 2004
Diffuse charge and Faradaic reactions in porous electrodes journal June 2011
Global Sensitivity Analysis To Characterize Operational Limits and Prioritize Performance Goals of Capacitive Deionization Technologies journal March 2019
Coupling desalination and energy storage with redox flow electrodes journal January 2018
Capacitive deionization of NH4ClO4 solutions with carbon aerogel electrodes journal October 1996
Fabrication of 3D flower-like MoS2/graphene composite as high-performance electrode for capacitive deionization journal January 2020
Dynamic Langmuir Model: A Simpler Approach to Modeling Capacitive Deionization journal June 2019
Developing Ion Electroadsorption Stereoselectivity, by Pore Size Adjustment with Chemical Vapor Deposition onto Active Carbon Fiber Electrodes. Case of Ca 2+ /Na + Separation in Water Capacitive Desalination journal April 2008
Study of the potentiometric response towards sodium ions of Na0.44−xMnO2 for the development of selective sodium ion sensors journal January 2007
High-performance capacitive deionization using nitrogen and phosphorus-doped three-dimensional graphene with tunable pore size journal March 2020
Water Desalination Using Capacitive Deionization with Microporous Carbon Electrodes journal February 2012
Capacitive desalination with flow-through electrodes journal January 2012
Electrophoretic deposition of carbon nanotubes–polyacrylic acid composite film electrode for capacitive deionization journal April 2012
A Desalination Battery Combining Cu 3 [Fe(CN) 6 ] 2 as a Na-Storage Electrode and Bi as a Cl-Storage Electrode Enabling Membrane-Free Desalination journal January 2019
Performance metrics for the objective assessment of capacitive deionization systems journal April 2019
A Combined Modeling and Experimental Study Assessing the Impact of Fluid Pulsation on Charge and Energy Efficiency in Capacitive Deionization journal January 2017
Conjugated polymers incorporating pendant functional groups—synthesis and characterisation journal January 1997
Na-Ion Desalination (NID) Enabled by Na-Blocking Membranes and Symmetric Na-Intercalation: Porous-Electrode Modeling journal January 2016
PANI/GO as a super adsorbent for the selective adsorption of uranium(VI) journal November 2014
Battery Electrode Materials with Omnivalent Cation Storage for Fast and Charge-Efficient Ion Removal of Asymmetric Capacitive Deionization journal July 2018
Electrochemically controlled transport of metal ions across polypyrrole membranes using a flow-through cell journal September 2001
Short-Circuited Closed-Cycle Operation of Flow-Electrode CDI for Brackish Water Softening journal July 2018
Remediation of heavy metal contaminated soil by asymmetrical alternating current electrochemistry journal June 2019
Concentration Polarization and Nonlinear Electrokinetic Flow near a Nanofluidic Channel journal July 2007
Exceptional capacitive deionization rate and capacity by block copolymer–based porous carbon fibers journal April 2020
Anion-Selective Redox Electrodes: Electrochemically Mediated Separation with Heterogeneous Organometallic Interfaces journal April 2016
Synthesis, characterisation and transport properties of layered conducting electroactive polypyrrole membranes journal September 1998
Outstanding performance of capacitive deionization by a hierarchically porous 3D architectural graphene journal October 2019
Two-Dimensional Molybdenum Carbide (MXene) with Divacancy Ordering for Brackish and Seawater Desalination via Cation and Anion Intercalation journal February 2018
Direct/Alternating Current Electrochemical Method for Removing and Recovering Heavy Metal from Water Using Graphene Oxide Electrode journal May 2019
Nitrogen-doped hierarchical porous carbon aerogel for high-performance capacitive deionization journal October 2019
Highly Stable Hybrid Capacitive Deionization with a MnO 2 Anode and a Positively Charged Cathode journal January 2018
Intrinsic tradeoff between kinetic and energetic efficiencies in membrane capacitive deionization journal February 2018
Redox-Active Polymers for Energy Storage Nanoarchitectonics journal December 2017
A dual-porosity model for ionic solute transport in expansive clays journal December 2007
Ultrahigh-Desalination-Capacity Dual-Ion Electrochemical Deionization Device Based on Na 3 V 2 (PO 4 ) 3 @C–AgCl Electrodes journal October 2018
Electrosorption behavior of graphene in NaCl solutions journal January 2009
Mesoporous Carbon for Capacitive Deionization of Saline Water journal December 2011
Removal of nitrate by asymmetric capacitive deionization journal August 2017
Selective lithium recovery from aqueous solution using a modified membrane capacitive deionization system journal November 2017
Electrochemically-mediated selective capture of heavy metal chromium and arsenic oxyanions from water journal November 2018
Nickel Hexacyanoferrate Nanoparticle Electrodes For Aqueous Sodium and Potassium Ion Batteries journal December 2011
Amidoxime-Functionalized Macroporous Carbon Self-Refreshed Electrode Materials for Rapid and High-Capacity Removal of Heavy Metal from Water journal March 2019
Diffuse-charge dynamics in electrochemical systems journal August 2004
Metallocene-containing conjugated polymers journal June 2008
Desalination of a thermal power plant wastewater by membrane capacitive deionization journal September 2006
A half-wave rectified alternating current electrochemical method for uranium extraction from seawater journal February 2017
