Hydrothermal Corrosion of First-Generation Dual-Purpose Coatings on Silicon Carbide for Accident-Tolerant Fuel Cladding

Doyle, Peter J.; Ang, Caen; Snead, Lance; Katoh, Yutai; Terrani, Kurt; Raiman, Stephen S.

doi:10.1016/j.jnucmat.2020.152695

Title: Hydrothermal Corrosion of First-Generation Dual-Purpose Coatings on Silicon Carbide for Accident-Tolerant Fuel Cladding

Journal Article · Tue Dec 08 00:00:00 EST 2020 · Journal of Nuclear Materials

DOI:https://doi.org/10.1016/j.jnucmat.2020.152695· OSTI ID:1737491

^[1]; Ang, Caen ^[2]; Snead, Lance ^[3];

^[1];

^[4]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Stony Brook Univ., NY (United States)
Texas A & M Univ., College Station, TX (United States)

In this study, four different commercial coatings, TiN, Cr, CrN, and Cr/CrN (multilayer) were deposited by physical vapor deposition (PVD) on high resistivity chemical vapor deposited (CVD) SiC for the dual purpose of corrosion mitigation and fission gas hermeticity. The coatings were exposed for up to 2600 hours in flowing high temperature (288-350°C), high purity, liquid water with dissolved hydrogen (0.15-3ppm) or dissolved oxygen (1-2ppm). The Cr/CrN coatings did not adhere well and spalled quickly during exposure. In oxygenated conditions, none of the coatings were protective . CrN coatings spalled preferentially at defect sites, but reacted slowly enough in the absence of defects to potentially be chemically protective. TiN coatings fully oxidized within a few hundred hours and spalled. In hydrogen, all the coatings were chemically stable. Coating failures were identified and attributed to localized spallation, potentially related to coating defects. Coating improvements are recommended to reduce spallation and improve coating protection for future generations of dual-purpose coatings.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE), Nuclear Fuel Cycle and Supply Chain. Advanced Fuel Campaign; USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1737491

Alternate ID(s):: OSTI ID: 1776058

Journal Information:: Journal of Nuclear Materials, Vol. 544; ISSN 0022-3115

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (40)

