Studies on magnetocaloric effect of Tb2Ni0.90Si2.94 compound

Pakhira, Santanu; Kundu, Mily; Ranganathan, R.; Mazumdar, Chandan

doi:10.1088/1361-648x/abcdb2

Studies on magnetocaloric effect of Tb₂Ni_0.90Si_2.94 compound

Journal Article · Tue Dec 15 23:00:00 EST 2020 · Journal of Physics. Condensed Matter

DOI:https://doi.org/10.1088/1361-648x/abcdb2· OSTI ID:1735845

^[1]; Kundu, Mily ^[2]; Ranganathan, R. ^[2]; ^[2]

Saha Inst. of Nuclear Physics, Kolkata (India); Ames Lab., Ames, IA (United States)
Saha Inst. of Nuclear Physics, Kolkata (India)

A comparative study has been carried out on the magnetocaloric properties of as-cast and annealed Tb₂Ni_0.90Si_2.94 intermetallic compound. While the as-cast material exhibits ferromagnetic cluster-glass behaviour below 9.9 K coexisting with antiferromagnetic (AFM) interaction, the annealed system shows AFM ordering below 13.5 K and spin freezing occurs below 4 K. The compound exhibits moderate magnetocaloric performance with maximum isothermal entropy changes (–ΔS_M) 8.8 and 10.9 J kg^–1 K^–1, relative cooling power (RCP) 306 and 365 J kg^–1, along with adiabatic temperature change (ΔT_ad) 5.5 and 8.15 K for 70 kOe magnetic field change in as-cast and annealed forms, respectively. The estimated magnetic entropy change is found to be larger for annealed sample in comparison to that of as-cast analogue. However, the full width at half maxima (FWHM) of –ΔS_M(T) behaviour is larger in as-cast compound due to the presence of inherent structural disorder which reduces with thermal annealing. A positive isothermal entropy change (–ΔS_M) and adiabatic temperature change (ΔT_ad) is observed for the as-cast compound in the measured field and temperature region. In contrast, the annealed system exhibits inverse magnetocaloric effect in the low field and temperature region where AFM interactions dominate. Magnetocaloric effect (MCE) is used as a tool to establish a subtle correlation between the observed magnetocaloric effect and the reported magnetic properties of the system.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1735845

Alternate ID(s):: OSTI ID: 23025324

Report Number(s):: IS--J-10,377

Journal Information:: Journal of Physics. Condensed Matter, Journal Name: Journal of Physics. Condensed Matter Journal Issue: 9 Vol. 33; ISSN 0953-8984

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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