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Dual conductor surface modified SOFC cathode particles and methods of making same

Patent ·
OSTI ID:1735146

A novel method to produce ALD films disposed on powders is disclosed. Examples include the formation of a cobalt doped zirconia (CDZ), hafnia, and cobalt doped hafnia (CDH) films on lanthanum strontium cobalt iron oxide (LSCF) powder for solid oxide fuel cell cathodes. The coated powders are sintered into porous cathodes that have utility for preventing the migration of cations in the powder to the surface of the sintered cathode and/or other performance enhancing attributes.

Research Organization:
Sonata Scientific, LLC, Bethel, CT (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
SC0013116
Assignee:
Sonata Scientific LLC (Bethel, CT)
Patent Number(s):
10,741,850
Application Number:
15/374,981
OSTI ID:
1735146
Country of Publication:
United States
Language:
English

References (6)

Atomic Layer Deposition Functionalized Composite SOFC Cathode La 0.6 Sr 0.4 Fe 0.8 Co 0.2 O 3-δ -Gd 0.2 Ce 0.8 O 1.9 : Enhanced Long-Term Stability journal October 2013
Enhancing SOFC cathode performance by surface modification through infiltration journal January 2014
Materials for Solid Oxide Fuel Cells journal February 2010
Enhanced performance of LSCF cathode through surface modification journal May 2012
Stabilizing Nanostructured Solid Oxide Fuel Cell Cathode with Atomic Layer Deposition journal August 2013
In situ characterization of strontium surface segregation in epitaxial La0.7Sr0.3MnO3 thin films as a function of oxygen partial pressure journal October 2008

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