Evaluation of steam corrosion and water quenching behavior of zirconium-silicide coated LWR fuel claddings Yeom, Hwasung; Lockhart, Cody; Mariani, Robert Journal of Nuclear Materials, Vol. 499 https://doi.org/10.1016/j.jnucmat.2017.11.045	journal	February 2018
Accident tolerant fuels for LWRs: A perspective Zinkle, S. J.; Terrani, K. A.; Gehin, J. C. Journal of Nuclear Materials, Vol. 448, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2013.12.005	journal	May 2014
Material Selection for Accident Tolerant Fuel Cladding Pint, B. A.; Terrani, K. A.; Yamamoto, Y. Metallurgical and Materials Transactions E, Vol. 2, Issue 3 https://doi.org/10.1007/s40553-015-0056-7	journal	September 2015
A comparative study of the oxidation behavior of Cr2N and CrN coatings Qi, Z. B.; Liu, B.; Wu, Z. T. Thin Solid Films, Vol. 544 https://doi.org/10.1016/j.tsf.2013.01.031	journal	October 2013
Raman fingerprint of chromate, aluminate and ferrite spinels: Raman fingerprint of chromate, aluminate and ferrite spinels D'Ippolito, Veronica; Andreozzi, Giovanni B.; Bersani, Danilo Journal of Raman Spectroscopy, Vol. 46, Issue 12 https://doi.org/10.1002/jrs.4764	journal	August 2015
Role of irradiation-induced defects on SiC dissolution in hot water Kondo, Sosuke; Mouri, Shinichiro; Hyodo, Yoshihiro Corrosion Science, Vol. 112 https://doi.org/10.1016/j.corsci.2016.08.007	journal	November 2016
Handbook of SiC properties for fuel performance modeling Snead, Lance L.; Nozawa, Takashi; Katoh, Yutai Journal of Nuclear Materials, Vol. 371, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2007.05.016	journal	September 2007
Surface characterisation of TiC _x N _{1 − x} coatings processed by cathodic arc physical vapour deposition: XPS and XRD analysis Siow, Ping Chuan; Ghani, Jaharah A.; Rizal, Muhammad Surface and Interface Analysis, Vol. 51, Issue 6 https://doi.org/10.1002/sia.6626	journal	February 2019
Behavior of an improved Zr fuel cladding with oxidation resistant coating under loss-of-coolant accident conditions Park, Dong Jun; Kim, Hyun Gil; Jung, Yang Il Journal of Nuclear Materials, Vol. 482 https://doi.org/10.1016/j.jnucmat.2016.10.021	journal	December 2016
Raman spectroscopy of ferromagnetic ${CrO}_{2}$ Iliev, M. N.; Litvinchuk, A. P.; Lee, H. -G. Physical Review B, Vol. 60, Issue 1 https://doi.org/10.1103/PhysRevB.60.33	journal	July 1999
Factors affecting the hydrothermal corrosion behavior of chemically vapor deposited silicon carbides Shin, Jung Ho; Kim, Daejong; Lee, Hyeon-Geun Journal of Nuclear Materials, Vol. 518 https://doi.org/10.1016/j.jnucmat.2019.03.026	journal	May 2019
Experimental evaluation of cold spray FeCrAl alloys coated zirconium-alloy for potential accident tolerant fuel cladding Dabney, Tyler; Johnson, Greg; Yeom, Hwasung Nuclear Materials and Energy, Vol. 21 https://doi.org/10.1016/j.nme.2019.100715	journal	December 2019
High temperature steam oxidation of chromium-coated zirconium-based alloys: Kinetics and process Brachet, Jean-Christophe; Rouesne, Elodie; Ribis, Joël Corrosion Science, Vol. 167 https://doi.org/10.1016/j.corsci.2020.108537	journal	May 2020
Microprobe Raman spectroscopy of TiN coatings oxidized by solar beam heat treatment Franck, M.; Celis, J-P.; Roos, J. R. Journal of Materials Research, Vol. 10, Issue 1 https://doi.org/10.1557/JMR.1995.0119	journal	January 1995
Hydrothermal corrosion of SiC in LWR coolant environments in the absence of irradiation Terrani, K. A.; Yang, Y.; Kim, Y. -J. Journal of Nuclear Materials, Vol. 465 https://doi.org/10.1016/j.jnucmat.2015.06.019	journal	October 2015
Evaluation of neutron economical effect of new cladding materials in light water reactors Oizumi, Akito; Akie, Hiroshi; Iwamoto, Nobuyuki Journal of Nuclear Science and Technology, Vol. 51, Issue 1 https://doi.org/10.1080/00223131.2014.849210	journal	October 2013
Characterization of PVD Cr, CrN, and TiN coatings on SiC Mouche, P. A.; Ang, C.; Koyanagi, T. Journal of Nuclear Materials, Vol. 527 https://doi.org/10.1016/j.jnucmat.2019.151781	journal	December 2019
Current status and critical issues for development of SiC composites for fusion applications Katoh, Y.; Snead, L. L.; Henager, C. H. Journal of Nuclear Materials, Vol. 367-370 https://doi.org/10.1016/j.jnucmat.2007.03.032	journal	August 2007
Raman study of NiFe ₂ O ₄ nanoparticles, bulk and films: effect of laser power: Raman study of NiFe ₂ O ₄ nanoparticles, bulk and films Ahlawat, Anju; Sathe, V. G. Journal of Raman Spectroscopy, Vol. 42, Issue 5 https://doi.org/10.1002/jrs.2791	journal	September 2010
The effects of neutron and ionizing irradiation on the aqueous corrosion of SiC Doyle, Peter; Sun, Kaichao; Snead, Lance Journal of Nuclear Materials, Vol. 536 https://doi.org/10.1016/j.jnucmat.2020.152190	journal	August 2020
Materials selection for nuclear applications: Challenges and opportunities Hosemann, P.; Frazer, D.; Fratoni, M. Scripta Materialia, Vol. 143 https://doi.org/10.1016/j.scriptamat.2017.04.027	journal	January 2018
Microstructure and hydrothermal corrosion behavior of NITE-SiC with various sintering additives in LWR coolant environments Parish, Chad M.; Terrani, Kurt A.; Kim, Young-Jin Journal of the European Ceramic Society, Vol. 37, Issue 4 https://doi.org/10.1016/j.jeurceramsoc.2016.11.033	journal	April 2017