Seven chemical separations to change the world journal April 2016
Selective adsorption of organic anions in a flow cell with asymmetric redox active electrodes journal September 2020
Highly Reversible Open Framework Nanoscale Electrodes for Divalent Ion Batteries journal October 2013
Effect of Chloride Oxidation on Local Electric Fields in Microelectrochemical Systems journal September 2019
Reduced graphene oxide and activated carbon composites for capacitive deionization journal January 2012
Graphene bonded carbon nanofiber aerogels with high capacitive deionization capability journal January 2018
Water desalination via capacitive deionization: what is it and what can we expect from it? journal January 2015
Electrochemical Parametric Pumping journal June 1978
An Asymmetric Electrochemical System with Complementary Tunability in Hydrophobicity for Selective Separations of Organics journal July 2019
Desalination via a new membrane capacitive deionization process utilizing flow-electrodes journal January 2013
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage journal January 2013
Overlimiting Current in a Microchannel journal September 2011
Enhancement of nitrate removal from a solution of mixed nitrate, chloride and sulfate ions using a nitrate-selective carbon electrode journal July 2013
New chelating sorbents for noble metals journal December 1985
Two-Dimensional Porous Electrode Model for Capacitive Deionization journal October 2015
Energy Efficiency of Capacitive Deionization journal February 2019
Direct prediction of the desalination performance of porous carbon electrodes for capacitive deionization journal January 2013
Rechargeable Lithium Batteries with Aqueous Electrolytes journal May 1994
Redox Active Polymers as Soluble Nanomaterials for Energy Storage journal September 2016
Doping-dependent ion selectivity of polyaniline membranes journal September 1999
Enhanced Electrochemical Stability of a Zwitterionic-Polymer-Functionalized Electrode for Capacitive Deionization journal February 2018
Electrochemical Properties of NaTi2(PO4)3 Anode for Rechargeable Aqueous Sodium-Ion Batteries journal January 2011
Removal of Aqueous Hg(II) by Polyaniline: Sorption Characteristics and Mechanisms journal July 2009
Electrochemical Desalination of Seawater and Hypersaline Brines with Coupled Electricity Storage journal January 2018
Attractive forces in microporous carbon electrodes for capacitive deionization journal February 2014
Overlimiting Current and Shock Electrodialysis in Porous Media journal December 2013
50th Anniversary Perspective : Conducting/Semiconducting Conjugated Polymers. A Personal Perspective on the Past and the Future journal June 2017
Water Recovery Rate in Short-Circuited Closed-Cycle Operation of Flow-Electrode Capacitive Deionization (FCDI) journal November 2019
A Prussian blue anode for high performance electrochemical deionization promoted by the faradaic mechanism journal January 2017
Hybrid capacitive deionization to enhance the desalination performance of capacitive techniques journal January 2014
Chemico-electromechanical coupling in microporous media journal October 2006
Hierarchical Porous Carbon for High-Performance Capacitive Desalination of Brackish Water journal May 2020
Electrosorption of Inorganic Salts from Aqueous Solution Using Carbon Aerogels journal July 2002
Capacitive deionization using nitrogen-doped mesostructured carbons for highly efficient brackish water desalination journal April 2019
Theory of Water Desalination with Intercalation Materials journal June 2018
Adaptive Membrane Systems Based on Conductive Electroactive Polymers journal January 1993
Enhancement in Desalination Performance of Battery Electrodes via Improved Mass Transport Using a Multichannel Flow System journal September 2019
Quantifying the trade-offs between energy consumption and salt removal rate in membrane-free cation intercalation desalination journal May 2018
Review of concepts and applications of electrochemical ion separation (EIONS) process journal May 2019
Transition from “Supercapacitor” to “Battery” Behavior in Electrochemical Energy Storage journal January 1991
Direct seawater desalination by ion concentration polarization journal March 2010
POLYORGS as complexing sorbents for preconcentration of trace metals journal January 1991
Enhancement of heavy metals removal efficiency from liquid wastes by using potential-triggered proton self-exchange effects journal June 2014
Electrodialysis for water desalination: A critical assessment of recent developments on process fundamentals, models and applications journal May 2018
A Redox-Shuttled Electrochemical Method for Energy-Efficient Separation of Salt from Water journal July 2019
A Desalination Battery journal January 2012
Novel Graphene-Like Electrodes for Capacitive Deionization journal November 2010
Simplified Prediction of Ion Removal in Capacitive Deionization of Multi-Ion Solutions journal January 2020
Electrodialysis desalination for water and wastewater: A review journal January 2020
Enhanced desalination efficiency in capacitive deionization with an ion-selective membrane journal January 2010
Hybrid Electrochemical Desalination System Combined with an Oxidation Process journal December 2017
A standard primary energy approach for comparing desalination processes journal January 2019
Theory of Water Desalination by Porous Electrodes with Immobile Chemical Charge journal November 2015
Full open-framework batteries for stationary energy storage journal January 2014
