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Materials Data on Na3Os by Materials Project

Dataset ·
DOI:https://doi.org/10.17188/1741013· OSTI ID:1741013
Na3Os is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. there are two inequivalent Na sites. In the first Na site, Na is bonded to four equivalent Na and four equivalent Os atoms to form a mixture of distorted corner, edge, and face-sharing NaNa4Os4 tetrahedra. All Na–Na bond lengths are 3.12 Å. All Na–Os bond lengths are 3.12 Å. In the second Na site, Na is bonded in a 8-coordinate geometry to eight equivalent Na and six equivalent Os atoms. All Na–Os bond lengths are 3.60 Å. Os is bonded in a distorted body-centered cubic geometry to fourteen Na atoms.
Research Organization:
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Organization:
The Materials Project; MIT; UC Berkeley; Duke; U Louvain
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1741013
Report Number(s):
mp-1186064
Country of Publication:
United States
Language:
English

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