Influence of phonon confinement, surface stress, and zirconium doping on the Raman vibrational properties of anatase TiO2 nanoparticles Lejon, Christian; Österlund, Lars Journal of Raman Spectroscopy, Vol. 42, Issue 11 https://doi.org/10.1002/jrs.2956	journal	April 2011
Characterisation of chromium nitride films produced by PVD techniques Barata, A.; Cunha, L.; Moura, C. Thin Solid Films, Vol. 398-399 https://doi.org/10.1016/S0040-6090(01)01498-5	journal	November 2001
The role of droplets on the cavitation erosion damage of TiN coatings produced with cathodic arc physical vapor deposition Azar, Golnaz Taghavi Pourian; Yelkarasi, Cagatay; Ürgen, Mustafa Surface and Coatings Technology, Vol. 322 https://doi.org/10.1016/j.surfcoat.2017.05.050	journal	August 2017
Development of cold spray chromium coatings for improved accident tolerant zirconium-alloy cladding Maier, Benjamin; Yeom, Hwasung; Johnson, Greg Journal of Nuclear Materials, Vol. 519 https://doi.org/10.1016/j.jnucmat.2019.03.039	journal	June 2019
Silicon Carbide Oxidation in Steam up to 2 MPa Terrani, Kurt A.; Pint, Bruce A.; Parish, Chad M. Journal of the American Ceramic Society, Vol. 97, Issue 8 https://doi.org/10.1111/jace.13094	journal	July 2014
Raman spectroscopy of sol-gel derived titanium oxide thin films: Raman spectroscopy of sol-gel derived titanium oxide thin films Wang, Xiaodong; Shen, Jun; Pan, Qiang Journal of Raman Spectroscopy, Vol. 42, Issue 7 https://doi.org/10.1002/jrs.2899	journal	February 2011
Hydrothermal corrosion of 2nd generation FeCrAl alloys for accident tolerant fuel cladding Raiman, Stephen S.; Field, Kevin G.; Rebak, Raul B. Journal of Nuclear Materials, Vol. 536 https://doi.org/10.1016/j.jnucmat.2020.152221	journal	August 2020
Oxidation kinetics of silicon carbide in steam at temperature range of 1400 to 1800 °C studied by laser heating Pham, Hai Vu; Nagae, Yuji; Kurata, Masaki Journal of Nuclear Materials, Vol. 529 https://doi.org/10.1016/j.jnucmat.2019.151939	journal	February 2020
Evaluation of the effects of neutron irradiation on first-generation corrosion mitigation coatings on SiC for accident-tolerant fuel cladding Doyle, Peter J.; Koyanagi, Takaaki; Ang, Caen Journal of Nuclear Materials, Vol. 536 https://doi.org/10.1016/j.jnucmat.2020.152203	journal	August 2020
Raman spectroscopy studies on the thermal stability of TiN, CrN, TiAlN coatings and nanolayered TiN/CrN, TiAlN/CrN multilayer coatings Barshilia, Harish C.; Rajam, K. S. Journal of Materials Research, Vol. 19, Issue 11 https://doi.org/10.1557/JMR.2004.0444	journal	November 2004
Oxidation Transitions for SiC Part II. Passive-to-Active Transitions Harder, Bryan; Jacobson, Nathan; Myers, Dwight Journal of the American Ceramic Society, Vol. 96, Issue 2 https://doi.org/10.1111/jace.12104	journal	December 2012
On the Vibrational Spectra and Structure of FeCrO3 and of the Ilmenite-Type Compounds CoTiO3 and NiTiO3 Baraton, M. I.; Busca, G.; Prieto, M. C. Journal of Solid State Chemistry, Vol. 112, Issue 1 https://doi.org/10.1006/jssc.1994.1256	journal	September 1994
On the Formation Mechanism of Chromium Nitrides: An in situ Study: On the Formation Mechanism of Chromium Nitrides Widenmeyer, Marc; Meissner, Elke; Senyshyn, Anatoliy Zeitschrift für anorganische und allgemeine Chemie, Vol. 640, Issue 14 https://doi.org/10.1002/zaac.201400246	journal	July 2014
Oxidation behavior of chromium nitride films Chen, Hong-Ying; Lu, Fu-Hsing Thin Solid Films, Vol. 515, Issue 4 https://doi.org/10.1016/j.tsf.2006.06.039	journal	December 2006
Raman spectrum of anatase, TiO2 Ohsaka, Toshiaki; Izumi, Fujio; Fujiki, Yoshinori Journal of Raman Spectroscopy, Vol. 7, Issue 6 https://doi.org/10.1002/jrs.1250070606	journal	December 1978
Revised pourbaix diagrams for chromium at 25–300 °C Beverskog, B.; Puigdomenech, I. Corrosion Science, Vol. 39, Issue 1 https://doi.org/10.1016/S0010-938X(97)89244-X	journal	January 1997
Hydrothermal corrosion behavior of CVD SiC in high temperature water Doyle, Peter J.; Zinkle, Steven; Raiman, Stephen S. Journal of Nuclear Materials, Vol. 539 https://doi.org/10.1016/j.jnucmat.2020.152241	journal	October 2020
Corrosion Behavior of Silicon Carbide in 290oC Water Hirayama, Hideo; Kawakubo, Takashi; Goto, Akira Journal of the American Ceramic Society, Vol. 72, Issue 11 https://doi.org/10.1111/j.1151-2916.1989.tb06029.x	journal	November 1989

Similar Records

Hydrothermal Corrosion of Coatings on Silicon Carbide in Boiling Water Reactor Conditions

Journal Article · Tue Nov 13 00:00:00 EST 2018 · Corrosion · OSTI ID:1737491

Raiman, Stephen S.; Doyle, Peter J.; Ang, Caen K.; +2 more

Mechanical Properties and Characterization of Coated SiC Fuel Cladding

Journal Article · Fri Jul 01 00:00:00 EDT 2016 · Transactions of the American Nuclear Society · OSTI ID:1737491

Ang, Caen; Kiggans, James; Terrani, Kurt; +4 more

Computation Modeling and Assessment of Nanocoatings for Ultra Supercritical Boilers

Technical Report · Tue Jun 21 00:00:00 EDT 2011 · OSTI ID:1737491

Shingledecker, J; Gandy, D; Cheruvu, N; +2 more

Related Subjects

36 MATERIALS SCIENCE
SiC
ATF cladding
coating
corrosion
Raman
LWR

Title: Hydrothermal Corrosion of First-Generation Dual-Purpose Coatings on Silicon Carbide for Accident-Tolerant Fuel Cladding

Citation Formats

References (40)

Similar Records

Related Subjects