Continuous Separation of Radionuclides from Contaminated Water by Shock Electrodialysis journal December 2019
Na2FeP2O7 as a Novel Material for Hybrid Capacitive Deionization journal June 2016
Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide journal September 2013
High-performance activated carbon from polyaniline for capacitive deionization journal October 2017
High performance electrochemical saline water desalination using silver and silver-chloride electrodes journal February 2020
Electropolymerized poly-4-vinylpyridine for removal of copper from wastewater journal May 2003
n- and p-Doped Poly(3,4-ethylenedioxythiophene):  Two Electronically Conducting States of the Polymer journal September 2000
Selective removal of nitrate ions by controlling the applied current in membrane capacitive deionization (MCDI) journal February 2013
Chelating Sorbents in Analytical Chemistry journal January 1986
Redox-electrodes for selective electrochemical separations journal June 2017
Desalting by Means of Porous Carbon Electrodes journal January 1971
Carbon aerogels electrode with reduced graphene oxide additive for capacitive deionization with enhanced performance journal January 2014
Metallopolymers with emerging applications journal April 2008
Small-scale desalination of seawater by shock electrodialysis journal February 2020
Metallopolymers: New Multifunctional Materials journal November 2007
Use of mesoporous conductive carbon black to enhance performance of activated carbon electrodes in capacitive deionization technology journal March 2011
Na4Mn9O18 as a positive electrode material for an aqueous electrolyte sodium-ion energy storage device journal March 2010
Chelating polymers and related supports for separation and preconcentration of trace metals journal May 1990
Million-fold Preconcentration of Proteins and Peptides by Nanofluidic Filter journal July 2005
Realizing the full potential of conjugated polymers: innovation in polymer synthesis journal January 2016
Selectivity of Polymer Membrane-Based Ion-Selective Electrodes: Self-Consistent Model Describing the Potentiometric Response in Mixed Ion Solutions of Different Charge journal October 1994
Electrically Switched Ion Exchange Based on Polypyrrole and Carbon Nanotube Nanocomposite for the Removal of Chromium(VI) from Aqueous Solution journal January 2018
Fluoride Removal from Brackish Groundwaters by Constant Current Capacitive Deionization (CDI) journal September 2016
Na2FeP2O7 as a positive electrode material for rechargeable aqueous sodium-ion batteries journal January 2014
The Future of Seawater Desalination: Energy, Technology, and the Environment journal August 2011
An ion gate membrane: electrochemical control of ion permeability through a membrane with an embedded electrode journal November 1982
New Iron-Based Mixed-Polyanion Cathodes for Lithium and Sodium Rechargeable Batteries: Combined First Principles Calculations and Experimental Study journal June 2012
Recent Trends in Metallopolymer Design: Redox-Controlled Surfaces, Porous Membranes, and Switchable Optical Materials Using Ferrocene-Containing Polymers journal May 2018
Low Energy Desalination Using Battery Electrode Deionization journal September 2017
Development of membrane systems based on conducting polymers journal June 1999
Water purification by shock electrodialysis: Deionization, filtration, separation, and disinfection journal February 2015
Electrokinetics in Microfluidic Channels Containing a Floating Electrode
  • Dhopeshwarkar, Rahul; Hlushkou, Dzmitry; Nguyen, Mark
  • Journal of the American Chemical Society, Vol. 130, Issue 32, p. 10480-10481 https://doi.org/10.1021/ja8036405
journal August 2008
Selective Electrochemical Separation and Recovery of Uranium from Mixture of Uranium(VI) and Lanthanide(III) Ions in Aqueous Medium journal August 2018
Electrodialysis, a mature technology with a multitude of new applications journal December 2010
Double doping of conjugated polymers with monomer molecular dopants journal January 2019
Aqueous Rechargeable Li and Na Ion Batteries journal September 2014
A comprehensive review on recently developed carbon based nanocomposites for capacitive deionization: From theory to practice journal December 2018
Tunnel structured manganese oxide nanowires as redox active electrodes for hybrid capacitive deionization journal February 2018
MXene as a novel intercalation-type pseudocapacitive cathode and anode for capacitive deionization journal January 2016
Electrochemically Mediated Seawater Desalination journal June 2013
Sponge-Templated Preparation of High Surface Area Graphene with Ultrahigh Capacitive Deionization Performance journal March 2014
Mesoporous carbon derived from ZIF-8 for high efficient electrosorption journal February 2019
Carbon Black Flow Electrode Enhanced Electrochemical Desalination Using Single-Cycle Operation journal December 2019
Ion Removal Performance, Structural/Compositional Dynamics, and Electrochemical Stability of Layered Manganese Oxide Electrodes in Hybrid Capacitive Deionization journal September 2018
Porous nitrogen-doped MXene-based electrodes for capacitive deionization journal March 2020
Improved performance in capacitive deionization of activated carbon electrodes with a tunable mesopore and micropore ratio journal July 2015
Focusing, sorting, and separating microplastics by serial faradaic ion concentration polarization journal January 2020
Electroactive ion exchange polymers journal June 1985